[4-[3-(Trifluoromethyl)phenyl]iodoniophenyl]sulfonyl-(trifluoromethylsulfonyl)azanide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [4-[3-(Trifluoromethyl)phenyl]iodoniophenyl]sulfonyl-(trifluoromethylsulfonyl)azanide
• 化学式: C₁₄H₈F₆INO₄S₂
• 分子量: 559.249
• InChiKey: RYEVVVWIMFJMBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  86
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  4-iodobenzenesulfonyl fluoride 在 dipotassium peroxodisulfate 、 硫酸 作用下， 以 乙腈 为溶剂， 反应 72.0h， 生成 [4-[3-(Trifluoromethyl)phenyl]iodoniophenyl]sulfonyl-(trifluoromethylsulfonyl)azanide
  参考文献：
  名称：

  Iodonium zwitterions

  摘要：

  The first example of a diaryl zwitterionic iodonium compound having the anionic function directly on the aromatic ring is described. Compound 2. Ph-I(+)-C6H4-4-SO2N(-)SO2CF3, is obtained in excellent yield and its X-ray structure was determined. 2 and the many analogues that can be prepared have excellent potential as photoacid generators (PAGs) in microlithography. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(03)00080-0

文献信息

• Iodonium zwitterions
  作者：Darryl D. DesMarteau、William T. Pennington、Vittorio Montanari、Brian H. Thomas

  DOI：10.1016/s0022-1139(03)00080-0

  日期：2003.7

  The first example of a diaryl zwitterionic iodonium compound having the anionic function directly on the aromatic ring is described. Compound 2. Ph-I(+)-C6H4-4-SO2N(-)SO2CF3, is obtained in excellent yield and its X-ray structure was determined. 2 and the many analogues that can be prepared have excellent potential as photoacid generators (PAGs) in microlithography. (C) 2003 Elsevier Science B.V. All rights reserved.