4-isopropyl-3-methyl-4'-(trifluoromethyl)-1,1'-biphenyl | 1314118-55-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-isopropyl-3-methyl-4'-(trifluoromethyl)-1,1'-biphenyl
• 英文别名: 2-Methyl-1-propan-2-yl-4-[4-(trifluoromethyl)phenyl]benzene
• CAS: 1314118-55-2
• 化学式: C₁₇H₁₇F₃
• 分子量: 278.317
• InChiKey: HODQRYZXHSGGNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-甲基-4-异丙基苯酚 在 potassium phosphate 、 chloro(2-dicyclohexylphosphino-2‘,4’,6’-triisopropyl-1,1‘-biphenyl)[2-(2’-amino-1,1‘-biphenyl)]palladium(II) 、 四丁基溴化铵 、 三乙胺 作用下， 以 N-甲基吡咯烷酮 、 水 、 甲苯 为溶剂， 生成 4-isopropyl-3-methyl-4'-(trifluoromethyl)-1,1'-biphenyl
  参考文献：
  名称：

  流动中的Suzuki–Miyaura交叉偶联反应：通过微流体萃取实现的多步合成

  摘要：

  持续成功：通过使用高效的微流体萃取操作和填充床反应器，可以实现从酚类开始的连续流动的Suzuki-Miyaura交叉偶联反应。以优异的产率获得了各种联芳基（14个实施例）。TBAB =卜4 Ñ +溴- 。

  DOI：

  10.1002/anie.201101480

文献信息

• Novel organic electroluminescent compounds and organic electroluminescent device using the same
  申请人：Gracel Display Inc.

  公开号：EP2098532A1

  公开（公告）日：2009-09-09

  The present invention relates to novel organic electroluminescent compounds exhibiting high luminous efficiency, and organic electroluminescent devices comprising the same. The organic electroluminescent compounds according to the invention are characterized in that they are represented by Chemical Formula (1):

  本发明涉及一种表现出高发光效率的新型有机电致发光化合物，以及包括它们的有机电致发光装置。本发明的有机电致发光化合物的特点在于它们由化学式（1）所表示：
• Novel compounds for electronic material and organic electronic device using the same
  申请人：Gracel Display Inc.

  公开号：EP2182002A1

  公开（公告）日：2010-05-05

  Provided are novel compounds for electronic material of high efficiency, and organic electronic devices and organic solar cells comprising the same. Specifically, the novel compounds for electronic material according to the invention are characterized in that they are represented by Chemical Formula (1): wherein, R1 and R2, or R3 and R4 are linked via (C3-C12)alkylene or (C3-C12)alkenylene to form at least one fused ring(s); provided that, if the ring formed from R3 and R4 of by linkage via alkylene or alkenylene is benzene, the ring formed from R7 and R8 of by linkage via alkylene or alkenylene is not benzene.

  本发明提供了用于高效电子材料的新型化合物，以及由其构成的有机电子器件和有机太阳能电池。具体地说，根据本发明的新型电子材料化合物的特征在于它们由化学式（1）表示： 其中，R1 和 R2 或 R3 和 R4 通过(C3-C12)亚烷基或(C3-C12)亚烯基连接，形成至少一个（多个）融合环；条件是，如果 R3 和 R4 所形成的环为(C3-C12) 的 R3 和 R4 通过亚烷基或烯基连接形成的环为苯，则 的 R7 和 R8 所形成的环不是苯。
• Novel red electroluminescent compounds and organic electroluminescent device using the same
  申请人：Kim Jin Ho

  公开号：US20090179555A1

  公开（公告）日：2009-07-16

  The present invention relates to novel organic electroluminescent compounds exhibiting high luminous efficiency, and organic electroluminescent devices comprising the same. The organic electroluminescent compounds according to the invention are represented by Chemical Formula (1):
• Novel red electroluminescent compounds and organi electroluminescent device using the same
  申请人：Kim Jin Ho

  公开号：US20090174316A1

  公开（公告）日：2009-07-09

  The present invention relates to novel red phosphorescent compounds exhibiting high luminous efficiency, and organic electroluminescent devices comprising the same. The red phosphorescent compounds according to the invention are represented by Chemical Formula (1):
• Suzuki-Miyaura Cross-Coupling Reactions in Flow: Multistep Synthesis Enabled by a Microfluidic Extraction
  作者：Timothy Noël、Simon Kuhn、Andrew J. Musacchio、Klavs F. Jensen、Stephen L. Buchwald

  DOI：10.1002/anie.201101480

  日期：2011.6.20

  Continuous success: A continuous‐flow Suzuki–Miyaura cross‐coupling reaction starting from phenols was made possible through use of an efficient microfluidic extraction operation and a packed‐bed reactor. Various biaryls were obtained in excellent yield (14 examples). TBAB=Bu4N+Br−.

  持续成功：通过使用高效的微流体萃取操作和填充床反应器，可以实现从酚类开始的连续流动的Suzuki-Miyaura交叉偶联反应。以优异的产率获得了各种联芳基（14个实施例）。TBAB =卜4 Ñ +溴- 。