1-(phenyldiazenyl)naphthalen-2-yl acetate | 39781-22-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-(phenyldiazenyl)naphthalen-2-yl acetate
• 英文别名: 1-Benzolazo-2-acetoxy-naphthalin；1-Phenylazo-2-naphtholacetat；2-Acetoxy-1-benzolazo-naphthalin；acetic acid-(1-phenylazo-[2]naphthyl ester)；Essigsaeure-(1-phenylazo-[2]naphthylester)；1-Phenylazo-2-acetoxy-naphthalin；1-Benzolazo-naphthol-(2)-acetat；(1-Phenyldiazenylnaphthalen-2-yl) acetate
• CAS: 39781-22-1
• 化学式: C₁₈H₁₄N₂O₂
• 分子量: 290.321
• InChiKey: CTYKHGHSEZKQEQ-UHFFFAOYSA-N

物化性质

• 熔点：
  117 °C
• 沸点：
  470.4±28.0 °C(Predicted)
• 密度：
  1.16±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  51
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-(phenyldiazenyl)naphthalen-2-yl acetate 在 乙醇 、 溶剂黄146 、 锌 作用下， 生成 1-氨基-2-萘酚
  参考文献：
  名称：

  Goldschmidt; Brubacher, Chemische Berichte, 1891, vol. 24, p. 2305

  摘要：

  DOI：
• 作为产物：
  描述：

  2-萘酚 在 potassium nitrite 、 乙醇 、 水 作用下， 生成 1-(phenyldiazenyl)naphthalen-2-yl acetate
  参考文献：
  名称：

  Ocular Scrofuloderma with Unilateral Proptosis

  摘要：

  AbstractProptosis due to an extraconal orbital abscess of tubercular origin with lacrimal gland involvement, representing ocular scrofuloderma, is a rare entity. This association has not been reported earlier in the literature. We describe a 7‐year‐old boy who presented with nodulo‐ulcerative lesions of tubercular etiology with discharging sinuses on right side of the face and a similar lesion on the right lower eyelid along with proptosis of 4 months duration. Computerized tomography (CT) scan of the head confirmed the extraconal, intraorbital, hyperdense, homogeneously enhancing mass separated from the lateral rectus muscle and further revealed involvement of lacrimal gland along with erosion of the temporal bone. The patient showed marked improvement of his dermatological and ophthalmological lesions with anti‐tubercular treatment. Subsequent ultrasound examinations of the orbit revealed regression in the size of the abscess from 10.7 mm to 5.0 mm and then complete disappearance of the abcess obviating surgical intervention.

  DOI：

  10.1111/j.1346-8138.2002.tb00255.x

文献信息

• Unusual fluorescence of <i>o</i>-phenylazonaphthol derivatives with aggregation-induced emission and their use in two-photon cell imaging
  作者：Yeoju Yoon、Seonyoung Jo、Sang Jun Park、Hwan Myung Kim、Dongwook Kim、Taek Seung Lee

  DOI：10.1039/c9cc03106e

  日期：——

  Unusual fluorescence of o-phenylazonaphthol derivatives with aggregated-induced emission (AIE) is reported for the first time, which can be used in two-photon cell imaging applications.

  首次报道了具有聚集诱导发光（AIE）特性的o-苯基偶氮萘酚衍生物的异常荧光，可用于双光子细胞成像应用。
• Bigiavi; Cerchiai, Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1922, vol. <5> 31 II, p. 28
  作者：Bigiavi、Cerchiai

  DOI：——

  日期：——
• Meldola; Morgan, Journal of the Chemical Society, 1889, vol. 55, p. 124
  作者：Meldola、Morgan

  DOI：——

  日期：——
• Meldola; Burls, vol. 63, p. 931
  作者：Meldola、Burls

  DOI：——

  日期：——
• Meldola; East, Journal of the Chemical Society, 1888, vol. 53, p. 466
  作者：Meldola、East

  DOI：——

  日期：——