4-tert-Butylpthalic acid N-potassiumimide | 127862-50-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4-tert-Butylpthalic acid N-potassiumimide
• 英文别名: 4-tert-butylphthalimide potassium salt；potassium 4-tert-butylphthalimide；potassium;5-tert-butylisoindol-2-ide-1,3-dione
• CAS: 127862-50-4
• 化学式: C₁₂H₁₂NO₂*K
• 分子量: 241.331
• InChiKey: ZPSREWLXTDUQBU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.34
• 重原子数：
  16.0
• 可旋转键数：
  0.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  48.24
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  4-tert-Butylpthalic acid N-potassiumimide 在 盐酸 、 1-溴代萘 、 zinc diacetate 作用下， 反应 8.0h， 生成 di(4-tert-butylbenzo)dibenzodiazaporphin
  参考文献：
  名称：

  New method for synthesis of the aza analogs of tetrabenzoporphin

  摘要：

  DOI：

  10.1007/bf00470696

文献信息

• Formation of tetrabenzoporphine skeleton by the reactions of phthalimide with zinc carbonates
  作者：Kunihiro Ichimura、Masako Sakuragi、Hisayuki Morii、Madoka Yasuike、Yasumasa Toba、Masaru Fukui、Osamu Ohno

  DOI：10.1016/s0020-1693(00)87937-2

  日期：1991.8

  The high temperature reactions of phthalimide potassium salt (PIK) with various zinc carbonates were carried out. The reaction of PIK with zinc acetate yielded tetrabenzoporphinato zinc (ZnTBP). Tetra-tert-butyltetrabenzoporphinato zinc (ZntBu4TBP), whose four tert-butyl substituents were positioned on the TBP periphery, was also prepared in a similar way using the 4-tert-butylphthalimide potassium salt (4-tBuPIK). These results were explained on the basis of the function of zinc acetate as the meso-methine carbon source of the TBP structure. The use of zinc phenylacetate instead of zinc acetate in the reaction of PIK led to the production of meso-phenyl substituted ZnTBPs, although they were different in the number of meso-phenyl substituent(s). The attempt to introduce alkyl residues at the meso-position(s) by the reaction of PIK in the presence of zinc alkylacetate having a long alkyl chain was not successful, except for the substitution of the methyl group using zinc propionate.
• Vorotnikov, A. M.; Kopranenkov, V. N.; Luk'yanets, E. A., Journal of general chemistry of the USSR, 1991, vol. 61, # 5.2, p. 1128 - 1130
  作者：Vorotnikov, A. M.、Kopranenkov, V. N.、Luk'yanets, E. A.

  DOI：——

  日期：——
• Vorotnikov, A. M.; Kopranenkov, V. N.; Luk'yanets, E. A., Journal of general chemistry of the USSR, 1991, vol. 61, p. 1128 - 1130
  作者：Vorotnikov, A. M.、Kopranenkov, V. N.、Luk'yanets, E. A.

  DOI：——

  日期：——