3-acetyl-5-nitro-4-(p-chlorophenyl)-4-penten-2-one | 649755-35-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-acetyl-5-nitro-4-(p-chlorophenyl)-4-penten-2-one
• 英文别名: 3-[1-(4-Chlorophenyl)-2-nitroethenyl]pentane-2,4-dione；3-[1-(4-chlorophenyl)-2-nitroethenyl]pentane-2,4-dione
• CAS: 649755-35-1
• 化学式: C₁₃H₁₂ClNO₄
• 分子量: 281.696
• InChiKey: ISUCMTJGLYMUHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  80
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-acetyl-5-nitro-4-(p-chlorophenyl)-4-penten-2-one 、 copper diacetate 以 乙醇 、 水 为溶剂， 以48%的产率得到3-acetyl-5-nitro-4-(p-chlorophenyl)-4-penten-2-one copper
  参考文献：
  名称：

  摘要：

  The reactions of alpha,beta-dibromo-beta-nitrostyrenes with acetylacetone and ethyl acetoacetate were studied. The structures of the products were determined by H-1 NMR, IR, and UV spectroscopy. The products derived from acetylacetone were converted into copper chelates.

  DOI：

  10.1023/a:1025652922798

文献信息

• ——
  作者：S. V. Makarenko、E. V. Trukhin、V. M. Berestovitskaya

  DOI：10.1023/a:1025652922798

  日期：——

  The reactions of alpha,beta-dibromo-beta-nitrostyrenes with acetylacetone and ethyl acetoacetate were studied. The structures of the products were determined by H-1 NMR, IR, and UV spectroscopy. The products derived from acetylacetone were converted into copper chelates.