(N)Mn(V)TPP | 83632-54-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (N)Mn(V)TPP
• 英文别名: nitrido(tetraphenylporphinato)manganese(V)；nitridomanganese(V) meso-tetraphenylporphyrinate；nitrido(tetraphenylporphyrin)manganese(V)；NMn(meso-tetraphenylporphinate)
• CAS: 83632-54-6
• 化学式: C₄₄H₂₈MnN₅
• 分子量: 681.678
• InChiKey: UMTCEDNOPWTKTH-YKKPBKTHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (N)Mn(V)TPP 以 solid matrix 为溶剂， 生成 2,3,5,7-四苯基-21H,23H-卟吩锰(2+)盐(1:1)
  参考文献：
  名称：

  Jin, Takashi; Suzuki, Toru; Imamura, Taira, Inorganic Chemistry, 1987, vol. 26, # 8, p. 1280 - 1285

  摘要：

  DOI：
• 作为产物：
  描述：

  azidomanganese(III) meso-tetraphenylporphyrin 以 solid matrix 为溶剂， 生成 (N)Mn(V)TPP
  参考文献：
  名称：

  Jin, Takashi; Suzuki, Toru; Imamura, Taira, Inorganic Chemistry, 1987, vol. 26, # 8, p. 1280 - 1285

  摘要：

  DOI：

文献信息

• Pyrolysis of Azidomanganese(III) Porphyrin Affording Nitridomanganese(V) Porphyrin
  作者：Yuichi Yamamoto、Taira Imamura、Toru Suzuki、Masatoshi Fujimoto

  DOI：10.1246/cl.1988.261

  日期：1988.2.5

  Azidomanganese(III) meso-tetraphenylporphyrin, MnIII (tpp)N3, in the solid state was pyrolyzed around 236 °C to yield nitridomanganese (V) meso-tetraphenylporphyrin, MnV (tpp)N.

  固态叠氮锰（III）介四苯基卟啉 MnIII (tpp)N3 在 236 ℃ 左右热解，生成硝基锰（V）介四苯基卟啉 MnV (tpp)N。
• Competitive Photochemical Reactions of Azidomanganese(III) Tetraphenylporphyrin in 2-Methyltetrahydrofuran
  作者：Taira Imamura、Yuichi Yamamoto、Toru Suzuki、Masatoshi Fujimoto

  DOI：10.1246/cl.1987.2185

  日期：1987.11.5

  The photoirradiation of MnIII(tpp)N3 (tpp = meso-tetraphenylporphinato) in the fluid solutions of 2-methyltetrahydrofuran at temperatures of 0 to −70 °C causes competitive reactions between the oxidation of the central manganese of the complex to yield MnV(tpp)N and the reduction to MnII(tpp). The reduction and the oxidation proceed advantageously at 25 °C and at −80 °C respectively.

  MnIII(tpp)N3 (tpp = meso-tetraphenylporphinato) 在 2-甲基四氢呋喃的流体溶液中在 0 至 -70 °C 的温度下进行光辐照会引起络合物中心锰氧化之间的竞争反应，生成 MnV(tpp )N 和还原为 MnII(tpp)。还原和氧化有利地分别在25℃和-80℃下进行。
• Effect of Octabromo Substitution on the Coordination Properties of Manganese(III) Octaphenyltetraazaporphyrin
  作者：M. E. Klyueva、N. V. Repina、N. V. Chizhova

  DOI：10.1007/s11176-005-0355-2

  日期：2005.6

  kinetics of formation of manganese(III) complexes with octaphenyltetraazaporphyrin and its octabromo derivative, of their dissociation and axial ligand exchange were carried out. The effect of octabromo substitution on the coordination properties of the compounds is determined by the -I effect of bromine atoms. The different effects on the kinetic parameters of the reactions [increase in the rate and significant

  对八苯基四氮杂卟啉及其八溴衍生物形成锰（III）配合物的动力学，解离和轴向配体交换进行了比较研究。八溴取代对化合物配位性能的影响取决于溴原子的-I效应。对反应动力学参数的不同影响[速率的增加和复合物形成时活化能的显着降低，解离的减缓以及酸配体与亚硝基（四苯基卟啉）锰（V）的交换加速]是由不同的反应中心参与了极限阶段（过程的不同机理）。
• Stereoelectronic Aspects of Inter-Metal Nitrogen Atom Transfer Reactions between Nitridomanganese(V) and Chromium(III) Porphyrins
  作者：Lawrence A. Bottomley、Frank L. Neely

  DOI：10.1021/ic960919c

  日期：1997.11.1

  Reactions of nitridomanganese(V) porphyrins with chromium(III) porphyrins resulted in the irreversible formation of nitridochromium(V) porphyrins and manganese(III) porphyrins. The progress of these reactions has been followed spectrophotometrically, electrochemically, and spectroscopically by EPR. Kinetic analysis of the spectrophotometric data obtained during these reactions for a variety of substituted porphyrins showed the reactions to be first order in each of the reactants. Rate constants were dependent upon the electronic and steric effects of the porphyrin substituent, upon the identity of the anion bound to the chromium(III) reactant, and upon the solvent dielectric constant. We propose that the mechanism of these nitrogen atom transfer reactions involves the nucleophilic attack of the nitridomanganese porphyrin donor on the cationic chromium(III) porphyrin acceptor facilitating a net, two-electron redox process mediated by a heterobimetallic mu-nitrido intermediate. This report represents the first systematic study of the stereoelectronic effects involved in the complete, inter-metal nitrogen atom transfer between two metalloporphyrins.
• Structural characterization of a complex of Manganese(V) nitrido[tetrakis(p-methoxyphenyl)porphinato] manganese(V)
  作者：Craig L. Hill、Frederick J. Hollander

  DOI：10.1021/ja00389a072

  日期：1982.12