2,3,3,3-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)propanoic acid | 130968-84-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 磺酰卤
• 英文名称: 2,3,3,3-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)propanoic acid
• CAS: 130968-84-2
• 化学式: C₅HF₉O₅S
• 分子量: 344.112
• InChiKey: WJSFYFPZPVDQMT-UHFFFAOYSA-N

物化性质

• 沸点：
  271.3±40.0 °C(Predicted)
• 密度：
  1.887±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  89
• 氢给体数：
  1
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  2,3,3,3-Tetrafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)propanoic acid 以 水 、 乙腈 为溶剂， 以97%的产率得到1,1,2,2-Tetrafluoro-2-[1,2,3,3,3-pentafluoro-2-(1,1,2,2-tetrafluoro-2-fluorosulfonyl-ethoxy)-1-trifluoromethyl-propoxy]-ethanesulfonyl fluoride
  参考文献：
  名称：

  Electrochemical synthesis of mono- and bisperfluoroalkanesulfonyl fluorides

  摘要：

  DOI：

  10.1007/bf01557746

文献信息

• Electrochemical synthesis of perfluoroalkylchlorides
  作者：V. A. Grinberg、V. F. Cherstkov、S. R. Sterlin、Yu. B. Vasil'ev、L. S. German

  DOI：10.1007/bf00961499

  日期：1990.8

  Electrooxidation of perfluorocarboxylic acids in the presence of Cl2 yields perfluoroalkylchlorides R(F)Cl. It is suggested that anodic oxidation of perfluorocarboxylate ions is the determining electrochemical stage in this electrochemical version of the Borodin-Hundsdikker reaction.
• Localization of electrochemically generated radicals as a function of their structure and the nature of the solvent
  作者：V. F. Cherstkov、V. A. Grinberg、S. R. Sterlin、Yu. B. Vasil'ev、L. S. German、E. I. Mysov

  DOI：10.1007/bf00961365

  日期：1991.5

  The electrooxidation of different perfluorocarboxylic acids has been investigated in the presence of ethylene, on electrodes with different adsorbing power [platinum and glassy carbon (GC)] in different solvents. It has been shown that the reaction zone of the ECG radicals is determined by their solubility; depending on this, it can be limited to the electrode surface or encompass the entire volume of the solution. The concept of the solubility of the ECG radicals made it possible to establish some regularities in the formation of cross combination products in the Kolbe electrosynthesis of different perfluorocarboxylic acids.
• GRINBERG, V. A.;CHERSTKOV, V. F.;STERLIN, S. R.;VASILEV, YU. B.;GERMAN, L+, IZV. AN CCCP. CEP. XIM.,(1990) N, S. 1841-1844
  作者：GRINBERG, V. A.、CHERSTKOV, V. F.、STERLIN, S. R.、VASILEV, YU. B.、GERMAN, L+

  DOI：——

  日期：——
• CHERSTKOV, V. F.;GRINBERG, V. A.;STERLIN, S. R.;VASILEV, YU. B.;GERMAN, L+, IZV. AN CCCP. CEP. XIM.,(1990) N0, S. 2448-2449
  作者：CHERSTKOV, V. F.、GRINBERG, V. A.、STERLIN, S. R.、VASILEV, YU. B.、GERMAN, L+

  DOI：——

  日期：——
• CHERSTKOV, V. F.;GRINBERG, V. A.;STERLIN, S. R.;VASILEV, YU. B.;GERMAN, L+, IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1134-1141
  作者：CHERSTKOV, V. F.、GRINBERG, V. A.、STERLIN, S. R.、VASILEV, YU. B.、GERMAN, L+

  DOI：——

  日期：——