γ-aminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclooctane | 389082-07-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: γ-aminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclooctane
• 英文别名: 3-(2-Methyl-6-phenyl-1,3,6,2-dioxazasilocan-2-yl)propan-1-amine
• CAS: 389082-07-9
• 化学式: C₁₄H₂₄N₂O₂Si
• 分子量: 280.442
• InChiKey: WAJSINJFEYEDNG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.96
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  47.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,4-二氯苯甲醛 、 γ-aminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclooctane 在 potassium carbonate 作用下， 以 苯 为溶剂， 反应 2.0h， 以99%的产率得到γ-N-(m,p-dichlorobenzylidene)aminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclooctane
  参考文献：
  名称：

  SYNTHESIS OF γ-N-ARYLIDENEAMINOPROPYL-2-METHYL-6-PHENYL-1,3-DIOXA-6-AZA-2-SILACYCLOOCTANES

  摘要：

  Several new gamma -N-arylideneaminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclo octanes have been prepared by the reaction of gamma -aminopropyldimethoxymethylsilane with phenyldiethanolamine first and then with arylaldehydes. The products were identified by elemental analyses, IR and H-1 NMR.

  DOI：

  10.1081/scc-100107022
• 作为产物：
  描述：

  3-氨丙基二甲氧基甲基硅烷 、 N,N-二羟乙基苯胺 以 甲苯 为溶剂， 反应 10.0h， 以81%的产率得到γ-aminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclooctane
  参考文献：
  名称：

  SYNTHESIS OF γ-N-ARYLIDENEAMINOPROPYL-2-METHYL-6-PHENYL-1,3-DIOXA-6-AZA-2-SILACYCLOOCTANES

  摘要：

  Several new gamma -N-arylideneaminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclo octanes have been prepared by the reaction of gamma -aminopropyldimethoxymethylsilane with phenyldiethanolamine first and then with arylaldehydes. The products were identified by elemental analyses, IR and H-1 NMR.

  DOI：

  10.1081/scc-100107022

文献信息

• SYNTHESIS OF γ-<i>N</i>-ARYLIDENEAMINOPROPYL-2-METHYL-6-PHENYL-1,3-DIOXA-6-AZA-2-SILACYCLOOCTANES
  作者：Fangzheng Li、Jimao Lin、Qinzheng Yang

  DOI：10.1081/scc-100107022

  日期：2001.1

  Several new gamma -N-arylideneaminopropyl-2-methyl-6-phenyl-1,3-dioxa-6-aza-2-silacyclo octanes have been prepared by the reaction of gamma -aminopropyldimethoxymethylsilane with phenyldiethanolamine first and then with arylaldehydes. The products were identified by elemental analyses, IR and H-1 NMR.