10-(4-tolyl) phenothiazine-S,S-dioxide | 16682-30-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 10-(4-tolyl) phenothiazine-S,S-dioxide
• 英文别名: 10-p-Tolylphenothiazin-5,5-dioxid；10-p-tolyl-10H-phenothiazine 5,5-dioxide；10-(4-Methylphenyl)phenothiazine 5,5-dioxide
• CAS: 16682-30-7
• 化学式: C₁₉H₁₅NO₂S
• 分子量: 321.4
• InChiKey: ZFIKHMPKEXFIMK-UHFFFAOYSA-N

物化性质

• 沸点：
  517.3±30.0 °C(Predicted)
• 密度：
  1.316±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  10-(p-tolyl)-10H-phenothiazine 在 双氧水 、 溶剂黄146 作用下， 以 二氯甲烷 为溶剂， 反应 16.0h， 以72%的产率得到10-(4-tolyl) phenothiazine-S,S-dioxide
  参考文献：
  名称：

  基于吩噻嗪衍生物的室温磷光分子及其制备 方法和应用

  摘要：

  本发明公开了一种基于吩噻嗪衍生物的室温磷光分子及其制备方法和应用。本发明基于吩噻嗪衍生物的室温磷光分子具有式(I)所示的结构，其中，R为‑OCH3、‑CH3、‑H、‑Br、‑Cl、‑F或‑CF3。本发明主要是以吩噻嗪为核通过碳氮偶联反应将苯环衍生物与之相连，再将其氧化，得到目标产物。该类化合物的固体粉末均有室温磷光现象，且它们的最长寿命达398ms，因此可用作防伪材料使用，且本发明的制备方法反应条件温和，产率较高。

  公开号：

  CN109206384B

文献信息

• Transition-Metal-Free Synthesis of <i>N-</i>Arylphenothiazines through an <i>N</i>- and <i>S</i>-Arylation Sequence
  作者：Tsubasa Matsuzawa、Takamitsu Hosoya、Suguru Yoshida

  DOI：10.1021/acs.orglett.1c00515

  日期：2021.3.19

  transition-metal-free conditions is disclosed. An N- and S-arylation sequence of o-sulfanylanilines enabled us to synthesize a wide variety of N-arylphenothiazines. In particular, one-pot synthesis of N-arylphenothiazines was accomplished from easily available modules through preparation of o-sulfanylanilines by thioamination of aryne intermediates and following N- and S-arylation sequence.

  公开了在无过渡金属的条件下由邻-硫烷基苯胺合成N-芳基吩噻嗪的有效方法。邻硫烷基苯胺的N-和S-芳基化序列使我们能够合成各种N-芳基吩噻嗪。特别是，N-芳基吩噻嗪的一锅法合成是通过容易地获得的模块，通过对芳烃中间体进行硫胺化并按照N-和S-芳基化顺序制备邻-硫烷基苯胺来完成的。
• Light emitting material, manufacture method thereof and organic light emitting diode using the light emitting material
  申请人：Shenzhen China Star Optoelectronics Technology Co., Ltd.

  公开号：US10208013B2

  公开（公告）日：2019-02-19

  The present invention provides a light emitting material, a manufacture method thereof and an organic light emitting diode using the light emitting material. The structure is unitary, and the formula weight is determined, and the better solubility and film formation are provided, and the thin film status is stable; it possesses a very high decomposition temperature and a lower sublimation temperature, and is easy to sublime to be light emitting material of high purity, and can be applied for small molecule organic light emitting diode. In the manufacture method of the light emitting material according to the present invention, m-bromothiophenol and 4-Bromo-2-fluorobenzonitrile are employed to be starting materials, and the intermediate of the light emitting material is obtained with a series of simple reactions, and finally, the light emitting material is obtained with Ullmann reaction or Suzuki reaction, and the steps are simple and the production is high.

  本发明提供了一种发光材料、其制造方法以及使用该发光材料的有机发光二极管。本发明提供了一种发光材料及其制造方法和一种使用该发光材料的有机发光二极管，该发光材料结构单一，配方重量确定，具有较好的溶解性和成膜性，薄膜状态稳定；具有很高的分解温度和较低的升华温度，易于升华成为高纯度的发光材料，可应用于小分子有机发光二极管。在本发明的发光材料的制造方法中，采用间溴苯硫酚和4-溴-2-氟苯腈作为起始原料，通过一系列简单的反应得到发光材料的中间体，最后通过乌尔曼反应或铃木反应得到发光材料，步骤简单，产量高。
• Light emitting material, manufacturing method thereof and organic light emitting diode using the light emitting material
  申请人：TCL China Star Optoelectronics Technology Co., Ltd.

  公开号：US10626327B2

  公开（公告）日：2020-04-21

  An organic light emitting diode includes a light emitting layer that includes a light emitting material of the constitutional formula The structure is unitary, and the formula weight is determined, and the better solubility and film formation are provided, and the thin film status is stable; it possesses a very high decomposition temperature and a lower sublimation temperature, and is easy to sublime to be light emitting material of high purity, and can be applied for small molecule organic light emitting diode. In the method for manufacturing the light emitting material, p-bromothiophenol and 4-Bromo-2-fluorobenzonitrile are employed to be starting materials, and an intermediate of the light emitting material is obtained with a series of simple reactions, and finally, the light emitting material is obtained with Ullmann reaction or Suzuki reaction, and these steps are simple and the production is high.

  一种有机发光二极管包括一个发光层，该发光层包括一种发光材料，其结构式为 结构单一，式重确定，具有较好的溶解性和成膜性，薄膜状态稳定；具有很高的分解温度和较低的升华温度，易于升华成为高纯度的发光材料，可应用于小分子有机发光二极管。在发光材料的制造方法中，采用对溴苯硫酚和4-溴-2-氟苯腈作为起始原料，通过一系列简单的反应得到发光材料的中间体，最后通过乌尔曼反应或铃木反应得到发光材料，步骤简单，产量高。
• LIGHT EMITTING MATERIAL, MANUFACTURE METHOD THEREOF AND ORGANIC LIGHT EMITTING DIODE USING THE LIGHT EMITTING MATERIAL
  申请人：Shenzhen China Star Optoelectronics Technology Co., Ltd.

  公开号：US20180170894A1

  公开（公告）日：2018-06-21

  The present invention provides a light emitting material, a manufacture method thereof and an organic light emitting diode using the light emitting material. The structure is unitary, and the formula weight is determined, and the better solubility and film formation are provided, and the thin film status is stable; it possesses a very high decomposition temperature and a lower sublimation temperature, and is easy to sublime to be light emitting material of high purity, and can be applied for small molecule organic light emitting diode. In the manufacture method of the light emitting material according to the present invention, p-bromophenol and 4-Bromo-2-fluorobenzonitrile are employed to be starting materials, and the intermediate of the light emitting material is obtained with a series of simple reactions, and finally, the light emitting material is obtained with Ullmann reaction or Suzuki reaction, and the steps are simple and the production is high.