Bis(4-dimethylanilin)aminyl | 2316-27-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Bis(4-dimethylanilin)aminyl
• 英文别名: Bis-(4-dimethylamino-phenyl)-aminradikal; Bis-(4-dimethylamino-phenyl)-Stickstoffradikal
• CAS: 2316-27-0
• 化学式: C₁₆H₂₀N₃
• 分子量: 254.355
• InChiKey: PVSQEUXTXYGHCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  18.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,4,6-三甲氧基苯酚 、 Bis(4-dimethylanilin)aminyl 生成 宾雪德拉氏绿隐色碱 、
  参考文献：
  名称：

  Incorporation of Ring Nitrogens into Diphenylamine Antioxidants: Striking a Balance between Reactivity and Stability

  摘要：

  The incorporation of nitrogen atoms into the aryl rings of conventional diphenylamine antioxidants enables the preparation of readily accessible, air-stable analogues, several of which have temperature-independent radical-trapping activities up to 200-fold greater than those of typical commercial diphenylamines. Amazingly, the nitrogen atoms raise the oxidation potentials of the amines without greatly changing their radical-trapping (H-atom transfer) reactivity.

  DOI：

  10.1021/ja300086z
• 作为产物：
  描述：

  宾雪德拉氏绿隐色碱 在 2,4,6-三甲氧基苯酚 作用下， 生成 Bis(4-dimethylanilin)aminyl
  参考文献：
  名称：

  Incorporation of Ring Nitrogens into Diphenylamine Antioxidants: Striking a Balance between Reactivity and Stability

  摘要：

  The incorporation of nitrogen atoms into the aryl rings of conventional diphenylamine antioxidants enables the preparation of readily accessible, air-stable analogues, several of which have temperature-independent radical-trapping activities up to 200-fold greater than those of typical commercial diphenylamines. Amazingly, the nitrogen atoms raise the oxidation potentials of the amines without greatly changing their radical-trapping (H-atom transfer) reactivity.

  DOI：

  10.1021/ja300086z