dl-1,2-diphenyl-1,2-ethanedithiol | 42311-15-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: dl-1,2-diphenyl-1,2-ethanedithiol
• 英文别名: meso-α,α'-Stilbendithiol；1,2-Diphenylethane-1,2-dithiol
• CAS: 42311-15-9
• 化学式: C₁₄H₁₄S₂
• 分子量: 246.397
• InChiKey: IUCYKRDPCHMHTM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dl-1,2-diphenyl-1,2-ethanedithiol 、 苯甲醛 在 三氟化硼乙醚 作用下， 生成 (5R)-2,4,5-triphenyl-1,3-dithiolane
  参考文献：
  名称：

  Electrochemical reduction of α,α′-Dibromo-dibenzylsulfone, -sulfoxide, and -sulfide

  摘要：

  DOI：

  10.1016/s0040-4039(01)90440-x
• 作为产物：
  描述：

  4-Phenyl-1,3,2-oxathiazolylium-5-olat 在 phosphate buffer 作用下， 以 乙腈 为溶剂， 生成 、 2,2'-diphenyl-2,2'-disulfanediyl-di-acetic acid 、 dl-1,2-diphenyl-1,2-ethanedithiol 、 α-mercaptophenylacetic acid
  参考文献：
  名称：

  4-Aryl-1,3,2-oxathiazolylium-5-olates 作为 pH 控制的 NO 供体：下一代 S-亚硝基硫醇

  摘要：

  S-亚硝基硫醇 (RSNO) 是生物系统中一氧化氮 (NO) 的重要外源和内源源。合成了一系列具有不同芳基对位取代基（-CF3、-H、-Cl 和 -OCH3）的 4-aryl-1,3,2-oxathiazolylium-5-olates 衍生物。发现这些化合物在酸性条件下（pH = 5）释放 NO。芳基氧杂噻唑盐的分解途径通过酸催化的开环机制进行，然后释放 NO 并产生 S 中心自由基。使用铁 (II) N-甲基-D-葡糖胺二硫代氨基甲酸酯 [(MGD)2-FeII] 和 5,5- 的自旋陷阱进行电子顺磁共振 (EPR) 自旋捕获研究以检测 NO 和 S 中心自由基二甲基-1-吡咯啉N-氧化物(DMPO)。还，EPR自旋捕获和紫外-可见分光光度法用于分析芳基对位取代对芳基恶噻唑盐的NO释放特性的影响。结果表明，-CF3 等吸电子取代基的存在增强了芳基氧杂噻唑基盐酸盐的 NO 释放能力，而供电子取代基如甲氧基

  DOI：

  10.1021/ja0682226

文献信息

• Organo-metal compositions, preparation and use
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0292176A2

  公开（公告）日：1988-11-23

  Complexes of a transition metal and a tetrasubstituted aromatic compound which contain at least two transition metal atoms. At least two of the substituents are -SH groups, the other two substituents being -SH, -OH and -NHR. The complexes are prepared by reacting the tetrasubstituted aromatic compound with a transition metal compound in the presence of a disubstituted aromatic compound. Depending on the relative proportions of the di- and tetra-­substituted compounds, the resulting complex may contain more than one residue from the tetra-substituted compound and more than two transition metal atoms. The complexes possess infra-red absorbing properties which vary in dependence on the particular complex, the complexes with more than one residue from the tetrasubstituted compound absorbing radiation of longer wavelength. The compounds can be used to provide infra-red absorbing compositions, for example as a coating or inter-layer for glass. The complexes may be used together with one or more different infra-red absorbing materials. The tetra-substituted aromatic compound may be a tetra-thiol and this can be prepared from an aromatic compound containing at least four halogen substituents by reaction with an alkaline thiol compound in the presence of iron and sulphur in a polar solvent such as dimethyl formamide.

  过渡金属与四取代芳香化合物的络合物，其中至少含有两个过渡金属原子。其中至少两个取代基为-SH 基团，另外两个取代基为-SH、-OH 和-NHR。这些配合物是通过四取代芳香族化合物与过渡金属化合物在二取代芳香族化合物存在下发生反应而制备的。根据二取代化合物和四取代化合物的相对比例，生成的络合物可能含有一个以上的四取代化合物残基和两个以上的过渡金属原子。这些复合物具有红外线吸收特性，这种特性因特定复合物而异，含有一个以上四取代化合物残基的复合物可吸收波长较长的辐射。这些化合物可用于提供红外线吸收成分，例如玻璃的涂层或中间层。复合物可与一种或多种不同的红外线吸收材料一起使用。四取代芳香族化合物可以是四硫醇，它可以由含有至少四个卤素取代基的芳香族化合物通过与碱性硫醇化合物在铁和硫的存在下在极性溶剂（如二甲基甲酰胺）中反应制备而成。
• High speed moisture cure polyurethane sealant
  申请人：SUNRISE MEISEI CORPORATION

  公开号：EP0370164A2

  公开（公告）日：1990-05-30

  Disclosed herein is a one part moisture cure sealant which is cured under an ordinary temperature by reaction with moisture contained in the air. This sealant contains a cure accelerating catalyst of: in a sealing composite containing urethane prepolymer. Due to the action of this catalyst, not only the cure rate is improved but difference in the cure rate between a low-­temperature/low-humidity season and a high-temperature/high-­humidity season is reduced. This sealant is also excellent in storage stability.

  本文公开了一种单组分湿气固化密封胶，它可在常温下通过与空气中的湿气反应而固化。这种密封剂含有一种固化加速催化剂： 的固化加速催化剂。由于这种催化剂的作用，不仅提高了固化速度，而且减少了低温低湿季节和高温高湿季节固化速度的差异。这种密封胶还具有出色的储存稳定性。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• SCHAUMANN, E.;RUEHTER, G., TETRAHEDRON LETT., 1985, 26, N 43, 5265-5268
  作者：SCHAUMANN, E.、RUEHTER, G.

  DOI：——

  日期：——