2,2,2,4,4,4-Hexachlor-1,3-bis(m-tolyl)cyclodiphosphazan | 33893-21-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2,2,4,4,4-Hexachlor-1,3-bis(m-tolyl)cyclodiphosphazan
• 英文别名: 2,2,2,4,4,4-Hexachloro-1,3-bis(3-methylphenyl)-1,3,2lambda5,4lambda5-diazadiphosphetidine；2,2,2,4,4,4-hexachloro-1,3-bis(3-methylphenyl)-1,3,2λ5,4λ5-diazadiphosphetidine
• CAS: 33893-21-9
• 化学式: C₁₄H₁₄Cl₆N₂P₂
• 分子量: 484.944
• InChiKey: BPNDGQCSJSGULU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2,2,4,4,4-Hexachlor-1,3-bis(m-tolyl)cyclodiphosphazan 、 (Z)-2-Cyano-3-(2-nitro-phenyl)-acrylamide 以 乙腈 为溶剂， 反应 3.0h， 以63%的产率得到(Z)-2-Cyano-N-(2,4-dichloro-4-oxo-1,3-di-m-tolyl-2λ⁵,4λ⁵-[1,3,2,4]diazadiphosphetidin-2-ylidene)-3-(2-nitro-phenyl)-acrylamide
  参考文献：
  名称：

  NEW DERIVATIVES OF IMINOCYCLODIPHOSPHAZANE, CHLOROPHOSPHAZOBENZYLIDENECYANO-ETHYL KETONE AND DICINNAMOYLPHOSPHORTRIAMIDE

  摘要：

  [(Arylidenecyanoacetyl)imino]cyclodiphosphazanes 3,4-chloroanilinodichlorophosphazo (4-nitrobenzylidene) cyanomethyl ketone 5 [(4-substituted benzylidenecyanoacetamido) (4-substituted anilino)] chlorophosphazobenzylidenecyanomethyl ketone 6 and di[(p-nitro-alpha-cyanocinnamoyl) (p-tolyl)]phosphortiamide 7 were synthesized from the reaction between cyclodiphosphazanes 1 and arylidene-cyano-acetamides 2. The postulated mechanism for the formation of such products were rationalized. The structures assigned were supported by UV, IR, H-1 NMR and mass spectra.

  DOI：

  10.1080/10426509708043567

文献信息

• REACTIONS OF CYCLODIPHOSPH(V)AZANES WITH PHENOLIC ALDEHYDES AND HYDROXYCINNAMONITRILE DERIVATIVES
  作者：H. A. Emam、M. R. Selim、F. M. Al-masry、A. H. Bedair

  DOI：10.1080/10426509808035743

  日期：1998.9.1

  Abstract Cyclodiphosphazane derivatives incorporated formyl and acrylonitrile moieties 2a, b, 4, 5 are reported. Various (formylphenyl) N-arylphosphoramidic chloride esters 7a-e were also prepared. The postulated mechanisms for the formation of such compounds are rationalized. Its U.V., IR 1H-NMR and mass spectra were discussed.

  摘要 报告了掺入甲酰基和丙烯腈部分 2a、b、4、5 的环二磷氮烷衍生物。还制备了各种(甲酰基苯基)N-芳基氨基磷酰氯酯7a-e。形成这些化合物的假定机制被合理化。对其UV、IR 1H-NMR和质谱进行了讨论。
• IBRAHIM E. H.; LASHIEN A. S., INDIAN J. CHEM., 1979, B18, NO 4, 368-369
  作者：IBRAHIM E. H.、 LASHIEN A. S.

  DOI：——

  日期：——