bis(N,N'-bis(2-oxybenzylidene)-2-oxyphenylmethanediamine)tetraaquadilanthanum(III) | 767295-55-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(N,N'-bis(2-oxybenzylidene)-2-oxyphenylmethanediamine)tetraaquadilanthanum(III)
• 英文别名: lanthanum(3+);2-[(E)-[(2-oxidophenyl)-[(E)-(2-oxidophenyl)methylideneamino]methyl]iminomethyl]phenolate;tetrahydrate
• CAS: 767295-55-6
• 化学式: C₄₂H₃₈La₂N₄O₁₀
• 分子量: 1036.6
• InChiKey: HJNGFWCMHHXTCX-ITXMXYLLSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(N,N'-bis(2-oxybenzylidene)-2-oxyphenylmethanediamine)tetraaquadilanthanum(III) 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Lanthanide Complexes with N,N′-Bis(2- hydroxybenzylidene)-2-hydroxyphenylmethanediamine

  摘要：

  Complexes of lanthanides with N,N'-bis(2-hydroxybenzylidene)-2-hydroxyphenylmethanediamine (HP were synthesized and investigated by the elemental, IR, magnetochemical, and thermogravimetric methods. Using the data obtained, they were found to have compositions Ln(2)L(2) . nH(2)O and La2L2 . MCl2 . 4H(2)O (Ln = La3+, Pr3+, Nd3+, Dy3+, Er3+; M = Cu2+, Co2+, Ni2+; n = 4, 6). Suggestions on their structures were made. In the interval of 20-140degreesC, these complexes were shown to be high-resistance semiconductors.

  DOI：

  10.1023/b:ruco.0000022803.79964.5f
• 作为产物：
  描述：

  1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,4-diene 、 氯化镧水合物 在 triethylamine 作用下， 以 甲醇 为溶剂， 以72%的产率得到bis(N,N'-bis(2-oxybenzylidene)-2-oxyphenylmethanediamine)tetraaquadilanthanum(III)
  参考文献：
  名称：

  Lanthanide Complexes with N,N′-Bis(2- hydroxybenzylidene)-2-hydroxyphenylmethanediamine

  摘要：

  Complexes of lanthanides with N,N'-bis(2-hydroxybenzylidene)-2-hydroxyphenylmethanediamine (HP were synthesized and investigated by the elemental, IR, magnetochemical, and thermogravimetric methods. Using the data obtained, they were found to have compositions Ln(2)L(2) . nH(2)O and La2L2 . MCl2 . 4H(2)O (Ln = La3+, Pr3+, Nd3+, Dy3+, Er3+; M = Cu2+, Co2+, Ni2+; n = 4, 6). Suggestions on their structures were made. In the interval of 20-140degreesC, these complexes were shown to be high-resistance semiconductors.

  DOI：

  10.1023/b:ruco.0000022803.79964.5f