1-amino-4-phenylnaphthalene-2-carbonitrile

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-amino-4-phenylnaphthalene-2-carbonitrile
• 英文别名: 1-amino-4-phenyl-2-naphthonitrile
• 化学式: C₁₇H₁₂N₂
• 分子量: 244.296
• InChiKey: LNVBARBQBDARRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  49.8
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-amino-4-phenylnaphthalene-2-carbonitrile 在 三氯氧磷 作用下， 以 四氢呋喃 为溶剂， 反应 10.0h， 生成 2-chloro-4,6-diphenylbenzo[h]quinazoline
  参考文献：
  名称：

  유기발광 화합물 및 이를 포함하는 유기전계발광소자

  摘要：

  本发明涉及一种有机发光化合物，其用化学式1表示，以及包含该有机发光化合物的有机电致发光器件。根据本发明采用了有机发光化合物的有机电致发光器件，相对于采用传统的有机发光主机材料的器件，能够在更低的电压下驱动，并具有更高的功率效率。【化学式1】

  公开号：

  KR20150111106A
• 作为产物：
  描述：

  硝基萘 在 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 potassium carbonate 、 potassium hydroxide 作用下， 以 1,4-二氧六环 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 20.33h， 生成 1-amino-4-phenylnaphthalene-2-carbonitrile
  参考文献：
  名称：

  유기발광 화합물 및 이를 포함하는 유기전계발광소자

  摘要：

  This is a patent related to organic light-emitting compounds represented by the following [Chemical Formula 1-1] to [Chemical Formula 1-2], and organic electroluminescent devices adopting them have excellent luminescent efficiency, low voltage operation capability, improved power efficiency, and long-term characteristics. [Chemical Formula 1-1] [Chemical Formula 1-2].

  公开号：

  KR20150042386A

文献信息

• 신규한 헤테로고리 화합물 및 이를 포함하는 유기 발광 소자
  申请人：SFC CO., LTD. 에스에프씨 주식회사(120060087061) Corp. No ▼ 135511-0105889BRN ▼134-81-54429

  公开号：KR20180010087A

  公开（公告）日：2018-01-30

  본 발명은 하기 [화학식 A]로 표시되는 헤테로고리 화합물 및 이를 포함하는 유기 발광 소자에 관한 것으로, 치환기 R1 내지 R14, X 및 Y는 각각 발명의 상세한 설명에 정의된 바와 동일하다. [화학식 A]

  本发明涉及如下[化学式A]所表示的杂环化合物以及包含该化合物的有机发光器件，其中取代基R1至R14、X和Y分别与发明详细描述中定义的相同。[化学式A]
• Synthesis of 1-Aminonaphthalene-2-carbonitrile Derivatives by the Reaction of 2-Vinylbenzonitriles with 2-Lithioacetonitrile
  作者：Kazuhiro Kobayashi、Kenichi Hashimoto、Takahiro Ukon、Shuhei Fukamachi、Osamu Morikawa、Hisatoshi Konishi

  DOI：10.1055/s-2008-1032153

  日期：2008.2

  A new and simple method for the preparation of 1-aminonaphthalene-2-carbonitrile derivatives has been developed. When 2-(1-arylethenyl)benzonitriles are treated with 2-lithioacetonitrile, 1-amino-4-aryl-3,4-dihydronaphthalene-2-carbonitriles are obtained in good yields. The reaction of 2-(1-aryl-2-methoxyethenyl)benzonitriles with 2-lithioacetonitrile leads to the formation of 1-amino-4-arylnaphthalene-2-carbonitriles in fair-to-good yields.

  我们开发了一种制备 1-氨基萘-2-甲腈衍生物的简便新方法。当 2-(1-芳基乙烯基)苯腈与 2-二硫代乙腈反应时，可获得 1-氨基-4-芳基-3,4-二氢萘-2-甲腈，且收率良好。2-(1-芳基-2-甲氧基乙烯基)苯腈与 2-二硫代乙腈反应可生成 1-氨基-4-芳基萘-2-甲腈，收率尚可。
• ORGANIC LIGHT EMITTING ELEMENT HAVING HIGH EFFICIENCY
  申请人：SFC Co., Ltd.

  公开号：EP3333241A1

  公开（公告）日：2018-06-13

  The present disclosure relates to an organic light-emitting diode exhibiting high luminance efficiency, low-voltage operation, and long lifespan and, more particularly, to an organic light-emitting diode, comprising: a first electrode; a second electrode facing the first electrode; and a light-emitting layer and an electron density control layer sequentially arranged between the first electrode and the second electrode wherein the light-emitting layer includes at least one of the amine compounds represented by Chemical Formula A or B and the electron density control layer includes at least one of the compounds represented by Chemical Formulas F to H. The structures of Chemical Formulas A, B, and F to H are as described in the specification.

  本公开涉及一种具有高发光效率、低电压工作和长使用寿命的有机发光二极管，更具体地说，涉及一种有机发光二极管，它包括第一电极；面对第一电极的第二电极；以及依次布置在第一电极和第二电极之间的发光层和电子密度控制层，其中发光层包括化学式 A 或 B 所代表的胺化合物中的至少一种，电子密度控制层包括化学式 F 至 H 所代表的化合物中的至少一种。化学式A、B和F至H的结构如说明书所述。
• Organic light-emitting diode with high efficiency
  申请人：SFC CO., LTD.

  公开号：US10741768B2

  公开（公告）日：2020-08-11

  The present disclosure relates to an organic light-emitting diode exhibiting high luminance efficiency, low-voltage operation, and long lifespan and, more particularly, to an organic light-emitting diode, comprising: a first electrode; a second electrode facing the first electrode; and a light-emitting layer and an electron density control layer sequentially arranged between the first electrode and the second electrode wherein the light-emitting layer includes at least one of the amine compounds represented by Chemical Formula A or B and the electron density control layer includes at least one of the compounds represented by Chemical Formulas F to H. The structures of Chemical Formulas A, B, and F to H are as described in the specification.

  本公开涉及一种具有高发光效率、低电压工作和长使用寿命的有机发光二极管，更具体地说，涉及一种有机发光二极管，它包括第一电极；面对第一电极的第二电极；以及依次布置在第一电极和第二电极之间的发光层和电子密度控制层，其中发光层包括化学式 A 或 B 所代表的胺化合物中的至少一种，电子密度控制层包括化学式 F 至 H 所代表的化合物中的至少一种。化学式A、B和F至H的结构如说明书所述。
• Novel synthesis of α-arylnaphthalenes from diphenylacetaldehydes and 1,1-diphenylacetones
  作者：Bartłomiej Kozik、Jarosław Wilamowski、Maciej Góra、Janusz J. Sepioł

  DOI：10.1016/j.tetlet.2006.03.054

  日期：2006.5

  A two-step synthesis of 1-amino-4-arylnaphthalene-2-carbonitriles from diphenylacetaldehydes and 1,1-diphenylacetones involves condensation of the carbonyl compounds with malonodinitrile and cyclization of the aryl-ylidenemalonodinitriles obtained in concentrated sulfuric acid. The benzannulation reaction is accompanied with a quasi-aromatic rearrangement. Some of synthesized aminonitriles reveal considerable biological activity against phytopathogenic fungi. (c) 2006 Elsevier Ltd. All rights reserved.