申请人:HITACHI, LTD.
公开号:EP0488275A2
公开(公告)日:1992-06-03
A superconducting magnet coil contains a coil of superconducting wire (2) and a cured product (3) of a curable resin composition with which the coil has been impregnated, the cured product having a thermal shrinkage factor of 1.5-0.3%, preferably 1.0-0.3%, when cooled from the glass transition temperature to 4.2 K, a bend-breaking strain of 2.9-3.9%, preferably 3.2-3.9%, at 4.2 K and a modulus of 500-1,000 kg/mm² at 4.2 K, or undergoing a thermal stress of 0-10 kg/mm² when cooled from the glass transition temperature to 4.2 K and resisting to quench during superconducting operation.
It is produced by winding a superconducting wire (2) to form a coil; impregnating the coil with a curable resin composition of low viscosity which contains for example at least one epoxy resin selected from the group consisting of diglycidyl ether of bisphenol A, diglycidyl ether of bisphenol F and diglycidyl ether of bisphenol AF, all having a number-average molecular weight of 350-1,000, a flexibilizer and a curing catalyst, to obtain a curable-resin composition-impregnated coil; and heating the curable-resin-composition-impregnated coil to cure the composition.
超导磁体线圈包含一个超导线材线圈(2)和一个浸渍了线圈的可固化树脂组合物的固化物(3),该固化物从玻璃转化温度冷却到4.2 K时的热收缩系数为1.5-0.3%,最好为1.0-0.3%,在4.2 K时的弯曲应变为2.9-3.9%,最好为3.2-3.9%,在4.2 K时的模量为500-1000 kg/mm²。2 K时的热收缩系数为1.5-0.3%,最好为1.0-0.3%;在4.2 K时的弯曲断裂应变为2.9-3.9%,最好为3.2-3.9%;在4.2 K时的模量为500-1,000 kg/mm²;或在从玻璃转化温度冷却到4.2 K时的热应力为0-10 kg/mm²,并且在超导运行期间不易淬火。
其生产方法是将超导线 (2) 绕成线圈;用低粘度的可固化树脂组合物浸渍线圈,该树脂组合物至少含有一种环氧树脂,该环氧树脂选自由双酚 A 的二缩水甘油醚、双酚 F 的二缩水甘油醚和双酚 AF 的二缩水甘油醚组成的组,它们的数均分子量都在 350-1,000 之间,还含有柔顺剂和固化催化剂,从而得到浸渍了可固化树脂组合物的线圈;加热可固化树脂组合物浸渍线圈以固化组合物。