Phenylsulfonyltrifluoroacetate | 72500-14-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenylsulfonyltrifluoroacetate
• 英文别名: Benzenesulfonyl 2,2,2-trifluoroacetate
• CAS: 72500-14-2
• 化学式: C₈H₅F₃O₄S
• 分子量: 254.187
• InChiKey: NICFWSSESJXYOB-UHFFFAOYSA-N

物化性质

• 熔点：
  39-42 °C(Solv: ethyl ether (60-29-7))
• 沸点：
  80-82 °C(Press: 2 Torr)
• 密度：
  1.516±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  68.8
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  Phenylsulfonyltrifluoroacetate 反应 3.5h， 生成 [dimethyl-[(2-oxopyrrolidin-1-yl)methyl]silyl] benzenesulfonate
  参考文献：
  名称：

  Baukov, Yu. I.; Kramarova, E. P.; Shipov, A. G., Journal of general chemistry of the USSR, 1989, vol. 59, # 1.2, p. 110 - 125

  摘要：

  DOI：
• 作为产物：
  描述：

  苯磺酸甲酯 反应 2.0h， 生成 Phenylsulfonyltrifluoroacetate
  参考文献：
  名称：

  Shipov, A. G.; Baukov, Yu. I., Journal of general chemistry of the USSR, 1984, vol. 54, # 8, p. 1642 - 1657

  摘要：

  DOI：

文献信息

• [EN] QUINAZOLINE CARBOXAMIDE AZETIDINES<br/>[FR] QUINAZOLINE CARBOXAMIDE AZÉTIDINES
  申请人：MERCK PATENT GMBH

  公开号：WO2012069146A1

  公开（公告）日：2012-05-31

  The invention provides novel quinazoline carboxamide azetidine compounds according to Formula (I) and use for the treatment of hyperproliferative diseases, such as cancer.

  本发明提供了一种新型的喹唑啉羧酰胺氮杂环化合物，其化学式为(I)，并可用于治疗高增殖性疾病，如癌症。
• Positive resist composition
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20020058200A1

  公开（公告）日：2002-05-16

  A positive resist composition comprises (A) a resin capable of decomposing by the action of an acid to increase solubility in an alkali developer, and (B) a compound capable of generating an aromatic sulfonic acid substituted with at least one group containing a fluorine atom upon irradiation with one of an actinic ray and radiation.

  一种正性光刻胶组合物包括(A)一种能够通过酸的作用分解以增加在碱性显影剂中的溶解度的树脂，和(B)一种能够在光辐照或辐射下生成至少含有一个氟原子的取代芳香基磺酸的化合物。
• PHOSPHORUS-CONTAINING HYDROQUINONE DERIVATIVES, PROCESS FOR THEIR PRODUCTION, PHOSPHORUS-CONTAINING EPOXY RESINS MADE BY USING THE DERIVATIVES, FLAME-RETARDANT RESIN COMPOSITIONS, SEALING MEDIA AND LAMINATED SHEETS
  申请人：NIPPON CHEMICAL INDUSTRIAL COMPANY LIMITED

  公开号：EP1300409A1

  公开（公告）日：2003-04-09

  A phosphorus-containing hydroquinone derivative represented by a general formula (1): (where R1 and R2 represent linear or branched alkyl groups that are identical or may be different, and/or R1 and R2 may form a circular group; X represents an oxygen atom or sulfur atom; Y and Z represent hydrogen atom, hydroxy group, linear or branched alkyl group, aralkyl group, alkoxy group, allyl group, aryl group or cyano group, and/or Y and Z may form a circular group). The present invention provides phosphorus-containing hydroquinone derivatives that are useful for intermediate materials for reactive type flame-retardant agents or phosphorus-containing epoxy resins.

  一种由通式（1）代表的含磷对苯二酚衍生物： (其中 R1 和 R2 代表相同或可能不同的直链或支链烷基，和/或 R1 和 R2 可形成一个环状基团；X 代表氧原子或硫原子；Y 和 Z 代表氢原子、羟基、直链或支链烷基、芳烷基、烷氧基、烯丙基、芳基或氰基，和/或 Y 和 Z 可形成一个环状基团）。本发明提供的含磷对苯二酚衍生物可用作反应型阻燃剂或含磷环氧树脂的中间材料。
• Phosphorus-containing hydroquinone derivatives, process for their production, phosphorus-containing epoxy resins made by using the derivatives, flame-retardant resin compositions, sealing media and laminated sheets
  申请人：——

  公开号：US20030125433A1

  公开（公告）日：2003-07-03

  A phosphorus-containing hydroquinone derivative represented by a general formula (1): 1 (where R 1 and R 2 represent linear or branched alkyl groups that are identical or may be different, and/or R 1 and R 2 may form a circular group; X represents an oxygen atom or sulfur atom; Y and Z represent hydrogen atom, hydroxy group, linear or branched alkyl group, aralkyl group, alkoxy group, allyl group, aryl group or cyano group, and/or Y and Z may form a circular group). The present invention provides phosphorus-containing hydroquinone derivatives that are useful for intermediate materials for reactive type flame-retardant agents or phosphorus-containing epoxy resins.

  由通式(1)代表的含磷对苯二酚衍生物： 1 (其中 R 1 和 R 2 代表相同或可能不同的直链或支链烷基，和/或 R 1 和 R 2 X代表氧原子或硫原子；Y和Z代表氢原子、羟基、直链或支链烷基、芳烷基、烷氧基、烯丙基、芳基或氰基，和/或Y和Z可组成一个环状基团）。本发明提供的含磷对苯二酚衍生物可用作反应型阻燃剂或含磷环氧树脂的中间材料。
• Shipov,A.G.; Baukov,Yu.I., Journal of general chemistry of the USSR, 1979, vol. 49, p. 1687 - 1688
  作者：Shipov,A.G.、Baukov,Yu.I.

  DOI：——

  日期：——