1-chloro-3,5,5-trimethylhexane | 42202-03-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1-chloro-3,5,5-trimethylhexane
• 英文别名: 1-Chlor-3,5,5-trimethyl-hexan；3.5.5-Trimethyl-hexylchlorid
• CAS: 42202-03-9
• 化学式: C₉H₁₉Cl
• 分子量: 162.703
• InChiKey: HYXSOHJGMQQODD-UHFFFAOYSA-N

物化性质

• 沸点：
  179-180 °C
• 密度：
  0.861±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-chloro-3,5,5-trimethylhexane 在 乙醚 、 乙醇 作用下， 生成 5,7,7-trimethyl-octan-2-one
  参考文献：
  名称：

  458.支链烃的合成和反应。第一部分：具有3：5：5-三甲基己基的烃

  摘要：

  DOI：

  10.1039/jr9510002064
• 作为产物：
  描述：

  3,5,5-三甲基-1-己醇 在 吡啶 、 氯化亚砜 作用下， 生成 1-chloro-3,5,5-trimethylhexane
  参考文献：
  名称：

  458.支链烃的合成和反应。第一部分：具有3：5：5-三甲基己基的烃

  摘要：

  DOI：

  10.1039/jr9510002064

文献信息

• Process for the preparation of phosphine oxides and sulphides
  申请人：Societe Nationale des Poudres et Explosifs

  公开号：US03932524A1

  公开（公告）日：1976-01-13

  A process for the preparation of phosphine oxides or sulphides of the formula: ##EQU1## in which R is a linear or branched aliphatic radical containing 5-12 carbon atoms, aralkyl radical selected from the group consisting of lower alkyl of 2-3 carbon atoms substituted by a phenyl group or R is cyclohexyl and X is an oxygen or sulphur atom comprising reacting a halo-compound of the formula R--Hal, in which Hal is chlorine, bromine or iodine, with magnesium to form a Grignard derivative of the formula RMgHal, the reaction being carried out initially in a very small amount of diethyl ether and then in a solvent mixture containing a preponderant amount of an aliphatic or aromatic hydrocarbon, which is liquid at room temperature or triethylamine, adding phosphorus oxychloride or phosphorus sulphochloride to the reaction mixture containing the Grignard derivative, and isolating the phosphine oxide or phosphine sulphide formed by removing the solvent by steam stripping or steam distillation. These compounds are valuable for use in the selective extraction of rare metals.

  一种制备磷氧化物或磷硫化物的方法，化学式如下：##EQU1## 其中R是含有5-12个碳原子的直链或支链脂肪基，芳基烷基基团，包括由苯基取代的2-3个碳原子的低碳烷基基团，或R是环己基，X是氧或硫原子，包括将具有化学式R-Hal的卤代化合物（其中Hal是氯、溴或碘）与镁反应形成化学式RMgHal的格氏试剂衍生物，反应最初在少量乙醚中进行，然后在包含大量脂肪或芳香烃的溶剂混合物中进行，该溶剂在室温下为液体，或者在三乙胺中进行，向含有格氏试剂的反应混合物中加入氧氯化磷或硫氯化磷，通过蒸汽蒸馏去除溶剂来分离形成的磷氧化物或磷硫化物。这些化合物在稀有金属的选择性提取中具有重要价值。
• LUBRICATING OIL ADDITIVE AND LUBRICATING OIL COMPOSITION FOR DIESEL ENGINES
  申请人：Kao Corporation

  公开号：EP0835924A1

  公开（公告）日：1998-04-15

  A lubricating oil additive for diesel engines comprising one or more members of carboxylic acids, metal salts of carboxylic acids, amine salts of carboxylic acids, and carboxylic acid amides, each having a substituted amino group or substituted amino groups in a molecule, wherein the substituted aminocarboxylic acid compounds have a function of dispersing water-containing calcium sulfate in an oil; and a lubricating oil composition for diesel engines including these lubricating oil additives for diesel engines. When the lubricating oil additives and the lubricating oil compositions for diesel engines of the present invention are added to the lubricating oil, the dispersion function of the water-containing calcium sulfate admixed in the lubricating oil is dramatically improved, and the dispersion functions in oil of the staining components, such as soots, sludges, and the like, mentioned above owned by the lubricating oil are enhanced, so that its detergency is dramatically improved. Therefore, it is made possible to lower the concentration in the amount of the metal-based detergent as well as to lengthen the service life of the lubricating oil.

