cis 1-chloro-5-decene | 71673-28-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: cis 1-chloro-5-decene
• 英文别名: 1-chloro-5-decene；5-Decene, 1-chloro-, (5Z)-；(E)-1-chlorodec-5-ene
• CAS: 71673-28-4
• 化学式: C₁₀H₁₉Cl
• 分子量: 174.714
• InChiKey: RTCAJAHYBVGCHJ-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903299090

反应信息

• 作为产物：
  描述：

  1-己烯 、 6-氯-1-己烯 、 反-5-癸烯醇 、 (E)-5-癸烯-1-乙酸酯 生成 cis 1-chloro-5-decene
  参考文献：
  名称：

  Biologically active compounds by catalytic olefin metathesis

  摘要：

  生物活性化合物，如信息素及其前体，是通过异构末端烯烃或环二烯和末端烯烃的催化交叉甲醇异构化反应产生的。

  公开号：

  US05916983A1

文献信息

• Metathesis syntheses of pheromones or their components
  申请人：——

  公开号：US20020022741A1

  公开（公告）日：2002-02-21

  The present invention relates to metathesis syntheses for insect sex-attractant pheromones or their components, such as E-5-decenyl acetate, the major component of the Peach Twig Borer pheromone; (5R, 6S)-6-acetoxy-5-hexadecanolide, the mosquito oviposition attractant pheromone; E9, Z11-hexadecadienal, the pecan nut casebearer moth pheromone; 9-tetradecenyl formate, an analog of the Diamondback Moth (DBM) pheromone; 11-tetradecenyl acetate, the Omnivorous Leafroller (OLR) pheromone; E-4-tridecenyl acetate, the major component of the Tomato Pinworm (TPW) pheromone; E,E-8,10-dodecadienol, the Codling Moth (CM) pheromone. The syntheses preferably employ a Class I-IV metathesis catalyst, entail few reaction steps, use generally commercially available starting materials, and have relatively short process times. These syntheses produce good yields without the need for expensive or sophisticated equipment. The invention also provides an inexpensive route for producing omega-haloalkenols by cross-metathesizing alpha-omega-diacetoxy alkenes and alpha-omega-dihalides to yield omega-haloalkenols, which are easily converted into omega-haloalkanols under traditional hydrogenation methods.

  本发明涉及对昆虫性诱素或其组分进行交换合成，如E-5-癸烯醇醋酸酯，桃枝蠕蛾性信息素的主要成分；（5R, 6S）-6-乙酰氧基-5-十六醇内酯，蚊子产卵引诱素；E9, Z11-癸二烯醛，山核桃果蛾性信息素；9-十四烯酸甲酯，菜青虫性信息素的类似物；11-十四烯醇醋酸酯，杂食卷叶蛾性信息素；E-4-十三烯醇醋酸酯，番茄针孔螟性信息素的主要成分；E,E-8,10-十二二烯醇，苹果蛾性信息素。这些合成通常采用I-IV类交换催化剂，步骤较少，使用通常易得的起始物质，并具有相对较短的工艺时间。这些合成产量良好，无需昂贵或复杂的设备。该发明还提供了通过交叉交换α-Ω-二乙酰基烯烃和α-Ω-二卤代烃来产生Ω-卤代烯醇的廉价途径，后者可以在传统的氢化方法下轻松转化为Ω-卤代烷醇。
• Metal complexes useful in metathesis and other reactions
  申请人：Walter Francis

  公开号：US20050043541A1

  公开（公告）日：2005-02-24

  This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.

  本发明提供了金属配合物，可用作交换反应中的催化剂组分，以及涉及将原子或基团转移至乙烯基或乙炔基不饱和化合物或其他反应底物的反应中，并且针对其亚类别，用于α-烯烃和可选的共轭二烯的聚合，具有在中等温度下高活性。它还提供了通过活性反应获得非常窄的分子量分布的聚合物的方法。它还提供了制备该金属配合物和涉及这种方法的新型中间体的方法。它还提供了该金属配合物的衍生物，适用于与载体进行共价键合，该共价键合的产物可用作异相催化反应的支持催化剂。它还提供了从双烯基化合物直接合成吡咯、呋喃和噻吩化合物的一步法。
• Metal carbene complexes, methods and intermediates for making them and their use in metathesis reactions
  申请人：UNIVERSITEIT GENT

