copper(II) N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate | 1173912-56-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: copper(II) N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate
• CAS: 1173912-56-5；1019329-74-8
• 化学式: C₅₆H₆₂CuN₄O₁₄S₂
• 分子量: 1142.8
• InChiKey: WCGLISQPHGCTAS-DEBRICFFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  copper(II) N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate 、 水 、 sodium iodide 以 乙腈 为溶剂， 生成 2(sodium iodide)*[Cu(N-(4-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate)]*2H2O
  参考文献：
  名称：

  Copper N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate: Complexing and ion-selective properties

  摘要：

  Copper(II) chelate with N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate CuL2 and its coordination compounds with Li, Na, and K salts have been synthesized. Their IR spectra have been studied and assignment of the key vibration frequencies of CuL2 and complexes based on it. On the basis of spectral, thermogravimetric, and elemental analysis datasassumptions concerning the compound structure are made. The ion-selective properties of CuL2 are studied by potentiometry.

  DOI：

  10.1134/s0036023608060120
• 作为产物：
  描述：

  4'-[2-(tosylamino)benzylideneamino]-2,3-benzo-15-crown-5 、 copper diacetate 以 甲醇 为溶剂， 生成 copper(II) N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate
  参考文献：
  名称：

  Copper N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate: Complexing and ion-selective properties

  摘要：

  Copper(II) chelate with N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate CuL2 and its coordination compounds with Li, Na, and K salts have been synthesized. Their IR spectra have been studied and assignment of the key vibration frequencies of CuL2 and complexes based on it. On the basis of spectral, thermogravimetric, and elemental analysis datasassumptions concerning the compound structure are made. The ion-selective properties of CuL2 are studied by potentiometry.

  DOI：

  10.1134/s0036023608060120