4-(2-Pyridylazo) resorcinol monosodium salt | 16593-81-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(2-Pyridylazo) resorcinol monosodium salt
• 英文别名: 4-(2-pyridylazo)resorcinol monosodium salt；Sodium 4-(2-pyridylazo)resorcinol；sodium;5-hydroxy-2-(pyridin-2-yldiazenyl)phenolate
• CAS: 16593-81-0；13311-52-9
• 化学式: C₁₁H₈N₃O₂*Na
• 分子量: 237.193
• InChiKey: KZRPHCQLJZXMJV-UHFFFAOYSA-M

物化性质

• 熔点：
  188 °C

计算性质

• 辛醇/水分配系数(LogP)：
  -0.72
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  83.7
• 氢给体数：
  1
• 氢受体数：
  5

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 海关编码：
  29333999,2933399090

反应信息

• 作为反应物：
  描述：

  4-(2-Pyridylazo) resorcinol monosodium salt 、 uranyl(VI) nitrate 以 乙醇 为溶剂， 以70%的产率得到di(4-(2-pyridylazo)resorcinyl) dioxouranium(VI)
  参考文献：
  名称：

  Sastry, Mandalika S.; Singh, Udai P.; Ghose, Ranjana, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1991, vol. 21, p. 73 - 88

  摘要：

  DOI：

文献信息

• Kinetics of Ligand Substitution Reaction between Cyanide Ion and NiL₂(L=4-(2-Pyridylazo)resorcinol, Diethylenetriamine, and Ethylenediamine)
  作者：Hari Chand Bajaj、Madhu Phull、Prem Chandra Nigam

  DOI：10.1246/bcsj.57.564

  日期：1984.2

  loss. The backward reaction between [Ni(CN)4]2− and L is first order in each reactant and inverse first order in cyanide. Though the mechanism for the reactions appears to be same, there are kinetic differences in the behaviour of en and the other two chelates. The rate determining step for the three reactions have been identified. The activation parameters for the forward reaction have been evaluated

  氰化物离子与一些双配合物 [NiL2]2−2n 的取代反应动力学，其中 Ln− 是 4-(2-吡啶偶氮)间苯二酚、二亚乙基三胺或乙二胺，形成方形平面配合物 [Ni(CN)4] 2- 已经在水溶液中进行了分光光度法研究。速率表达式的形式为：rate=kdNiL2+k'[CN−]}[NiL22−2n]，其中 k' 在 par 和 dien 情况下是复合速率常数，在 en 情况下等于 kCNNiL2。这些结果表明这些双配合物没有直接转化为 [Ni(CN)4]2- 而是首先失去一个配体分子，而氰化物有助于这种损失。[Ni(CN)4]2-和L之间的逆反应在每种反应物中都是一级反应，而在氰化物中则是逆一级反应。虽然反应的机制看起来是一样的，en 和其他两种螯合物的行为存在动力学差异。已经确定了三个反应的速率确定步骤。已经评估了正向反应的活化参数以支持...
• SERS Surfaces Modified with a 4-(2-Pyridylazo)resorcinol Disulfide Derivative: Detection of Copper, Lead, and Cadmium
  作者：L. Gayle. Crane、DaoXin. Wang、L. Malia. Sears、Bernard. Heyns、Keith. Carron

  DOI：10.1021/ac00098a021

  日期：1995.1.15

  We have developed a surface-enhanced Raman spectroscopic technique for the determination of Ph(2+), Cd2+, and Cu2+ concentration using a 4-(2-pyridylazo)resorcinol (PAR) coating modified with a disulfide. The disulfide provided a strong anchor to a roughened sih er substrate. Atomic specificity was demonstrated by the distinct spectral changes that occurred through the interaction of Pb2+, Cd2+, and Cu2+ ions with the indicator. The absorption of these metals by the coating was followed with SERS and could be fit to a Frumkin isotherm. Langmuirian behavior was not observed; this is most likely due to the electrostatic repulsions as the metal cations are absorbed. The detection limits at pH 6 for Pb2+, Cd2+, and Cu2+ were 522, 50.3, and 1.49 ppb, respectively. Flow experiments using an optical fiber probe indicated instantaneous response to changes in metal concentration.
• Sastry, Mandalika S.; Singh, Udai P.; Ghose, Ranjana, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, <hi>1991</hi>, vol. 21, p. 73 - 88
  作者：Sastry, Mandalika S.、Singh, Udai P.、Ghose, Ranjana、Ghose, Animesh K.

  DOI：——

  日期：——
• Sastry, Mandalika S.; Singh, Udai P., Crystal Research and Technology
  作者：Sastry, Mandalika S.、Singh, Udai P.

  DOI：——

  日期：——
• Sastry, Mandalika S.; Singh, Udai P.; Ghose, Ranjana, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1991, vol. 21, p. 73 - 88
  作者：Sastry, Mandalika S.、Singh, Udai P.、Ghose, Ranjana、Ghose, Animesh K.

  DOI：——

  日期：——