9-(Trideuteriomethoxy)fluorene | 88655-95-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 9-(Trideuteriomethoxy)fluorene
• 英文别名: 9-trideuteromethoxyfluorene
• CAS: 88655-95-2
• 化学式: C₁₄H₁₂O
• 分子量: 199.225
• InChiKey: JGLHXBNHKQAROV-FIBGUPNXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  9.23
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  9-(Trideuteriomethoxy)fluorene 在 甲醇 作用下， 反应 0.17h， 生成 9,9'-联芴 、 9-Deutero-fluoren 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Contrasting photosolvolytic reactivities of 9-fluorenol vs. 5-suberenol derivatives. Enhanced rate of formation of cyclically conjugated four .pi. carbocations in the excited state

  摘要：

  DOI：

  10.1021/ja00195a048
• 作为产物：
  描述：

  9-溴芴 在 氘代甲醇 作用下， 反应 48.0h， 以76%的产率得到9-(Trideuteriomethoxy)fluorene
  参考文献：
  名称：

  Contrasting photosolvolytic reactivities of 9-fluorenol vs. 5-suberenol derivatives. Enhanced rate of formation of cyclically conjugated four .pi. carbocations in the excited state

  摘要：

  DOI：

  10.1021/ja00195a048

文献信息

• Electronic effects on the substitution reactions of benzhydrols and fluorenyl alcohols. Determination of mechanism and effects of antiaromaticity
  作者：Stephen R. D. George、Timothy E. Elton、Jason B. Harper

  DOI：10.1039/c5ob01637a

  日期：——

  Fusion of benzhydrols to give fluorenols is found to not affect the electronic susceptibility of substitution reactions suggesting the antiaromaticity of the intermediate serves simply to slow the process.

  将联苯酚融合成氟酚，发现它并不影响取代反应的电子敏感性，这表明中间体的反芳香性仅用于减慢过程。
• Further mass spectral studies of flavones
  作者：F. H. Guidugli、C. E. Ardanaz、J. Kavka、M. E. Garibay、P. Joseph-Nathan

  DOI：10.1002/oms.1210210305

  日期：1986.3

  AbstractFurther evidence supporting the structure of the [M − 1]+ ion found in the mass spectrum of flavone as being the [dibenzo‐β‐tropolone − H]+ species was obtained by comparison of linked scan measurements performed in flavone, 3‐deuteroflavone, 5,6,7,8‐tetradeuteroflavone, 2′,3′,4′,5′,6′‐pentadeuteroflavone and dibenzo‐β‐tropolone. This fragmentation process has also been demonstrated in the case of 3‐methoxyflavone by high‐resolution measurements, deuterium labelling, metastable decompositions and evaluation of the subspectra of 9‐methoxyfluorenol, fluorenone and biphenylene. The structure of the ion at m/z 181 in the spectrum of flavone was found to be the [2‐phenylbenzoxetane − 1]+ species.
• Contrasting photosolvolytic reactivities of 9-fluorenol vs. 5-suberenol derivatives. Enhanced rate of formation of cyclically conjugated four .pi. carbocations in the excited state
  作者：Peter Wan、Erik Krogh

  DOI：10.1021/ja00195a048

  日期：1989.6