1-Pentafluorphenylpentan | 40316-36-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Pentafluorphenylpentan
• 英文别名: 1-Pentafluorophenylpentane；1,2,3,4,5-pentafluoro-6-pentylbenzene
• CAS: 40316-36-7
• 化学式: C₁₁H₁₁F₅
• 分子量: 238.2
• InChiKey: XCFZXIJTILBJHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  正丁基锂 、 2,3,4,5,6-五氟苄基氯 以 正己烷 为溶剂， 生成 1-Pentafluorphenylpentan
  参考文献：
  名称：

  Leshina,T.V. et al., Journal of Organic Chemistry USSR (English Translation), 1972, vol. 8, p. 2412 - 2416

  摘要：

  DOI：

文献信息

• Diphenyl ether derivatives
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0240121A2

  公开（公告）日：1987-10-07

  The invention provides novel insecticidally useful fluorinated aralkyl derivatives of formula: wherein W represents one or more substituents selected from halo, alkyl, alkoxy, alkoxyalkyl, haloalkyl and haloalkoxy, or W represents a bidentate group linking adjacent carbon atoms selected from alkylene and alkylenedioxy; Y is a group selected from wherein X is a group of formula -(CF₂)nR³, where R³ is selected from hydrogen, chloro and fluoro and n is one or two; R¹ is selected from hydrogen, chloro, fluoro and hydroxy; R² is selected from methyl, cyano, ethynyl and hydrogen and Q is selected from carbon bearing a hydrogen and nitrogen. The invention also provides processes and intermediates for the preparation of the title compounds, and compositions containing the title compounds.

  本发明提供了具有杀虫作用的新型含氟芳烷基衍生物，其式如下 其中 W 代表选自卤代、烷基、烷氧基、烷氧基烷基、卤代烷基和卤代烷氧基的一个或多个取代基，或 W 代表连接选自亚烷基和亚烷基二氧基的相邻碳原子的双齿基团；Y 是选自以下的基团 其中 X 是式-(CF₂)nR³的基团，其中 R³ 选自氢、氯和氟，n 是 1 或 2；R¹ 选自氢、氯、氟和羟基；R² 选自甲基、氰基、乙炔基和氢，Q 选自含氢和氮的碳。本发明还提供了制备标题化合物的工艺和中间体，以及含有标题化合物的组合物。
• Chemical intermediates
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0390228A2

  公开（公告）日：1990-10-03

  intermediates of formula:- wherein Q is selected from carbon bearing a hydrogen atom and nitrogen; Z represents one or more substituents selected from fluoro, benzyl, phenoxy, chlorophenoxy, fluorophenoxy and bromophenoxy, and R4 is selected from hydroxy, bromo, chloro and iodo, or R4 is selected from a group of formula:-- P(R)3 and a group of formula:- wherein R represents alkyl or aryl. The intermediates of the invention are useful in the preparation of insecticidal compoumds.

  式的中间体 其中 Q 选自含氢原子的碳和氮；Z 代表一个或多个取代基，选自氟、苄基、苯氧基、氯苯氧基、氟苯氧基和溴苯氧基，R4 选自羟基、溴基、氯基和碘基，或 R4 选自式基团：- P(R)3 和一个式组 其中 R 代表烷基或芳基。本发明的中间体可用于制备杀虫化合物。
• METHOD FOR PRODUCING POLYMER COMPOUND
  申请人：Sumitomo Chemical Co., Ltd

  公开号：EP2540756A1

  公开（公告）日：2013-01-02

  The problem to be solved of the present invention is to provide a method for producing a polymer compound having an increased molecular weight through a short-time polymerization process. Means for solving the problem is a method for producing a polymer compound having a repeating unit represented by formula (2), which method comprising a step of polymerizing a first aromatic compound having at least two first functional groups each containing a boron atom with a second aromatic compound having at least two second functional groups which are capable of reacting with the first functional group, in the presence of an organic solvent, a palladium complex, a base and a compound represented by formula (1): wherein Ra, Rb, Rc, Rd, Re and Rf are the same or different, and each represents a hydrogen atom or a monovalent organic group, or any two of Ra to Rf are bound with each other to form a non-aromatic ring, and the remainder are the same or different, and each represents a hydrogen atom or a monovalent organic group;         -Ar-     (2) wherein Ar represents a divalent group resulting from the removal of two hydrogen atoms from an aromatic compound.

  本发明要解决的问题是提供一种通过短时间聚合工艺生产分子量增大的高分子化合物的方法。解决该问题的方法是一种生产具有式（2）表示的重复单元的聚合物化合物的方法，该方法包括以下步骤：在有机溶剂、钯络合物、碱和式（1）表示的化合物存在下，使具有至少两个第一官能团（每个官能团含有一个硼原子）的第一芳香族化合物与具有至少两个第二官能团（能与第一官能团反应）的第二芳香族化合物聚合： 其中 Ra、Rb、Rc、Rd、Re 和 Rf 相同或不同，各自代表一个氢原子或一个一价有机基团，或 Ra 至 Rf 中的任意两个相互结合形成一个非芳香环，其余相同或不同，各自代表一个氢原子或一个一价有机基团； -Ar- (2) 其中 Ar 代表从芳香族化合物中去除两个氢原子后产生的二价基团。
• Leshina,T.V. et al., Journal of Organic Chemistry USSR (English Translation), 1972, vol. 8, p. 2412 - 2416
  作者：Leshina,T.V. et al.

  DOI：——

  日期：——