Rhodium-catalyzed sulfur atom exchange reaction between organic polysulfides and sulfur
作者:Mieko Arisawa、Ken Tanaka、Masahiko Yamaguchi
DOI:10.1016/j.tetlet.2005.05.024
日期:2005.7
RhH(PPh3)4 and cis-1,2-bis(diphenylphosphino)ethylene (dppv) catalyze the exchange of sulfur atoms betweensulfur and organic polysulfides. The exchange of dialkyl trisulfides with sulfur proceeds at a high efficiency within 5 min at room temperature yielding a mixture of organic polysulfides.
A lubricant composition comprising a major proportion of polyalkylene glycol of lubricating viscosity and a minor proportion dissolved therein of (a) at least one sulphur-containing antiwear or extreme pressure agent, (b) at least one amine salt of at least one partially esterified monothiophosphoric acid, and (c) at least one amine salt of at least one partially esterified phosphoric acid. Such compositions have improved resistance to wear, oxidative degradation and metallic corrosion.
TRIPHENYLBORON COMPOUND-CONTAINING ANTIFOULING COATING COMPOSITION HAVING IMPROVED STABILITY, ANTIFOULING AGENT SET USED THEREFOR, AND METHOD FOR SUPPRESSING/CONTROLLING DECOMPOSITION OF TRIPHENYLBORON COMPOUND
申请人:CHUGOKU MARINE PAINTS, LTD.
公开号:EP2161318A1
公开(公告)日:2010-03-10
An object of the present invention is to provide an antifouling coating material composition in which, though containing a triphenylboron compound as an antifouling agent, the triphenylboron compound is inhibited from being decomposed in production and long term storage and which is excellent in a storage stability and a static antifouling property of an antifouling coating film obtained therefrom.
The antifouling coating material composition of the present invention comprises at least (A) a coating film-forming resin and (B) a triphenylboron-amine complex (b1) as an antifouling agent, and it further comprises (C) an amine compound other than the triphenylboron-amine complex (b1) described above as a decomposition inhibitor for the above compound (b1). A content of the amine compound (C) described above is preferably a proportion of 1.0 to 210 parts by weight per 100 parts by weight of the component (b1).