N,N-双(三甲基硅烷基)-5-己烯-1-胺 | 89333-68-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: N,N-双(三甲基硅烷基)-5-己烯-1-胺
• 英文名称: 6-bis(trimethylsilyl)amino-1-hexene
• 英文别名: N-(Hex-5-en-1-yl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine；N,N-bis(trimethylsilyl)hex-5-en-1-amine
• CAS: 89333-68-6
• 化学式: C₁₂H₂₉NSi₂
• 分子量: 243.54
• InChiKey: WPAKSPNQLFRAMN-UHFFFAOYSA-N

物化性质

• 沸点：
  257.4±33.0 °C(Predicted)
• 密度：
  0.810±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.31
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N-双(三甲基硅烷基)-5-己烯-1-胺 在 sodium hypochlorite 、 dimethylborane 、 氨 作用下， 生成 1,6-己二胺
  参考文献：
  名称：

  Kabalka, George W.; Wang, Zhe, Synthetic Communications, 1990, vol. 20, # 14, p. 2113 - 2118

  摘要：

  DOI：
• 作为产物：
  描述：

  氨基甲基化试剂A 、 5-溴-1-戊烯 在 magnesium 作用下， 以 乙醚 为溶剂， 反应 4.0h， 以73%的产率得到N,N-双(三甲基硅烷基)-5-己烯-1-胺
  参考文献：
  名称：

  New Polyethylene Based Anion Exchange Membranes (PE–AEMs) with High Ionic Conductivity

  摘要：

  This paper discusses a new class of high performance polyethylene-based anion exchange membranes (PE-AEMs) that contain a wide concentration range of pendant (flexible) ammonium chloride (NR(3)(+)Cl(-)) groups and with or without a cross-linked PE matrix structure. The chemistry involves a metallocene-mediated polymerization of ethylene, silane-protected alpha,omega-aminoolefin [C(x)N(SiMe(3))(2)], with or without styrenic diene (crosslinker), to form ethylene/C(x)N(SiMe(3))(2) copolymers and ethylene/C,N(SiMe(3))(2)/diene terpolymers, respectively. The resulting co- and ter-polymers were completely soluble in common organic solvents and were solution-casted into uniform films (thickness, 50-70 mu m; without backing material) and then thermal cross-linked in ethylene/C(x)N(SiMe(3))(2)/diene case, further interconverting the silane-protected amino groups into the desired -NR(3)(+)Cl(-) groups (R: H, CH(3), and C(3)H(7)) under solid state conditions. The resulting PE-NR(3)(+)Cl(-) and cross-linked x-PE-N(CH(3))(3)(+)Cl(-) membranes were systematically studied to understand how the PE structure (-NR(3)(+)Cl(-) concentration, R group, cross-linking density, ete.) affects ionic conductivity, water uptake, film stability, and ion selectivity. For comparison, several commercially available AEMs were also examined. Evidently, an x-PE-N(CH(3))(3)(+)Cl(-) membrane, with 28.1 mol % -N(CH(3))(3)(+)Cl(-) groups and 0.2 mol 96 cross-linkers, shows moderate water swelling and outperforms all commercial membranes with exceptionally high ionic conductivities of 119.6 mS/cm in 2 N HCl solution and 78.8 mS/cm in 2 N HCl-0.2N CuCl solution at room temperature.

  DOI：

  10.1021/ma200836d

文献信息

• New preparation of N,N-bis(trimethylsilyl)enamines via iron carbonyl photocatalysed isomerisation of unsaturated amines
  作者：R.J.P. Corriu、V. Huynh、J.J.E. Moreau、M. Pataud-Sat

  DOI：10.1016/s0022-328x(00)99329-x

  日期：1983.10

  A new synthesis of N,N-bis(trimethylsilyl)enamines from straight chain olefinic amines has been devised which makes use of iron pentacarbonyl photocatalysed isomerisation. Complete conversion of the olefinic amines to the enamines was observed for substituted N,N-bis(trimethylsilyl)allylamines and non-allylic amines. The enamines obtained are potential sources of aldehydes and precursors of substituted

