1,4-bis-dichlorophosphinooxy-benzene | 41105-12-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis-dichlorophosphinooxy-benzene
• 英文别名: Hydrochinondiphosphorigsaeure-tetrachlorid；p-Phenylendiphosphorigsaeure-tetrachlorid；1,4-Bis-dichlorphosphinooxy-benzol；Dichloro-(4-dichlorophosphanyloxyphenoxy)phosphane
• CAS: 41105-12-8
• 化学式: C₆H₄Cl₄O₂P₂
• 分子量: 311.856
• InChiKey: UMESBNRNSWZBCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-bis-dichlorophosphinooxy-benzene 在 乙醚 、 水 作用下， 生成 1,4-phenylene bisphosphoric acid
  参考文献：
  名称：

  Process for the manufacture of phosphoric esters of phenols

  摘要：

  公开号：

  US02345690A1
• 作为产物：
  描述：

  对苯二酚 在 三氯化磷 作用下， 生成 1,4-bis-dichlorophosphinooxy-benzene
  参考文献：
  名称：

  Knauer, Chemische Berichte, 1894, vol. 27, p. 2566

  摘要：

  DOI：

文献信息

• 2,6-Di-tertiary butyl phenyl phosphites and synthetic resin compositions containing these phosphites
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0033395A2

  公开（公告）日：1981-08-12

  2,6-Di-tertiary butyl phenyl phosphites are provided having the structure: wherein: R is selected from the group consisting of hydrogen, methyl, ethyl, and (CH2)mCOOR, where R is selected from the group consisting of alkyl having from one up to about ten carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about twelve carbon atoms; and m is a number within the range from 0 to 5; R2 is selected from the group consisting of hydrogen, alkyl having from one to about twenty-two carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; the residue of a polyhydric alcohol having from two to about eighteen carbon atoms, and from two to three hydroxyl groups; and the residue of a polyphenol having from six to about eighteeen carbon atoms and from two to about ten phenolic hydroxyl groups; R3 is selected from the group consisting of hydrogen and P(OR2)2; Z is the bivalent or trivalent residue of a polyhydric alcohol having from two to about eighteen carbon atoms, and from two to three hydroxyl groups; or of a polyphenol having from six to about eighteen carbon atoms and from two to about ten phenolic hydroxyl groups; n, is 0 or 1; and n2 is a number from 1 to 5; as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and/or light due to the presence of an organic phosphite of this class.

  2,6-二叔丁基苯基亚磷酸酯具有以下结构： 其中 R选自由氢、甲基、乙基和(CH2)mCOOR组成的组，其中R选自由具有1至约10个碳原子的烷基、具有3至约12个碳原子的环烷基、具有6至约12个碳原子的烷芳基和芳基组成的组，m是0至5范围内的数字； R2 选自由氢、具有 1 至约 22 个碳原子的烷基、具有 3 至约 12 个碳原子的环烷基、具有 6 至约 18 个碳原子的烷芳基和芳基、具有 2 至约 18 个碳原子和 2 至 3 个羟基的多元醇残基、具有 6 至约 8 个碳原子和 2 至约 10 个酚羟基的多元酚残基组成的组； R3 选自氢和 P(OR2)2 组成的组； Z 是二价或三价多元醇的残基，该多元醇具有 2 至约 18 个碳原子和 2 至 3 个羟基；或具有 6 至约 18 个碳原子和 2 至约 10 个酚羟基的多元酚的残基； n 是 0 或 1；以及 n2 是 1 至 5 的数字；以及合成树脂组合物，由于含有该类有机亚磷酸酯，其耐热和/或耐光变质的性能得到增强。
• Sunagawa et al., Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1957, vol. 77, p. 1176,1179
  作者：Sunagawa et al.

  DOI：——

  日期：——
• Appel, Rolf; Schulte, Peter; Knoch, Falk, Phosphorus and Sulfur and the Related Elements, 1988, vol. 36, p. 147 - 152
  作者：Appel, Rolf、Schulte, Peter、Knoch, Falk

  DOI：——

  日期：——
• US4371646A
  申请人：——

  公开号：US4371646A

  公开（公告）日：1983-02-01
• Knauer, Chemische Berichte, 1894, vol. 27, p. 2566
  作者：Knauer

  DOI：——

  日期：——