2-methoxy-6-((E){[(5-methyl-2-furyl)methyl]imino}methyl)phenol | 1311271-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-methoxy-6-((E){[(5-methyl-2-furyl)methyl]imino}methyl)phenol
• CAS: 1311271-53-0
• 化学式: C₁₄H₁₅NO₃
• 分子量: 245.278
• InChiKey: PXUQXANSZJGBLW-OVCLIPMQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.92
• 重原子数：
  18.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  54.96
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  2-methoxy-6-((E){[(5-methyl-2-furyl)methyl]imino}methyl)phenol 、 copper(II) acetate monohydrate 以 乙醇 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Syntheses, characterizations and structures of NO donor Schiff base ligands and nickel(II) and copper(II) complexes

  摘要：

  New Schiff base derivatives (L-1 and L-2) were prepared by the condensation of 2-hydroxy-3-methoxybenzaldehyde (o-vanillin) and 3-hydroxy-4-methoxybenzaldehyde (iso-vanillin) with 5-methylfurfurylamine. Two new complexes [Ni(L-1)(2)] and [Cu(L-1)(2)] have been synthesized with bidentate NO donor Schiff base ligand (L-1). The Ni(II) and Cu(II) atoms in each complex are four coordinated in a square planar geometry. Schiff bases (L-1 and L-2) and complexes [Ni(L-1)(2)] and (Cu(L-1)(2)] were characterized by elemental analyses, FT-IR, UV-vis, mass and H-1, C-13 NMR spectroscopies. The crystal structures of the ligand (L-2) and complexes [Ni(L-1)(2)] and [Cu(L-1)(2)] have also been determined by using X-ray crystallographic technique. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.04.037
• 作为产物：
  描述：

  5-甲基糠胺 、 邻香草醛 以 乙醇 为溶剂， 反应 3.0h， 以83%的产率得到2-methoxy-6-((E){[(5-methyl-2-furyl)methyl]imino}methyl)phenol
  参考文献：
  名称：

  Syntheses, characterizations and structures of NO donor Schiff base ligands and nickel(II) and copper(II) complexes

  摘要：

  New Schiff base derivatives (L-1 and L-2) were prepared by the condensation of 2-hydroxy-3-methoxybenzaldehyde (o-vanillin) and 3-hydroxy-4-methoxybenzaldehyde (iso-vanillin) with 5-methylfurfurylamine. Two new complexes [Ni(L-1)(2)] and [Cu(L-1)(2)] have been synthesized with bidentate NO donor Schiff base ligand (L-1). The Ni(II) and Cu(II) atoms in each complex are four coordinated in a square planar geometry. Schiff bases (L-1 and L-2) and complexes [Ni(L-1)(2)] and (Cu(L-1)(2)] were characterized by elemental analyses, FT-IR, UV-vis, mass and H-1, C-13 NMR spectroscopies. The crystal structures of the ligand (L-2) and complexes [Ni(L-1)(2)] and [Cu(L-1)(2)] have also been determined by using X-ray crystallographic technique. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.04.037