三苯基(水杨酰氧基)锡烷 | 24379-26-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三苯基(水杨酰氧基)锡烷
• 中文别名: 聚乙烯二醇戊二酸酯
• 英文名称: 2-hydroxybenzoatotriphenyltin(IV)
• 英文别名: (o-hydroxybenzoato)triphenyltin；2-Carboxyphenolate;triphenylstannanylium
• CAS: 24379-26-8
• 化学式: C₂₅H₂₀O₃Sn
• 分子量: 487.142
• InChiKey: KBUBQYVZGBKROA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.22
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2918230000

反应信息

• 作为产物：
  描述：

  三苯基氢氧化锡 、 水杨酸 以 苯 为溶剂， 生成 三苯基(水杨酰氧基)锡烷
  参考文献：
  名称：

  某些三苯基锡（IV）羧酸盐的13 C和119 Sn NMR研究

  摘要：

  Ph 3 SnOCOR类型的脂肪族和芳香族三苯基锡（IV）羧酸盐的CDCl 3溶液的13 C和119 Sn NMR （Ph =苯基； R = H，Ch 3，C 2 H 5，C（CH 3）3，CF 3，CH 2氯，三氯甲烷2，CCL 3，CH 2 Br和CHBr 2）和型pH值3 SnOCOC 6 H ^ 4 X（X = H，4-NH 2，4-OCH 3，4-C（CH 3）3，4-CH3，4-NHCOCH 3，4-OH，4-SH，4-I，4-CL，4-CN，4-NO 2，2-OH和2_NH 2）已被记录。化学位移δ（的值119 Sn）和δ（13 C）本位和耦合常数1 Ĵ（119 Sn的13的三苯基锡（IV）基团的C）提供的证据表明，化合物是单体物质在溶液中而不管它们的结构处于固态。

  DOI：

  10.1016/s0022-328x(00)99251-9

文献信息

• 13C and 119Sn NMR study of some triphenyltin(IV) carboxylates
  作者：J. Holec̆ek、K. Handlír̆、M. Nádvorník、A. Lyc̆ka

  DOI：10.1016/s0022-328x(00)99251-9

  日期：1983.11

  The 13C and 119Sn NMR of CDCl3 solutions of aliphatic and aromatic triphenyltin(IV) carboxylates of type Ph3SnOCOR (Ph = phenyl; R = H, Ch3, C2H5, C(CH3)3, CF3, CH2Cl, CHCl2, CCl3, CH2Br and CHBr2) and of the type Ph3SnOCOC6H4X (X = H, 4-NH2, 4-OCH3, 4-C(CH3)3, 4-CH3,4-NHCOCH3, 4-OH, 4-SH, 4-I, 4-Cl, 4-CN, 4-NO2, 2-OH and 2_NH2) have been recorded. The value of the chemical shifts δ(119Sn) and δ(13C)ipso

  Ph 3 SnOCOR类型的脂肪族和芳香族三苯基锡（IV）羧酸盐的CDCl 3溶液的13 C和119 Sn NMR （Ph =苯基； R = H，Ch 3，C 2 H 5，C（CH 3）3，CF 3，CH 2氯，三氯甲烷2，CCL 3，CH 2 Br和CHBr 2）和型pH值3 SnOCOC 6 H ^ 4 X（X = H，4-NH 2，4-OCH 3，4-C（CH 3）3，4-CH3，4-NHCOCH 3，4-OH，4-SH，4-I，4-CL，4-CN，4-NO 2，2-OH和2_NH 2）已被记录。化学位移δ（的值119 Sn）和δ（13 C）本位和耦合常数1 Ĵ（119 Sn的13的三苯基锡（IV）基团的C）提供的证据表明，化合物是单体物质在溶液中而不管它们的结构处于固态。
• Malhotra, K. C.; Sharma, Neera; Soni, Rekha, Journal of the Indian Chemical Society, 1993, vol. 70, p. 633 - 636
  作者：Malhotra, K. C.、Sharma, Neera、Soni, Rekha、Chaudhry, S. C.

  DOI：——

  日期：——
• Vollano, Jean F.; Day, Roberta O.; Rau, Denise N., Inorganic Chemistry, 1984, vol. 23, # 20, p. 3153 - 3160
  作者：Vollano, Jean F.、Day, Roberta O.、Rau, Denise N.、Chandrasekhar、Holmes, Robert R.

  DOI：——

  日期：——
• Malhotra K. C., Sharma Neeraj, Soni Rekha, Chaudhry S. C., J. Indian Chem. Soc, 70 (1993) N 7, S 633-635
  作者：Malhotra K. C., Sharma Neeraj, Soni Rekha, Chaudhry S. C.

  DOI：——

  日期：——
• Synthesis, characterization and biological activities of some new organotin(IV) derivatives: Crystal structure of [(Sn Ph3) (OOCC6H4OH)] and [(SnMe3)2 (OOC)2C6Cl4 (DMSO)2]
  作者：M. Khawar Rauf、M. Adeel Saeed、Imtiaz-ud-Din、M. Bolte、A. Badshah、B. Mirza

  DOI：10.1016/j.jorganchem.2008.06.027

  日期：2008.9

  Some new organotin(IV) carboxylates 1-3 of 2-hydroxybenzoic acid (LA) and 4-6 of 2,3,4,5-tetrachloro-6( methoxycarbonyl) benzoic acid (L-B) have been synthesized, respectively, by the esterification of triorganotin oxide/hydroxide with the corresponding acids in an appropriate mole ratios. Multinuclear NMR (H-1, C-13 and Sn-119), IR and X-ray crystallographic studies were carried out to elucidate their structures both in solution and in solid state. The X-ray crystallographic data for 3 was recollected at low temperature. The compound 4 was dissolved in DMSO and a new compound 4 center dot 2DMSO [(SnMe3)(2)(OOC)(2)C6Cl4(DMSO)(2)] was crystallized out. The structure shows that two Sn moieties are attached to the ligand (LB) through two carboxylic groups. The two molecules of DMSO are coordinated to each of the Sn atoms via oxygen atom to terminate the conventional polymeric chain of trimethyl carboxylates to a discrete molecule, having trigonal bipyramidal geometry around the Sn atoms. Some of the synthesized compounds exhibited significant antifungal activities and have a potential to be used as drugs. (C) 2008 Elsevier B. V. All rights reserved.