2,2'-dihydroxy-1,1'-bianthracene

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,2'-dihydroxy-1,1'-bianthracene
• 英文别名: (+/-)-2.2'-Dihydroxy-[1.1']bianthryl；[1,1']Bianthryl-2,2'-diol；Dihydroxy-bianthracenylidene；1-(2-hydroxyanthracen-1-yl)anthracen-2-ol
• 化学式: C₂₈H₁₈O₂
• 分子量: 386.45
• InChiKey: NWDQPAMKMGYKOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  30
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  全氟丁基磺酰氟 、 2,2'-dihydroxy-1,1'-bianthracene 生成 [1-[2-(1,1,2,2,3,3,4,4,4-Nonafluorobutylsulfonyloxy)anthracen-1-yl]anthracen-2-yl] 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
  参考文献：
  名称：

  Perfluoro-n-alkylsulfonic acid derivatives

  摘要：

  本文描述了双(全氟烷基磺酸盐)化合物的制备方法和用途，例如作为合成手性和膦配体的起始材料，用于过渡金属催化剂。

  公开号：

  US06353125B1
• 作为产物：
  描述：

  2-羟基蒽 在 manganese(II) iodide 作用下， 以 氯仿 为溶剂， 反应 12.0h， 以74%的产率得到2,2'-dihydroxy-1,1'-bianthracene
  参考文献：
  名称：

  MnI₂-catalyzed Dimerization of 2-Hydroxyanthracene

  摘要：

  对2-羟基蒽的二聚反应进行了研究，使用了5 mol %的多种催化剂，这些催化剂被证实在2-萘醇的二聚反应中表现良好。催化剂如Cu(OH)Cl·TMEDA、[Mn(acac)3]和[Mn(acac)2]的表现并不令人满意。然而，MnI2在相同条件下仅给出了微量的2-萘醇二聚产物，却能在74%的产率下生成2,2′-二羟基-1,1′-双蒽。

  DOI：

  10.1246/cl.130251

文献信息

• Enantioselective oxidative-coupling of polycyclic phenols
  作者：Shinobu Takizawa、Junpei Kodera、Yasushi Yoshida、Makoto Sako、Stefanie Breukers、Dieter Enders、Hiroaki Sasai

  DOI：10.1016/j.tet.2014.01.017

  日期：2014.3

  Enantioselective oxidative-coupling of polycyclic phenols, such as 2-anthracenol, 9- or 3-phenanthrol, and 5-chrysenol was established by using vanadium(V/IV) catalysis under air or 02 as a co-oxidant. In the vanadium catalyzed reaction, the corresponding coupling products were obtained in good to excellent yields with up to 93% enantiomeric excess. (C) 2014 Elsevier Ltd. All rights reserved.
• 337. The symmetrical dianthryls. Part II
  作者：F. Bell、D. H. Waring

  DOI：10.1039/jr9490001579

  日期：——
• [EN] COMPOSITION HAVING HIGH HEAT- AND CHEMICAL-RESISTANCE AND METHOD FOR PREPARING PROTECTIVE THIN FILM USING SAME<br/>[FR] COMPOSITION DOTÉE D'UNE RÉSISTANCE ÉLEVÉE À LA CHALEUR ET AUX PRODUITS CHIMIQUES ET PROCÉDÉ DE FABRICATION D'UN FILM MINCE PROTECTEUR L'UTILISANT
  申请人：SKC CO LTD

  公开号：WO2015016641A1

  公开（公告）日：2015-02-05

  The present invention relates to a composition comprising an aromatic compound having high heat- and chemical-resistance and a method for preparing a protective thin film using same. The protective thin film prepared from the inventive composition is capable of maintaining its physical shape with no thermal deformation even when exposed to high heat of 300C or greater, shows excellent chemical resistance against an acid, a base or an organic solvent, and maintains the shape of an exposed surface during plasma treatment, thereby effectively functioning as a protective thin film for the protection of an underlying material.
• MnI₂-catalyzed Dimerization of 2-Hydroxyanthracene
  作者：Sicheng Zhang、Yanqing Wang、Zhiyi Song、Kiyohiko Nakajima、Tamotsu Takahashi

  DOI：10.1246/cl.130251

  日期：2013.7.5

  Dimerization of 2-hydroxyanthracene was investigated with 5 mol % of various catalysts that are efficient catalysts for the dimerization of 2-naphthol. Catalysts such as Cu(OH)Cl·TMEDA, [Mn(acac)3], and [Mn(acac)2] did not give satisfactory results. However, MnI2, which gave only trace amounts of dimerization product of 2-naphthol under the same conditions, afforded 2,2′-dihydroxy-1,1′-bianthracene in 74% yield.

  对2-羟基蒽的二聚反应进行了研究，使用了5 mol %的多种催化剂，这些催化剂被证实在2-萘醇的二聚反应中表现良好。催化剂如Cu(OH)Cl·TMEDA、[Mn(acac)3]和[Mn(acac)2]的表现并不令人满意。然而，MnI2在相同条件下仅给出了微量的2-萘醇二聚产物，却能在74%的产率下生成2,2′-二羟基-1,1′-双蒽。
• Perfluoro-n-alkylsulfonic acid derivatives
  申请人：Merck Patent GmbH

  公开号：US06353125B1

  公开（公告）日：2002-03-05

  Described are bis(perfluoro-n-alkane-sulfonate) compounds, methods for preparing these compounds and use of these compounds, for example as starting materials for the synthesis of chiral and phosphine ligands for transition metal catalysts.

  本文描述了双(全氟烷基磺酸盐)化合物的制备方法和用途，例如作为合成手性和膦配体的起始材料，用于过渡金属催化剂。