bis(4-phenylbuthyl)ether | 4973-42-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(4-phenylbuthyl)ether
• 英文别名: Bis-<4-phenyl-butyl>-aether；Bis-(4-phenyl-butyl)-aether；4-(4-Phenylbutoxy)butylbenzene
• CAS: 4973-42-6
• 化学式: C₂₀H₂₆O
• 分子量: 282.426
• InChiKey: LXIQJYAYQYNRCS-UHFFFAOYSA-N

物化性质

• 沸点：
  100 °C(Press: 0.2 Torr)
• 密度：
  0.979±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  21
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-苯基丁酸 在 三乙基硅烷 、 indium(III) bromide 、 硫酸 作用下， 以 氯仿 为溶剂， 反应 4.0h， 以78%的产率得到bis(4-phenylbuthyl)ether
  参考文献：
  名称：

  羧酸的铟催化还原酯化：酯和对称醚的顺序制备

  摘要：

  描述了通过涉及InBr 3和硫酸的组合催化剂对两种羧酸进行空前的还原二聚以产生酯衍生物的方法。还证明了在同一罐中通过氢化硅烷将酯进行铟催化的脱氧，从而将原位形成的酯顺序转化为对称的醚。

  DOI：

  10.1002/adsc.201100524

文献信息

• Direct Etherification of Alkyl Halides by Sodium Hydride in the Presence of <i>N</i>,<i>N</i>-Dimethylformamide
  作者：Young Jung、Cheng Jin、Ho Lee、Sang Lee、In Kim

  DOI：10.1055/s-2007-991068

  日期：——

  A novel synthetic method for the preparation of various alkyl ethers is described. The reaction between alkyl halides and sodium hydride in the presence of N,N-dimethylformamide afforded the corresponding symmetrical and unsymmetrical ethers in high yields. A reaction mechanism for etherification is also proposed.

  本文描述了一种新颖的合成各种烷基醚的方法。在N,N-二甲基甲酰胺存在下，烷基卤与氢化钠反应，高效地合成了相应的对称性和非对称性醚。同时，还提出了一种醚化反应的机理。
• UV curable hardcoat compositions and processes
  申请人：RED SPOT PAINT & VARNISH CO., INC.

  公开号：EP0864618A2

  公开（公告）日：1998-09-16

  Described is a preferred UV curable coating composition comprising (exclusive of any solvent present): (a) about 5% to 90% by weight of an acrylated aliphatic urethane having a molecular weight of about 500 to 2000 and formed by the reaction of a multifunctional acrylate with a molecular weight of about 90 to 500 and containing at least three polymerizable unsaturated groups per molecule, with an aliphatic urethane based on a polymer of allyl carbomonocycle diisocyanate with alkanepolyol polyacrylates; (b) about 5% to 30% by weight of a multifunctional acrylate having a molecular weight of about 170 to 1000 and containing at least two polymerizable unsaturated groups per molecule; and (c) a photopolymerization initiator and/or sensitizer. Also described are preferred processes and coated articles involving the preferred coating compositions.

  描述了一种优选的紫外线固化涂料组合物，该组合物包括（不包括任何存在的溶剂）：(a) 约 5%至 90%（按重量计）的丙烯酸脂族聚氨酯，其分子量约为 500 至 2000，由分子量约为 90 至 500、每分子至少含有三个可聚合的不饱和基团的多功能丙烯酸酯与基于碳单胞二异氰酸酯烯丙基与烷基多元醇聚丙烯酸酯的聚合物的脂族聚氨酯反应形成；(b) 约 5%至 30%（按重量计）的多功能丙烯酸酯，其分子量约为 170 至 1000，且每个分子至少含有两个可聚合的不饱和基团；以及 (c) 光聚合引发剂和/或敏化剂。此外，还描述了涉及优选涂层组合物的优选工艺和涂层物品。
• UV Curable blend compositions and processes
  申请人：RED SPOT PAINT & VARNISH CO., INC.

