| 162338-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 162338-76-3；862877-53-0
• 化学式: C₄₂H₃₀Fe₂N₆O₆
• 分子量: 826.431
• InChiKey: XYRVXSLCLMIOQG-LWFXLYSCSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水杨醛吖嗪 在 [Fe3O(OOCCH3)6(H2O)3] 、 sodium hydroxide 作用下， 以 甲醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Efficient photocatalytic properties of a dinuclear iron complex with bis[2-hydroxybenzaldehyde]hydrazonate ligand

  摘要：

  A novel photooxidative system for degrading toxic organic pollutants is reported. A new complex of Fe2L3(L = bis[2-hydroxybenzaldehyde]hydrazone) synthesized can efficiently activate hydrogen peroxide (H2O2) to oxidize and mineralize the target complexes rhodamine B (RhB) and methyl orange (MO) in aqueous media under ambient temperature and normal pressure and with visible light irradiation. (C) 2013 Peng Wu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2013.03.015

文献信息

• The formation of a metallosupramolecular porous helicate through salicylaldehydethiosemicarbazone: Synthesis, Characterization, Cytotoxic activity, DNA binding and DFT calculations
  作者：Elif Avcu Altiparmak、Guneş Ozen Eroglu、Elif Ozcelik、Namık Özdemir、Serap Erdem Kuruca、Nergis Arsu、Bahri Ülküseven、Tulay Bal‐Demirci

  DOI：10.1002/aoc.5023

  日期：——

  dinucleating O, N, N, O donor ligands provide three diazine (═N─N═) bridges between the metal ions and facial O3N3 coordination spheres around them. The ligands are folded about the N─N single bond and coordinated to the two metal ions in a helical fashion to form the triple helical structure. In the crystal lattice, chains of centrosymmetric rings, which are connected to one another via π─π stacking interactions

  水杨醛-S-甲基异硫半脲在乙二胺碱和氯化铁（III）存在下的反应生成了不可预见的同位双核三链螺旋铁（III）螺旋盐。通过元素分析，红外，紫外-可见光谱，磁矩测量对合成的螺旋藻进行表征，并评估其对K562，HL-60和THP-1白血病细胞的细胞毒活性。此外，固态结构已通过单晶X射线衍射技术确定。在复杂的，三dinucleating O，N，N，O供体配体提供了三个二嗪（═ Ñ ─ Ñ ═）金属离子和面部O之间进行桥3 Ñ 3他们周围的协调领域。的配位体被折叠大约N个─ N条单键和配位到两种金属离子以螺旋方式以形成三股螺旋结构。在晶格中，通过C-H··O分子间相互作用产生通过π-π堆积相互作用相互连接的中心对称环链。密度泛函理论（DFT）计算也证实了该结果。从细胞毒性试验获得的结果表明，低浓度对白血病细胞有效。具有高的固有结合常数（K b  = 8×10 6 M -1）证实了螺旋-DNA复合物
• Priggemeyer; Eggers-Borkenstein; Ahlers, Inorganic Chemistry, 1995, vol. 34, # 6, p. 1445 - 1454
  作者：Priggemeyer、Eggers-Borkenstein、Ahlers、Henkel、Körner、Witzel、Nolting、Hermes、Krebs

  DOI：——

  日期：——
• A Diiron(III) Complex Containing N-N Bridges. Synthesis, Structure, and Properties
  作者：Jagadam Saroja、Vadivelu Manivannan、Partha Chakraborty、Samudranil Pal

  DOI：10.1021/ic00115a044

  日期：1995.5

  A dinuclear iron(III complex, Fe-2(salhn)(3) having three N-N linkages was synthesized using the tetradentate Schiff base ligand N,N'-bis(salicylidene)hydrazine (H(2)salhn). The complex was characterized by analytical, spectroscopic and X-ray crystallographic techniques. It is redox active and displays two one electron reductions corresponding to Fe-2(III)/(FeFeII)-Fe-III and (FeFeII)-Fe-III/Fe-2(II) couples. A weal; antiferromagnetic spin-coupling is observed between the two high-spin Fe(III) centers due to superexchange via the N-N bridges.[GRAPHICS]ated (1-) and (3-) states confirm the MLCT formulation for the lowest excited states of the (2-) precursor complexes by showing typical low-spin Fe(III) signals of the oxidized species [(abpy)Fe(CN)(4)](-) and partially hyperfine-structured spectra for the reduced forms [(bpz)M(CN)(4)](3-). The latter are clearly tetracyanoiron(II) or -ruthenium(II) complexes of the corresponding anion radical acceptor ligands and are thus isoelectronic with monoanionic tetracarbonylchromium(0) or -molybdenum(0) radical complexes.