  已经设计了利用五羰基铁光催化异构化的由直链烯烃胺合成N，N-双（三甲基甲硅烷基）烯胺的新方法。对于取代的N，N-双（三甲基甲硅烷基）烯丙基胺和非烯丙基胺，观察到烯烃胺完全转化为烯胺。获得的烯胺是醛和取代的氮杂-2-丁二烯的前体的潜在来源。
• Controlled functionalization of poly(4-methyl-1-pentene) films for high energy storage applications
  作者：Min Zhang、Lin Zhang、Meng Zhu、Yiguang Wang、Nanwen Li、Zhijie Zhang、Quan Chen、Linan An、Yuanhua Lin、Cewen Nan

  DOI：10.1039/c5ta09949h

  日期：——

  A new family of poly(4-methyl-1-pentene) ionomers with high energy density at a high breakdown strength, high charge-discharge energy efficiency and a very narrow breakdown distribution for energy storage in future capacitor devices.

  一种新的聚（4-甲基-1-戊烯）离子聚合物家族，具有高能量密度、高击穿强度、高充放电能量效率和非常窄的击穿分布，可用于未来电容器设备中的能量存储。
• CORRIU, R. J. P.;HUYNH, V.;MOREAU, J. J. E.;PATAUD-SAT, M., J. ORGANOMET. CHEM., 1983, 255, N 3, 359-364
  作者：CORRIU, R. J. P.、HUYNH, V.、MOREAU, J. J. E.、PATAUD-SAT, M.

  DOI：——

  日期：——
• Kabalka, George W.; Wang, Zhe, Synthetic Communications, 1990, vol. 20, # 14, p. 2113 - 2118
  作者：Kabalka, George W.、Wang, Zhe

  DOI：——

  日期：——
• New Polyethylene Based Anion Exchange Membranes (PE–AEMs) with High Ionic Conductivity
  作者：Min Zhang、Hyung Kyu Kim、Elena Chalkova、Fedkin Mark、Serguei N. Lvov、T. C. Mike Chung

  DOI：10.1021/ma200836d

  日期：2011.8.9

  This paper discusses a new class of high performance polyethylene-based anion exchange membranes (PE-AEMs) that contain a wide concentration range of pendant (flexible) ammonium chloride (NR(3)(+)Cl(-)) groups and with or without a cross-linked PE matrix structure. The chemistry involves a metallocene-mediated polymerization of ethylene, silane-protected alpha,omega-aminoolefin [C(x)N(SiMe(3))(2)], with or without styrenic diene (crosslinker), to form ethylene/C(x)N(SiMe(3))(2) copolymers and ethylene/C,N(SiMe(3))(2)/diene terpolymers, respectively. The resulting co- and ter-polymers were completely soluble in common organic solvents and were solution-casted into uniform films (thickness, 50-70 mu m; without backing material) and then thermal cross-linked in ethylene/C(x)N(SiMe(3))(2)/diene case, further interconverting the silane-protected amino groups into the desired -NR(3)(+)Cl(-) groups (R: H, CH(3), and C(3)H(7)) under solid state conditions. The resulting PE-NR(3)(+)Cl(-) and cross-linked x-PE-N(CH(3))(3)(+)Cl(-) membranes were systematically studied to understand how the PE structure (-NR(3)(+)Cl(-) concentration, R group, cross-linking density, ete.) affects ionic conductivity, water uptake, film stability, and ion selectivity. For comparison, several commercially available AEMs were also examined. Evidently, an x-PE-N(CH(3))(3)(+)Cl(-) membrane, with 28.1 mol % -N(CH(3))(3)(+)Cl(-) groups and 0.2 mol 96 cross-linkers, shows moderate water swelling and outperforms all commercial membranes with exceptionally high ionic conductivities of 119.6 mS/cm in 2 N HCl solution and 78.8 mS/cm in 2 N HCl-0.2N CuCl solution at room temperature.