  公开号：EP0888885A2

  公开（公告）日：1999-01-07

  An ultraviolet curable blend composition comprising (exclusive of any solvent present): (a) about 35% to about 65% by weight of a first acrylated aliphatic urethane having a molecular weight of between about 500 and 2000 and formed by the reaction of (i) a first multifunctional acrylate with a molecular weight of between about 190 and 500 and containing at least three polymerizable unsaturated groups per molecule, with (ii) an aliphatic urethane based on a polymer of alkyl carbomonocycle diisocyanate with alkanepolyol polyacrylates; (b) about 5% to about 25% by weight of a second acrylated aliphatic urethane having a molecular weight of about 1200 to about 2600 and formed by the reaction of a second multifunctional acrylate with a molecular weight of about 110 to about 500 with an aliphatic urethane based on a polyether and having a molecular weight of about 800 to about 2200; (c) about 10% to about 55% by weight of a third multifunctional acrylate having a molecular weight of between about 170 and about 1000 and containing at least two polymerizable unsaturated groups per molecule; and (d) a photopolymerization initiator and/or sensitizer. Also described are preferred processes and coated articles involving preferred compositions.

  一种可紫外线固化的混合物组合物，包括（不包括任何存在的溶剂）(a) 约 35%至约 65%（按重量计）的第一丙烯酸脂族聚氨酯，其分子量在约 500 至 2000 之间，由以下物质反应形成：(i) 第一多功能丙烯酸酯，其分子量在约 190 至 500 之间，每个分子至少含有三个可聚合的不饱和基团；(ii) 基于烷基碳单环二异氰酸酯与烷基多元醇聚丙烯酸酯聚合物的脂族聚氨酯；(b) 约 5%至约 25%（按重量计）的第二种丙烯酸脂族聚氨酯，其分子量约为 1200 至约 2600，由分子量约为 110 至约 500 的第二种多功能丙烯酸酯与基于聚醚且分子量约为 800 至约 2200 的脂族聚氨酯反应形成；(c) 第三种多功能丙烯酸酯约 10%至约 55%（按重量计），其分子量在约 170 至约 1000 之间，每个分子至少含有两个可聚合的不饱和基团；以及 (d) 光聚合引发剂和/或敏化剂。此外，还介绍了涉及优选组合物的优选工艺和涂覆制品。
• UV curable coating compositions and uses thereof
  申请人：General Electric Company

  公开号：EP1857509A1

  公开（公告）日：2007-11-21

  The present invention is directed to curable acrylate coating compositions and coated articles resulting therefrom. The curable acrylate coating composition comprises at least two polyfunctional acrylate derivatives, at least one photoinitiator and at least one nanoscale filler.

  本发明涉及可固化丙烯酸酯涂料组合物及其制成的涂层物品。可固化丙烯酸酯涂料组合物包括至少两种多官能丙烯酸酯衍生物、至少一种光引发剂和至少一种纳米级填料。
• PROCESSES FOR PRODUCTION OF GROUP II METAL SULFIDE PHOSPHOR PRECURSORS AND PHOSPHORS
  申请人：Kuraray Co., Ltd.

  公开号：EP2216295A1

  公开（公告）日：2010-08-11

  The process of the invention is provided to achieve uniform doping of an activator metal into phosphor particles and to improve efficiency of utlization of a metal element to be used in the production of a Group II metal sulfide phosphor and a precursor thereof. Specifically, the object of the invention is achieved by a process for producing a Group II metal sulfide phosphor precursor, comprising adding to an organic solvent an aqueous solution containing at least one of a Group II element compound, a sulfurizing agent, and a compound containing any of copper, silver, manganese, gold, and rare-earth elements to obtain a reaction mixture, heating the reaction mixture to produce an azeotrope of the water and the organic solvent, and removing the water from the reaction mixture to produce a desired Group II metal sulfide in the reaction mixture, wherein the removal of the water from the reaction mixture is carried out by recovering only the water condensed from a vapor produced by the azeotropic distillation.

  本发明提供的工艺可实现在荧光粉颗粒中均匀掺入活化剂金属，并提高用于生产第 II 族金属硫化物荧光粉及其前体的金属元素的利用效率。具体地说，本发明的目的是通过一种生产第二族金属硫化物荧光粉前体的工艺来实现的，该工艺包括向有机溶剂中加入含有第二族元素化合物、硫化剂和含有铜、银、锰、金和稀土元素中任何一种的化合物的水溶液，以获得反应混合物、加热反应混合物以产生水和有机溶剂的共沸物，从反应混合物中除去水以在反应混合物中生成所需的第二族金属硫化物，其中从反应混合物中除去水的方法是仅回收共沸蒸馏产生的蒸汽中冷凝的水。