2-hydroxymethyl-1-(p-vinylphenyl)cyclopropane | 321900-16-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-hydroxymethyl-1-(p-vinylphenyl)cyclopropane
• 英文别名: [2-(4-Ethenylphenyl)cyclopropyl]methanol；[2-(4-ethenylphenyl)cyclopropyl]methanol
• CAS: 321900-16-7
• 化学式: C₁₂H₁₄O
• 分子量: 174.243
• InChiKey: XFOODBWLTRIPQS-UHFFFAOYSA-N

物化性质

• 沸点：
  302.0±21.0 °C(Predicted)
• 密度：
  1.075±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-hydroxymethyl-1-(p-vinylphenyl)cyclopropane 在 吡啶 、 chromium(VI) oxide 作用下， 生成 2-formyl-1-(p-vinylphenyl)cyclopropane
  参考文献：
  名称：

  Synthesis of 2-formyl-1-(p-vinylphenyl)cyclopropane and its polymerization and copolymerization with styrene

  摘要：

  2-Formyl-1-(p-vinylphenyl)cyclopropane was prepared, and its homopolymerization and copolymerization with styrene were performed. The effect of the substituent on the monomer reactivity and the photosensitivity of the copolymer obtained were examined.

  DOI：

  10.1134/s1070427208040204
• 作为产物：
  描述：

  对二乙烯苯 在 lithium aluminium tetrahydride 、 copper(II) sulfate 作用下， 以 乙醚 为溶剂， 生成 2-hydroxymethyl-1-(p-vinylphenyl)cyclopropane
  参考文献：
  名称：

  2-氯甲基-1-（对乙烯基苯基）环丙烷的合成及其与苯乙烯的共聚

  摘要：

  合成了一种新的多官能单体2-氯甲基-1-（对乙烯基苯基）环丙烷，并与苯乙烯进行自由基共聚。确定共聚常数，并计算Alfrey–Price Q–e参数。研究了包含光敏基团（环丙烷环，氯化有机部分）的合成共聚物的光化学交联。该共聚物表现出较高的光敏性（54 cm 2 J –1），可以用作负性光刻胶的光敏基材。

  DOI：

  10.1134/s1070427218020209

文献信息

• Synthesis and polymerization of (p-Vinylphenyl)cyclopropylmethyl cinnamate
  作者：K. G. Guliev、A. M. Alieva、A. M. Guliev

  DOI：10.1134/s1070427213010165

  日期：2013.1

  (p-Vinylphenyl)cyclopropylmethyl cinnamate was synthesized, and its radical polymerization was performed. The synthesized polyfunctional polymers containing UV-sensitive > C=O, > C=C <, and a double dagger groups exhibit high photosensitivity. Photochemical cross-linking of the polymers was studied. The polymers synthesized can be used for preparing photosensitive materials.
• Photosensitivity of polymers based on epoxy-substituted vinylphenylcyclopropanes
  作者：K. G. Guliev、G. Z. Ponomareva、A. M. Guliev

  DOI：10.1134/s1070427206030323

  日期：2006.3

  The capability of polymers synthesized from new monomers, 2-glycidyloxymethyl- and 2-glycidyl-oxycarbonyl-1-(p-vinylphenyl)cyclopropane, to photochemical cross-linking was evaluated from variation of their solubility after UV irradiation. The dependence of the photosensitivity of the polymers on the structure of substituents was studied.
• Synthesis of 2-Chloromethyl-1-(p-vinylphenyl)cyclopropane and Its Copolymerization with Styrene
  作者：K. G. Guliyev、A. I. Sadygova、G. Z. Ponomareva、A. M. Aliyeva、Ts. D. Gulverdashvili、D. B. Tagiyev

  DOI：10.1134/s1070427218020209

  日期：2018.2

  A new polyfunctional monomer, 2-chloromethyl-1-(p-vinylphenyl)cyclopropane, was synthesized, and its radical copolymerization with styrene was performed. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The photochemical cross-linking of the synthesized copolymer containing photosensitive groups (cyclopropane ring, chlorinated organic moiety) was

  合成了一种新的多官能单体2-氯甲基-1-（对乙烯基苯基）环丙烷，并与苯乙烯进行自由基共聚。确定共聚常数，并计算Alfrey–Price Q–e参数。研究了包含光敏基团（环丙烷环，氯化有机部分）的合成共聚物的光化学交联。该共聚物表现出较高的光敏性（54 cm 2 J –1），可以用作负性光刻胶的光敏基材。
• Synthesis of 2-formyl-1-(p-vinylphenyl)cyclopropane and its polymerization and copolymerization with styrene
  作者：K. G. Guliev

  DOI：10.1134/s1070427208040204

  日期：2008.4

  2-Formyl-1-(p-vinylphenyl)cyclopropane was prepared, and its homopolymerization and copolymerization with styrene were performed. The effect of the substituent on the monomer reactivity and the photosensitivity of the copolymer obtained were examined.