1,2,3,4-四苯基四硅烷 | 141272-69-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,2,3,4-四苯基四硅烷
• 英文名称: 1,2,3,4-tetraphenyltetrasilane
• 英文别名: Phenyl-[phenyl(phenylsilyl)silyl]-phenylsilylsilane；phenyl-[phenyl(phenylsilyl)silyl]-phenylsilylsilane
• CAS: 141272-69-7
• 化学式: C₂₄H₂₆Si₄
• 分子量: 426.812
• InChiKey: AKNNDUFEGGGXKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.32
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  苯硅烷 在 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 甲基锂 作用下， 以 乙醚 为溶剂， 生成 1.2.3-Triphenyltrisilan 、 1,2,3,4-四苯基四硅烷
  参考文献：
  名称：

  TRIHYDRIDOSILYL-TERMINATED POLYSILANES AND METHODS OF PREPARATION

  摘要：

  提供了新型三氢基硅基终止的聚硅烷以及它们的合成方法，这些方法适用于其他聚硅烷。合成方法可方便地制备出具有最少的易燃中间体和副产物处理的产品。这些新型化合物至少包含三个硅-硅键和至少一个末端硅原子，其有三个氢取代基。

  公开号：

  US20120071678A1

文献信息

• Rapid, Highly Linear-Selective Dehydrocoupling of Phenylsilane with New Group 4 Metallocene-Based Combination Catalysts
  作者：Hee-Gweon Woo、Sun-Jung Song

  DOI：10.1246/cl.1999.457

  日期：1999.6

  The dehydrocoupling of phenylsilane with Cp′2MCl2/Red-Al (Cp′ = C5H5 or C5Me5; M = Ti, Zr, Hf; Red-Al = Na[H2Al(OCH2CH2OMe)2]) cormbination catalysts rapidly produces linear polyphenylsilanes, and the linear selectivity drastically decreases in the order of Cp(C5Me5)Hf > Cp2Hf > Cp(C5Me5)Zr > Cp2Zr > Cp2Ti; in the presence of solvent (neat > toluene > THF) and 4 Å molecular sieve; with heating.

  苯基硅烷与 Cp′2MCl2/Red-Al（Cp′ = C5H5 或 C5Me5；M = Ti、Zr、Hf；Red-Al=Na[H2Al(OCH2CH2OMe)2])偶联催化剂可快速生成线性多苯基硅烷，线性选择性急剧下降，顺序为 Cp(C5Me5)Hf > Cp2Hf > Cp(C5Me5)Zr > Cp2Zr > Cp2Ti；存在溶剂（纯净 >甲苯 > 四氢呋喃）和 4 Å 分子筛；加热。
• Dehydrogenative polymerization of silanes to polysilanes by zirconocene and hafnocene catalysts. A new polymerization mechanism
  作者：Hee Gweon Woo、T. Don Tilley

  DOI：10.1021/ja00202a070

  日期：1989.9
• Reactivity of group 4 benzamidinate complexes towards mono- and bis-substituted silanes and 1,5-hexadiene
  作者：Victoria Volkis、Claudia Averbuj、Moris S. Eisen

  DOI：10.1016/j.jorganchem.2007.01.002

  日期：2007.4

  Zirconium and titanium bis(benzamidinate) dimethyl complexes were found to be active catalytic precursors for the oligomerization of mono- and bis-substituted silanes. The activation of such complexes, by an excess of MAO or by an equimolar amount of B(C6F5)(3), increases the catalytic activity of the complexes and the molecular weight of the obtained oligosilanes. The maximum polymerization index that was accomplished (n = 90) is by far the largest obtained with other organometallic complexes. In addition, the activated benzamidinate catalysts were also found to be active for the polymerization of 1,5-hexadiene producing poly(methyl-1,3-cyclopentane). For the latter, the results obtained with C-2-symmetry bis(benzamidinate) dimethyl complexes were compared with a chiral complex bearing a myrtanyl group at the benzamidinate ligand. (c) 2007 Elsevier B.V. All rights reserved.
• ansa-Metallocenes: Catalysts for the dehydrocoupling of hydrosilanes
  作者：Raef M Shaltout、Joyce Y Corey

  DOI：10.1016/0040-4020(94)01121-f

  日期：1995.4

  The dehydrocoupling of PhMeSiH(2) to form oligomers and of PhSiH(3) to form polysilanes has been performed with the precatalyst combination of [Me(2)El(C5H4)(2)MCl(2) (El = Si, C; M = Ti, Zr, Hf) and nBuLi. The results are compared to those produced from (eta(5)-C5H5)(2)MCl(2)/nBuLi.
• Woo, Hee-Gweon; Walzer, John F.; Don Tilley, Journal of the American Chemical Society, 1992, vol. 114, # 18, p. 7047 - 7055
  作者：Woo, Hee-Gweon、Walzer, John F.、Don Tilley

  DOI：——

  日期：——