N-octadecylperylene-3,4:9,10-tetracarboxylic-3,4-anhydride-9,10-imide | 183863-10-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并吡喃类
• 英文名称: N-octadecylperylene-3,4:9,10-tetracarboxylic-3,4-anhydride-9,10-imide
• 英文别名: 18-Octadecyl-7-oxa-18-azaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 183863-10-7
• 化学式: C₄₂H₄₅NO₅
• 分子量: 643.823
• InChiKey: JPLAHXSMWWCAPL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  48
• 可旋转键数：
  17
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  80.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,8-二氨基萘 、 N-octadecylperylene-3,4:9,10-tetracarboxylic-3,4-anhydride-9,10-imide 以 various solvent(s) 为溶剂， 反应 24.0h， 以71%的产率得到24-Octadecyl-3,13,24-triazadecacyclo[16.14.2.219,22.14,8.02,13.015,33.020,29.021,26.030,34.012,37]heptatriaconta-1(33),2,4,6,8(37),9,11,15,17,19(36),20(29),21(26),22(35),27,30(34),31-hexadecaene-14,23,25-trione
  参考文献：
  名称：

  Synthesis and Properties of Benzimidazole and Naphthoimidazole Derivatives of Perylenedicarboximide

  摘要：

  Benzimidazole and naphthoimidazole derivatives of N-alkylperylene-dicarboximide were prepared by the condensation of N-alkyl-3,4:9,10-perylene-tetracarboxylic acid monoanhydride monoimide with o-phenylenediamine and diaminonaphthalenes. Properties of these derivatives as pigments were tested, and the thermal stability and solubility of these derivatives were also investigated.

  DOI：

  10.3987/com-00-s(i)64
• 作为产物：
  描述：

  十八胺 、 3,4:9,10-perylenetetracarboxylic monoanhydride monopotassium salt 以 丙醇 、 水 为溶剂， 反应 2.0h， 以66%的产率得到N-octadecylperylene-3,4:9,10-tetracarboxylic-3,4-anhydride-9,10-imide
  参考文献：
  名称：

  Surface-enhanced fluorescence and SERRS spectra of N-octadecyl-3,4:9,10-perylenetetracarboxylic monoanhydride on silver island films

  摘要：

  The Langmuir-Blodgett (LB) technique has been used to fabricate monolayers of N-octadecyl-3,4:9,10-perylenetetracarboxylic monoanhydride monoimide (OD-PTCO) on infrared transparent windows, glass and silver island substrates. The long alkyl chain CH3-(CP2)(17)-PTCO, a perylene derivative with a low quantum yield, was specially synthesized for the study of the electromagnetically surface-enhanced fluorescence (SEF). It is shown that lame enhancement factors for SEF (>10) are obtained for OD-PTCO LB films deposited on silver island films of 6, 10 and 14 nm mass thickness. The three-dimensional images of the silver island films used to produce surface-enhanced spectra were obtained by atomic force microscopy. The delicate interplay between energy transfer and electromagnetic enhancement are illustrated by spectra containing the surface-enhanced resonant Raman scattering and SEF effects in the same spectral region. The infrared and resonance Raman scattering spectra of the bulk and LB films are also reported. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s1386-1425(97)83023-5

文献信息

• Active Regulation of Supramolecular Chirality through Integration of CdSe/CdS Nanorods for Strong and Tunable Circular Polarized Luminescence
  作者：Rongjuan Liu、Zhenyu Feng、Caikun Cheng、Hui Li、Jiaming Liu、Jingjing Wei、Zhijie Yang

  DOI：10.1021/jacs.1c12676

  日期：2022.2.9

  the chirality switching from folding to unfolding of 2D supramolecular nanosheets, akin to the chirality inversion in the helix-to-superhelix transition in conventional one-dimensional (1D) supramolecular systems. We also show that the strong van der Waals interactions from aliphatic chains are crucial in achieving such chirality transfer and inversion. Overall, we demonstrate that these achiral CdS/CdSe

  在人工自组装系统中建立协同性将协同重塑其特性并扩大其应用范围。在这里，我们展示了非手性 CdSe/CdS 纳米棒 (NRs) 和手性苝二亚胺 (PDI) 基分子之间的协同性如何建立在它们的共组装之上。我们证明了从手性分子组装体到 CdSe/CdS NRs 的手性转移是通过链 - 链范德华相互作用将 NRs 封装到 PDI 上卷中实现的，这反过来又导致纳米复合材料的圆偏振发光显着增强。此外，纳米复合材料的圆偏振发射带可以通过设计 NR 的发射带进行微调。更重要的是，当 NR 在大量 NR 下自组装成手性超晶格时，这些纳米复合材料能够反转其手性。详细的机理研究表明，这些卡住的 NRs 组件阻碍了二维 (2D) 手性纳米片的折叠，从而抑制了层间激子耦合并实现了具有反向手性的纳米复合材料。我们的发现举例说明了一种反转二维超分子纳米片从折叠到展开的手性转换的方法，类似于传统一维（1D）超分子系统中螺
• Self-Assembly of Amphiphilic Perylene−Cyclodextrin Conjugate and Vapor Sensing for Organic Amines
  作者：Bang-Ping Jiang、Dong-Sheng Guo、Yu Liu

  DOI：10.1021/jo1014596

  日期：2010.11.5

  An asymmetric, amphiphilic perylene bisimide derivative 1 was synthesized by grafting permethyl-beta-cyclodextrin at one side and an octadecyl chain at the other side. Its aggregation capability and morphology, which attract intense interest, were carefully examined by combination of UV-vis, NMR, and fluorescence spectroscopy, DLS, XRD, TEM, and SEM. By adjusting the volume ratio of water and methanol, we are able to control the morphology, benefiting from the amphiphilicity of 1. Furthermore, the particular resulting aggregates were employed as solid-state fluorescence sensing for organic amines. An improvement or both selectivity and sensitivity is achieved compared to previous publications.