  一种柴油发动机用润滑油添加剂，包括羧酸、羧酸的金属盐、羧酸的胺盐和羧酸酰胺中的一种或多种成分，每种成分的分子中都有一个或多个取代的氨基，其中取代的氨基羧酸化合物具有分散油中含水硫酸钙的功能；以及一种柴油发动机用润滑油组合物，包括这些柴油发动机用润滑油添加剂。将本发明的柴油发动机用润滑油添加剂和润滑油组合物添加到润滑油中后，掺入润滑油中的含水硫酸钙的分散功能得到显著改善，润滑油所拥有的上述沾污成分（如煤烟、淤泥等）在油中的分散功能得到增强，从而使其清净性得到显著改善。因此，可以降低金属基清洁剂的用量浓度，并延长润滑油的使用寿命。
• ONLINE FULLY CONTINUOUS FLOW PRODUCTION PROCESS FOR DIRECTLY PREPARING ORGANIC PEROXIDE FROM ALCOHOL OR ALKANE
  申请人：Shanghai Hybrid-Chem Technologies

  公开号：EP3666754A1

  公开（公告）日：2020-06-17

  A continuous flow production process for preparing organic peroxides directly from alcohols or alkanes takes very safe alcohols or alkanes as starting materials, and directly reacts to obtain designated peroxides. The production process is carried out in an integrated continuous flow reactor, and a safe starting source of alcohol or alkane is continuously added at the feed inlet of the integrated continuous flow reactor, and continuously provided with a designated peroxide at the discharge port of the integrated continuous flow reactor.

  一种直接从醇或烷烃制备有机过氧化物的连续流生产工艺，以非常安全的醇或烷烃为起始原料，直接反应得到指定的过氧化物。该生产工艺在一体化连续流反应器中进行，在一体化连续流反应器的进料口连续加入安全的醇或烷烃起始原料，并在一体化连续流反应器的出料口连续提供指定的过氧化物。
• Online continuous flow process for the preparation of organic peroxides direct from alcohols or alkanes
  申请人：Shanghai Hybrid-chem Technologies

  公开号：US10919849B2

  公开（公告）日：2021-02-16

  A continuous flow production process for preparing organic peroxides directly from alcohols or alkanes takes very safe alcohols or alkanes as starting materials, and directly reacts to obtain designated peroxides. The production process is carried out in an integrated continuous flow reactor, and a safe starting source of alcohol or alkane is continuously added at the feed inlet of the integrated continuous flow reactor, and continuously provided with a designated peroxide at the discharge port of the integrated continuous flow reactor.

  一种直接从醇或烷烃制备有机过氧化物的连续流生产工艺，以非常安全的醇或烷烃为起始原料，直接反应得到指定的过氧化物。该生产工艺在一体化连续流反应器中进行，在一体化连续流反应器的进料口连续加入安全的醇或烷烃起始原料，并在一体化连续流反应器的出料口连续提供指定的过氧化物。
• Soluble poly(aryl-oxadiazole) conjugated polymers
  申请人：——

  公开号：US20030023029A1

  公开（公告）日：2003-01-30

  This invention discloses a class of soluble poly(arylene-oxadiazole) polymers and copolymers comprising at least 20 repeat units, which may be the same or different, represented by the formula: 1 wherein Arom can be a fluorene group, an aromatic hydrocarbon ring, an aromatic C 2+ heterocyclic ring, or two aromatic rings linked by a single bond, ethenyl bond, or ethynyl bond. A process for preparing the polymers and copolymers by reacting dicarboxylic acids and hydrazine salt is provided. The polymers are useful in electroluminescent devices, photovoltaic cells, and diodes.

  本发明公开了一类由至少 20 个重复单元组成的可溶性聚（芳基烯-噁二唑）聚合物和共聚物，这些重复单元可以相同或不同，由式表示： 1 其中 Arom 可以是芴基、芳香烃环、芳香 C 2+； 杂环，或由单键、乙烯键或乙炔键连接的两个芳香环。提供了一种通过二羧酸和肼盐反应制备聚合物和共聚物的工艺。这些聚合物可用于电致发光装置、光伏电池和二极管。