  公开号：EP1329455A1

  公开（公告）日：2003-07-23

  Compounds having one of the general formulae:    wherein: M is a metal; Z is selected from the group consisting of oxygen, sulphur, NR"" and PR""; R", R"' and R"" are each a radical independently selected from hydrogen, C1-6 alkyl, C3-8 cycloalkyl, aryl and heteroaryl, or R" and R"' together form an aryl or heteroaryl radical, each said radical being optionally substituted; R' is either as defined for R", R"' and R"" when included in a compound having the general formula (IA) or, when included in a compound having the general formula (IB), is selected from hydrogen, C1-6 alkylene and C3-8 cycloalkylene, the said alkylene and cycloalkylene group being optionally substituted; R1 is a constraint steric hindrance group having a pKa of at least about 15; R2 is an anionic ligand; R3 and R4 are each hydrogen or a radical selected from, among others, C1-20 alkyl, C1-20 alkenyl; R3 and R4 together may form a fused aromatic ring system, and y represents the number of sp2 carbon atoms between M and the carbon atom bearing R3 and R4 and is an integer from 0 to 3 inclusive are useful as catalysts for olefin metathesis and atom transfer radical polymerization.

  具有下列通式之一的化合物 其中 M 是金属； Z 选自由氧、硫、NR""和 PR""组成的组； R"、R"'和 R""各自是独立选自氢、C1-6 烷基、C3-8 环烷基、芳基和杂芳基的基团，或 R" 和 R"'共同形成芳基或杂芳基，每个所述基团均被任选取代； 当包含在通式（IA）化合物中时，R'与 R"、R"'和 R""的定义相同；当包含在通式（IB）化合物中时，R'选自氢、C1-6 亚烷基和 C3-8 环亚烷基，所述亚烷基和环亚烷基任选被取代； R1 是一个限制性立体阻碍基团，其 pKa 至少约为 15； R2 是阴离子配体； R3 和 R4 分别为氢或选自 C1-20 烷基、C1-20 烯基等的自由基； R3 和 R4 可共同形成一个融合的芳香环系统，以及 y 代表 M 与含有 R3 和 R4 的碳原子之间的 sp2 碳原子数，是 0 至 3（包括 3 个）的整数。 可用作烯烃偏聚和原子转移自由基聚合的催化剂。
• Metal complexes for use in olefin methathesis and atom or group transfer reactions
  申请人：UNIVERSITEIT GENT

  公开号：EP1577282A2

  公开（公告）日：2005-09-21

  Improved catalysts useful in a number of organic synthesis reactions such as olefin metathesis and atom or group transfer reactions are made by bringing into contact a multi-coordinated metal complex comprising a multidentate Schiff base ligand, and one or more other ligands, with an acid under conditions such that said acid is able to at least partly cleave a bond between the metal and the multidentate Schiff base ligand of said metal complex, optionally through intermediate protonation of said Schiff base ligand.

  在烯烃复分解反应和原子或基团转移反应等一系列有机合成反应中使用的改良催化剂，是通过将包含多叉席夫碱配体和一个或多个其他配体的多配位金属络合物与酸接触而制成的，接触条件是所述酸能够至少部分裂解金属与所述金属络合物的多叉席夫碱配体之间的键，还可选择通过所述席夫碱配体的中间质子化。
• Metal complexes for use in metathesis, atom transfer radical reactions, addition polymerisation and vinylation reactions, methods and intermediates for making them
  申请人：UNIVERSITEIT GENT

  公开号：EP1743899A1

  公开（公告）日：2007-01-17

  This invention relates to metal complexes which are useful as catalyst components in olefin metathesis reactions, atom or group transfer radical polymerisation or addition reactions and vinylation reactions. It also relates to the direct one-step synthesis of pyrrole, furan and thiophene compounds, such as dialkyl 1H-pyrrol-1-yl methyl phosphonates, from diallyl compounds.

  本发明涉及在烯烃偏聚反应、原子或基团转移自由基聚合或加成反应以及乙烯基化反应中用作催化剂组分的金属络合物。本发明还涉及从二烯丙基化合物中一步直接合成吡咯、呋喃和噻吩化合物，如 1H-吡咯-1-基甲基膦酸二烷基酯。