9-undecynylamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 9-undecynylamine
• 英文别名: Undec-9-yn-1-amine
• 化学式: C₁₁H₂₁N
• 分子量: 167.294
• InChiKey: KJQYPVWERCKXKP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-undecynylamine 在 4-二甲氨基吡啶 、 lithium aluminium tetrahydride 、 [Re(≡CCH₂Ph)(^4-CF3-PhPO)₂(py)] 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 、 三乙胺 作用下， 以 四氢呋喃 、 二氯甲烷 、 甲苯 为溶剂， 反应 52.17h， 生成 1-tosylazacyclononadec-10-yne
  参考文献：
  名称：

  Alkyne Metathesis with d2 Re(V) Alkylidyne Complexes Supported by Phosphino-Phenolates: Ligand Effect on Catalytic Activity and Applications in Ring-Closing Alkyne Metathesis,d2 Re(V) 炔烃复合物与膦基酚盐支持的炔烃复分解：配体对催化活性的影响及其在闭环炔烃复分解中的应用

  摘要：

  A family of d2 Re(V) alkylidyne complexes bearing two decorated phosphino-phenolates (POs) and a labile pyridine ligand were prepared that can efficiently promote alkyne metathesis reactions in toluene. The relative activity of these complexes varies with the PO ligands. Complexes with an electron-rich metal center have a higher activity. Ligand exchange experiments suggest that the pyridine ligands

  DOI：

  10.1021/jacs.2c00368
• 作为产物：
  描述：

  N-(9-undecynyl)-phthalimide 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 1.0h， 以62%的产率得到9-undecynylamine
  参考文献：
  名称：

  闭环炔烃复分解。立体选择性合成细胞毒性海洋生物碱motuporamine C.

  摘要：

  DOI：

  10.1021/jo991944d

文献信息

• Lubricant for powder metallurgy, powdery mixture for powder metallurgy, and process for producing sinter
  申请人：Suzuki Hironori

  公开号：US20070154340A1

  公开（公告）日：2007-07-05

  A lubricant for powder metallurgy which includes a polyhydroxycarboxylic acid amide. The lubricant improves both flowability and lubricity, irrespective of a presence or absence of any complicated pretreatment step.
• US7789934B2
  申请人：——

  公开号：US7789934B2

  公开（公告）日：2010-09-07
• Ring-Closing Alkyne Metathesis. Stereoselective Synthesis of the Cytotoxic Marine Alkaloid Motuporamine C
  作者：Alois Fürstner、Antonio Rumbo

  DOI：10.1021/jo991944d

  日期：2000.4.1
• Alkyne Metathesis with d²Re(V) Alkylidyne Complexes Supported by Phosphino-Phenolates: Ligand Effect on Catalytic Activity and Applications in Ring-Closing Alkyne Metathesis
  作者：Mingxu Cui、Herman H. Y. Sung、Ian D. Williams、Guochen Jia

  DOI：10.1021/jacs.2c00368

  日期：2022.4.13

  Re(V) alkylidyne complexes bearing two decorated phosphino-phenolates (POs) and a labile pyridine ligand were prepared that can efficiently promote alkyne metathesis reactions in toluene. The relative activity of these complexes varies with the PO ligands. Complexes with an electron-rich metal center have a higher activity. Ligand exchange experiments suggest that the pyridine ligands of the Re(V) alkylidynes

  A family of d2 Re(V) alkylidyne complexes bearing two decorated phosphino-phenolates (POs) and a labile pyridine ligand were prepared that can efficiently promote alkyne metathesis reactions in toluene. The relative activity of these complexes varies with the PO ligands. Complexes with an electron-rich metal center have a higher activity. Ligand exchange experiments suggest that the pyridine ligands