2-(2-phenyl-4H-chromen-4-ylidene)malononitrile | 15058-06-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 2-(2-phenyl-4H-chromen-4-ylidene)malononitrile
• 英文别名: (2-phenyl-chromen-4-ylidene)-malononitrile；(2-Phenyl-chromen-4-yliden)-malononitril；4-Dicyanomethylen-2-phenyl-4H-benzopyran；4-Dicyanomethylen-2-phenyl-4H-benzopyran；4--flaven；Flavanyliden-malondinitril；4-Dicyanomethylene-2-phenyl-4h-benzopyran；2-(2-phenylchromen-4-ylidene)propanedinitrile
• CAS: 15058-06-7
• 化学式: C₁₈H₁₀N₂O
• mdl: MFCD02252580
• 分子量: 270.29
• InChiKey: TXSUHQPUMYIQIH-UHFFFAOYSA-N

物化性质

• 熔点：
  179-180 °C(Solv: acetic acid (64-19-7))
• 沸点：
  436.0±45.0 °C(Predicted)
• 密度：
  1.278±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(2-phenyl-4H-chromen-4-ylidene)malononitrile 在 盐酸 、 ammonium hydroxide 作用下， 以 吡啶 、 溶剂黄146 为溶剂， 生成 (4-amino-2-phenyl-chromeno[3,4-c]pyridin-5-ylidene)-phenyl-amine
  参考文献：
  名称：

  Reynolds,G.A. et al., Journal of Heterocyclic Chemistry, 1970, vol. 7, p. 1061 - 1069

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 potassium permanganate 、 N,N-二甲基甲酰胺 作用下， 生成 2-(2-phenyl-4H-chromen-4-ylidene)malononitrile
  参考文献：
  名称：

  Kroehnke; Dickore, Chemische Berichte, 1959, vol. 92, p. 46,58

  摘要：

  DOI：

文献信息

• FeCl₃-promoted tandem 1,4-conjugate addition/6-<i>endo-dig</i> cyclization/oxidation of propargylamines and benzoylacetonitriles/malononitriles: direct access to functionalized 2-aryl-4<i>H</i>-chromenes
  作者：Xinwei He、Hui Wang、Xiaoting Cai、Qianqian Li、Jiajia Tao、Yongjia Shang

  DOI：10.1039/c8ob01927d

  日期：——

  An efficient and concise procedure has been developed for the synthesis of functionalized 2-aryl-4H-chromenes based on a tandem reaction of propargylamines and benzoylacetonitriles/malononitriles in the presence of FeCl3 as an environmentally friendly promoter. This reaction involves a highly efficient tandem sequence consisting of 1,4-conjugate addition, 6-endo-dig cyclization, and oxidation. This

  一种有效和简洁的方法已经为官能化的2-芳基4的合成已经开发ħ -chromenes基于炔丙胺和benzoylacetonitriles的串联反应/丙二腈在的FeCl存在3作为环保型启动子。该反应涉及由1，4-缀合物加成，6-内-挖-环化和氧化组成的高效串联序列。该方案可耐受多种官能团，从而为制造2-芳基-4 H-色烯骨架提供了一种实用而有效的方法。
• Elagamey, Abdel Ghani A.; El-Taweel, Fathy M. A.; Sowellim, Salah Z. A., Collection of Czechoslovak Chemical Communications, 1990, vol. 55, # 2, p. 524 - 534
  作者：Elagamey, Abdel Ghani A.、El-Taweel, Fathy M. A.、Sowellim, Salah Z. A.、Sofan, Mamdouh A.、Elnagdi, Mohamed H.

  DOI：——

  日期：——
• van Allan,J.A. et al., Journal of Heterocyclic Chemistry, 1970, vol. 7, p. 1363 - 1368
  作者：van Allan,J.A. et al.

  DOI：——

  日期：——
• ELAGAMEY, ABDEL GHANI A.;EL-TAWEEL, FATHY M. A.;SOWELLIM, SALAH Z. A.;SOF+, COLLECT. CZECHOSL. CHEM. COMMUN., 55,(1990) N, C. 524-534
  作者：ELAGAMEY, ABDEL GHANI A.、EL-TAWEEL, FATHY M. A.、SOWELLIM, SALAH Z. A.、SOF+

  DOI：——

  日期：——
• Optical recording material and optical recording medium
  申请人：Miyazawa Takashi

  公开号：US20070184386A1

  公开（公告）日：2007-08-09

  The present invention provides a high level optical recording material which is capable of recording and reading by a blue laser with a short wavelength. An optical recording material comprises an organic dye compound A whose absorption maximum wavelength (λmax) is not less than 340 nm and not more than 440 nm and a metal-complex compound B whose absorption maximum wavelength (λmax) is not less than 500 nm and not more than 900 nm, the content of the organic dye compound A is higher than the content of the metal-complex compound B, and light resistance x determined by a predetermined method is not less than 30%.