N,N'-2,5-cyclohexadiene-1,4-diylidenebis | 16720-35-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-2,5-cyclohexadiene-1,4-diylidenebis
• 英文别名: N,N′-(cyclohexa-2,5-diene-1,4-diylidene)dibenzamide；N,N'-2,5-cyclohexadiene-1,4-diylidenebis(benzamide)；p-Benzoquinonedibenzimide；N,N'-cyclohexa-2,5-diene-1,4-diylidene-bis-benzamide；N,N'-Cyclohexa-2,5-dien-1,4-diyliden-bis-benzamid；N.N'-Dibenzoyl-p-chinondiimin；N,N'-(cyclohexa-2,5-diene-1,4-diylidene)di-benzamide；N-(4-benzoyliminocyclohexa-2,5-dien-1-ylidene)benzamide
• CAS: 16720-35-7
• 化学式: C₂₀H₁₄N₂O₂
• 分子量: 314.343
• InChiKey: UCLANOULAXIXOO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-2,5-cyclohexadiene-1,4-diylidenebis 在 氯仿 、 水 作用下， 生成 N,N'-(4'-dimethylamino-biphenyl-2,5-diyl)-bis-benzamide
  参考文献：
  名称：

  Quinone Imides. XLV. Structures of Aromatic Amine Adducts of p-Benzoquinonedibenzimide^*

  摘要：

  DOI：

  10.1021/jo01362a001

文献信息

• The three component reaction involving isocyanides, dimethyl acetylenedicarboxylate and quinoneimides: a facile synthesis of spirofused γ-iminolactams
  作者：Vijay Nair、R. Dhanya、S. Viji

  DOI：10.1016/j.tet.2005.04.008

  日期：2005.6

  The three component reaction of the zwitterion generated from dimethyl acetylenedicarboxylate and isocyanides with various quinoneimides is described. The reaction afforded the corresponding γ-spiroiminolactams in good yields.

  描述了由乙炔二羧酸二甲酯和异氰酸酯产生的两性离子与各种醌酰亚胺的三组分反应。该反应以良好的产率提供了相应的γ-螺氨基内酰胺。
• Quinone Imides. II. p-Quinone Diacyl and Diaroylimides
  作者：Roger Adams、John L. Anderson

  DOI：10.1021/ja01167a098

  日期：1950.11
• Reaction of N,N′-disubstituted 1,4-benzoquinone diimines with sodium arenesulfinates
  作者：S. A. Konovalova、A. P. Avdeenko、A. A. Santalova、G. V. Palamarchuk、V. V. D’yakonenko、O. V. Shishkin

  DOI：10.1134/s1070428015010078

  日期：2015.1

  Radical anion 1,6-addition path in the reactions of N,N'-disubstituted 1,4-benzoquinone diimines with sodium arenesulfinates is favored by increase of the electron-donating power of the substituent in the para position of arenesulfinate ion and redox potential of the initial 1,4-benzoquinone diimine.
• Quinone Imides. XIV. Addition of Hydrogen Chloride to p-Quinonedibenzimides and Related Compounds
  作者：Roger Adams、D. S. Acker

  DOI：10.1021/ja01132a024

  日期：1952.6
• Quinone Imides. XLVI. The Addition of Heterocyclic Active Methylene Compounds to p Benzoquinone Diimides
  作者：Roger Adams、Leslie M. Werbel、M. D. Nair

  DOI：10.1021/ja01546a027

  日期：1958.7