6-acetoxy-1-naphthoic chloride | 832146-39-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-acetoxy-1-naphthoic chloride
• 英文别名: 6-acetoxy-[1]naphthoyl chloride；6-Acetoxy-naphthoesaeure-(1)-chlorid；6-Acetoxy-[1]naphthoylchlorid
• CAS: 832146-39-1
• 化学式: C₁₃H₉ClO₃
• 分子量: 248.666
• InChiKey: ZCFBLRSDMCDUPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.14
• 重原子数：
  17.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  43.37
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 6-acetoxy-1-naphthoic chloride 在 乙醚 、 苯 作用下， 生成 2-acetoxy-1-(6-acetoxy-[1]naphthyl)-ethanone
  参考文献：
  名称：

  脱氧皮质酮的一些萘类似物。

  摘要：

  DOI：

  10.1021/ja01202a006
• 作为产物：
  描述：

  苯甲醚 在 吡啶 、 三氯化铝 、 氯化亚砜 、 氢溴酸 、 溶剂黄146 、 苯 作用下， 生成 6-acetoxy-1-naphthoic chloride
  参考文献：
  名称：

  脱氧皮质酮的一些萘类似物。

  摘要：

  DOI：

  10.1021/ja01202a006

文献信息

• Synthesis and Curing Behaviors of Cross-Linkable Polynaphthols from Renewable Resources:  Preparation of Artificial Urushi
  作者：Takashi Tsujimoto、Hiroshi Uyama、Shiro Kobayashi

  DOI：10.1021/ma035271j

  日期：2004.3.1

  This paper describes the synthesis and curing of cross-linkable polynaphthols from renewable resources. Naphthol monomers bearing an unsaturated group from renewable triglyceride oils were designed and oxidatively polymerized to produce new cross-linkable precursor polymers. The monomers were prepared by acylation of hydroxynaphthoic acids with unsaturated alcohols, obtained by reduction of natural oils. The oxidative polymerization was carried out by Fe-salen catalyst to give soluble polynaphthols. NMR analysis showed that the naphthol moiety was chemoselectively reacted during the polymerization, yielding the polymers possessing the unsaturated group in the side chain. The resulting polymers were readily cured by thermal treatment or cobalt naphthenate catalyst to give the cross-linked film ("artificial urushi") with high hardness and gloss surface.