2,4,6-三(甲基硫烷基)苯酚 | 90033-58-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 2,4,6-三(甲基硫烷基)苯酚
• 英文名称: 2,4,6-Trisphenol
• 英文别名: 2,4,6-Tris(methylsulfanyl)phenol
• CAS: 90033-58-2
• 化学式: C₉H₁₂OS₃
• 分子量: 232.392
• InChiKey: GXJRCSYIGYLJOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  96.1
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-(甲硫基)苯酚 生成 2,4,6-三(甲基硫烷基)苯酚
  参考文献：
  名称：

  RANKEN, P. F.

  摘要：

  DOI：

文献信息

• Thioether substituted aryl carbonate protecting groups
  申请人：Timar Zoltan

  公开号：US20080146787A1

  公开（公告）日：2008-06-19

  Embodiments of the invention include thioether substituted aryl carbonate protecting groups, and nucleoside monomers protected with thioether substituted aryl carbonate protecting groups. Aspects of the invention further included methods of synthesizing nucleic acids, e.g., oligonucleotides, using such protected nucleoside monomer monomers, as well as nucleic acids produced using methods of the invention and compositions thereof.

  本发明的实施方式包括硫醚取代的芳基碳酸酯保护基，以及使用硫醚取代的芳基碳酸酯保护基保护的核苷单体。本发明的方面还包括使用这种受保护的核苷单体单体合成核酸（例如寡核苷酸）的方法，以及使用本发明的方法合成的核酸及其组成物。
• TRANSITION METAL COMPOUND AND CATALYST FOR OLEFIN POLYMERIZATION
  申请人：HANAOKA Hidenori

  公开号：US20110319578A1

  公开（公告）日：2011-12-29

  A transition metal compound represented by the formula (1-1) or the formula (1-2) (M is a transition metal atom) and a process for producing a catalyst for olefin polymerization comprising a step of bringing the transition metal compound into contact with a co-catalytic component for activation.

  一种由化学式(1-1)或化学式(1-2)所代表的过渡金属化合物（其中M是一种过渡金属原子）和制备催化剂的方法，包括将该过渡金属化合物与协同催化剂成分接触以激活的步骤。
• METHOD FOR PRODUCING OLEFIN BLOCK POLYMER USING GROUP 4 TRANSITION METAL COMPLEX
  申请人：Sumitomo Chemical Company, Limited.

  公开号：US20140163173A1

  公开（公告）日：2014-06-12

  A method for producing an olefin block polymer, the method including: polymerizing olefins using a polymerization catalyst (X) and an organometallic compound (C) containing an atom of any of Groups 2, 12, and 13 of the periodic table of the elements, the organometallic compound (C) excluding an activating co-catalyst agent (B), wherein the polymerization catalyst (X) is formed by bringing a transition metal compound (A) into contact with the activating co-catalyst agent (B), the transition metal compound (A) is represented by the following general formula (1), and the activating co-catalyst agent (B) is selected from among an organoaluminumoxy compound (B-1), an organoboron compound (B-2), a zinc co-catalyst component (B-3), and ion-exchange layered silicate (B-4).

  一种生产烯烃块状聚合物的方法，包括：使用聚合催化剂（X）和含有元素周期表2组、12组和13组中任意一种元素的有机金属化合物（C）聚合烯烃，其中有机金属化合物（C）不包括活化共催化剂（B），聚合催化剂（X）通过将过渡金属化合物（A）与活化共催化剂（B）接触形成，过渡金属化合物（A）由下列通式（1）表示，活化共催化剂（B）从有机铝氧化合物（B-1）、有机硼化合物（B-2）、锌共催化组分（B-3）和离子交换层状硅酸盐（B-4）中选取。
• (Hydrocarbylthio)phenols and their preparation
  申请人：ETHYL CORPORATION

  公开号：EP0122203A1

  公开（公告）日：1984-10-17

  (Hydrocarbylthio)phenols containing at leasttwo hydrocarbylthio groups or hydrocarbylthio groups in either or both of the meta positions, relative to the hydroxy group, on a phenolic ring are prepared by reacting phenolic compounds with an excess of hydrocarbyl disulfide in the presence of catalytic amounts of an aluminium phenoxide. Novel and useful (hydrocarbylthio)phenols containing at least two hydrocarbylthio groups or hydrocarbylthio groups in either of both of the meta positions, relative to the hydroxy group, on a phenolic ring can be prepared by this process. (Hydrocarbylthio)phenols containing at least two hydrocarbylthio groups or hydrocarbylthio groups in either of both of the meta positions, relative to the hydroxy group, on a phenolic ring are effective antioxidants for organic material normally susceptible to oxidative deterioration, such as mineral oil.

  (相对于羟基而言，在酚环的任一或两个元位置上至少含有两个烃硫基或烃硫基的（烃硫基）酚，是通过在催化量的苯氧化铝存在下，使酚类化合物与过量的二硫化烃反应制备的。通过这种方法可以制备出新的有用的（烃基硫基）酚，这些酚至少含有两个烃基硫基，或者烃基硫基位于酚环上相对于羟基的两个元位置中的一个。(在酚醛环上相对于羟基的两个元位置中的任一位置上含有至少两个烃硫基或烃硫基的（烃硫基）苯酚是通常易氧化变质的有机材料（如矿物油）的有效抗氧化剂。
• RESIN COMPOSITION, CROSS-LINKED PRODUCT, AND METHOD FOR MANUFACTURING CROSS-LINKED PRODUCT
  申请人：Sumitomo Chemical Company Limited

  公开号：EP3130635A1

  公开（公告）日：2017-02-15

  There are provided a resin composition capable of affording a cross-linked foam excellent in heat storage performance, a cross-linked product of the resin composition, and a method for producing the cross-linked product. Specifically, there is provided a resin composition containing an olefin polymer comprising a main chain containing monomer units derived from ethylene and branch chains having 5 or more carbon atoms, the number of the branch chains being within the range of 20 chains to 40 chains per 1000 carbon atoms constituting the olefin polymer, and having a melting peak temperature measured with DSC of within the range of 10°C to 50°C, a crystallization peak temperature measured with DSC of within the range of 0°C to 40°C, and a melt enthalpy measured with DSC of 50 J/g or more, and an olefin polymer having a melting peak temperature measured with DSC of within the range of 50°C to 180°C.

  本发明提供了一种能够产生蓄热性能优异的交联泡沫的树脂组合物、该树脂组合物的交联产品以及生产该交联产品的方法。具体地说，提供了一种含有烯烃聚合物的树脂组合物，该烯烃聚合物由含有来自乙烯的单体单元的主链和具有 5 个或更多碳原子的支链组成，构成烯烃聚合物的每 1000 个碳原子中支链的数量在 20 至 40 个范围内、用 DSC 测得的熔融峰值温度在 10°C 至 50°C 范围内，用 DSC 测得的结晶峰值温度在 0°C 至 40°C 范围内，用 DSC 测得的熔融焓在 50 J/g 或以上，以及用 DSC 测得的熔融峰值温度在 50°C 至 180°C 范围内的烯烃聚合物。