N-(2-thioethyl)-2-hydroxyacetophenoneimine | 58199-71-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N-(2-thioethyl)-2-hydroxyacetophenoneimine
• 英文别名: 2-[1-(2-mercapto-ethylimino)-ethyl]-phenol；6-{1-[(2-Sulfanylethyl)amino]ethylidene}cyclohexa-2,4-dien-1-one；2-[C-methyl-N-(2-sulfanylethyl)carbonimidoyl]phenol
• CAS: 58199-71-6
• 化学式: C₁₀H₁₃NOS
• 分子量: 195.285
• InChiKey: FPZNHAJMOJYESN-UHFFFAOYSA-N

物化性质

• 沸点：
  294.9±40.0 °C(Predicted)
• 密度：
  1.11±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  33.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  二氯二茂钛 、 N-(2-thioethyl)-2-hydroxyacetophenoneimine 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Singh, R. V., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1985, vol. 24, # 12, p. 1064 - 1065

  摘要：

  DOI：

文献信息

• Singh,R.V.; Tandon,J.P., Journal fur praktische Chemie (Leipzig 1954), 1979, vol. 321, p. 683 - 690
  作者：Singh,R.V.、Tandon,J.P.

  DOI：——

  日期：——
• SYNTHESIS AND CHARACTERIZATION OF SOME DIOXOMOLYBDENUM(VI) COMPLEXES WITH O, N, S DONOR SCHIFF BASES DERIVED FROM S-METHYLDITHIOCARBAZATE, S-BENZYLDITHIOCARBAZATE, 2-AMINOETHANETHIOL, AND SUBSTITUTED SALICYLALDEHYDES
  作者：Niren Kathale、N. Sumita Rao、N. N. Rao、K. N. Munshi

  DOI：10.1081/sim-100104856

  日期：2001.5.31

  Synthesis and characterization of some dioxomolybdenum(VI) complexes which can be represented by the general formulae MoO2(L)(EtOH) (where LH2 = Schiff base derived from o-hydroxyacetophenone (hap), o-hydroxypropiophenone (hpp), and S-methyldithiocarbazate (SMDTC), S-benzyldithiocarbazate (SBDTC) and 2-aminoethanethiol (AmET)) are reported. The various Schiff base ligands prepared by condensation of appropriate amino compounds and substituted salicylaldehydes are H(2)hap-SBDTC (1a), H(2)hpp-SBDTC (2a), H(2)hpp-SMDTC (3a), H(2)hap-SMDTC (4a), H(2)hap-AmET (5a) and H(2)hpp-AmEt (6a). The various Schiff base complexes prepared by reacting cis-MoO2(acaC)(2) and the ligands (1a)-(6a) are MoO2 (hap-SBDTC)(EtOH) (1b), MoO2(hpp-SBDTC)(EtOH) (2b) MoO2(hpp)-SMDTC)(EtOH) (3b), MoO2(hap-SMDTC)(EtOH) (4b), MoO2(hap-AmET)(EtOH) (5b) and MoO2(hpp-AmET) (EtOH) (6b). These complexes have been characterized by elemental analyses, UV-Vis, IR, NMR, AAS, TGA and conductivity measurements. The complexes are monomers nonelectrolytes, diamagnetic and six-coordinated. The Schiff bases behave as dibasic tridentate ligands and coordinate through the phenolic oxygen, thioenolic sulfur and azomethine nitrogen atoms.