di-μ-oxo-bis[N-trimethylene(2-imino-2-methyl-1-benzoylglyoxal-1-phenylhydrazonato)copper] | 189060-26-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di-μ-oxo-bis[N-trimethylene(2-imino-2-methyl-1-benzoylglyoxal-1-phenylhydrazonato)copper]
• 英文别名: dicopper;3-[[(3Z)-4-oxo-4-phenyl-3-phenylazanidyliminobutan-2-ylidene]amino]propan-1-olate
• CAS: 189060-26-2
• 化学式: C₃₈H₃₈Cu₂N₆O₄
• 分子量: 769.85
• InChiKey: VCPXSSSPEXBFII-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper diacetate 、 以 甲醇 为溶剂， 生成 di-μ-oxo-bis[N-trimethylene(2-imino-2-methyl-1-benzoylglyoxal-1-phenylhydrazonato)copper]
  参考文献：
  名称：

  摘要：

  The binuclear complexes of Cu2+ and Ni2+ with a new ligand system obtained through condensation of amino alcohols with 2-phenylhydrazone 1-phenylbutane-1,2,3-trione were synthesized. The compositions and structures of ligands and complexes were determined using elemental analysis, IR and NMR spectroscopy and magnetochemistry. The nickel complexes were found to be diamagnetic; in the copper complexes, substantial antiferromagnetic exchange interaction was observed (for Cu2+ complexes with n = 2 and 3, 2J is equal to -396 and -393 cm(-1), respectively). The structure of the exchange fragment[GRAPHICS]is discussed.

  DOI：

  10.1023/a:1025611727728

文献信息

• Panova, G. V.; Zakharov, A. N.; Zefirov, N. S., Russian Journal of General Chemistry, 1994, vol. 64, # 1.1, p. 16 - 19
  作者：Panova, G. V.、Zakharov, A. N.、Zefirov, N. S.

  DOI：——

  日期：——