Cu2(C10H12O4)(2,2'-dipyridylamine)(CF3COO)2 | 245483-57-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cu2(C10H12O4)(2,2'-dipyridylamine)(CF3COO)2
• CAS: 245483-57-2
• 化学式: C₃₄H₃₀Cu₂F₆N₆O₈
• 分子量: 891.73
• InChiKey: HEMMGRUIINFRQE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4,4'-联吡啶 、 Cu2(C10H12O4)(2,2'-dipyridylamine)(CF3COO)2 以 甲醇 为溶剂， 以90%的产率得到[Cu2(C10H12O4)(2,2'-dipyridylamine)2(4,4'-dipyridyl)](CF3CO2)2
  参考文献：
  名称：

  Polynuclear Co(II) and Cu(II) complexes of tetraacetylethane: Cu^II₂(dpa)₂(tae)(O₂CCF₃)₂, {[Cu^II₂(dpa)₂(tae)(4,4<i>'</i>-bipy)](O₂CCF₃)₂}<I>_n</I>, and [Co^II₂(dpa)₄(tae)](O₂CCH₃)₂(H₂O)₂, dpa = 2,2<i>'</i>-dipyridylamine, tae = tetraacetylethane dianion

  摘要：

  The syntheses and structures of copper(II) and cobalt(II) complexes employing tetraacetylethane as the bridging ligand have been investigated. The reaction of Cu(O2CCF3)(2) with tetraacetylethane (tae) and 2,2'-dipyridylamine (dpa) yielded a dinuclear complex Cu-2(II)(dpa)(2)(tae)(O2CCF3)(2) (1), which has an extended hydrogen-bonded chain structure in the solid state. The reaction of 4,4'-dipyridyl (4,4'-bipy) with compound 1 resulted in the formation of a polymeric compound {[Cu-2(II)(dpa)(2)(tae)(4,4'-bipy)](O2CCF3)(2)}(n) (2), where the dinuclear unit is crosslinked by the 4,4'-dipyridyl ligand. The reaction of Co(O2CCH3)(2) with tetraacetylethane and 2,2'-dipyridylamine yielded a helical dinuclear complex [Co-2(II)(dpa)(4)(tae)](O2CCH3)(2)(H2O)(2) (3), which forms a hydrogen-bonded band architecture in the solid state. The three-dimensional structure of 3 has molecular sieve-like channels that host methanol molecules reversibly. While only either negligible or weak magnetic exchanges appear to be present in compounds 1 and 2, there appears to be a significant ferromagnetic exchange in 3, which is likely caused by orbital orthogonality of the Co(IT) ions, as supported by the crystal structure and EHMO calculations.

  DOI：

  10.1139/cjc-77-8-1424
• 作为产物：
  描述：

  3,4-二乙酰基-2,5-己二酮 、 2,2'-二吡啶胺 、 copper(II) trifluoroacetate 以 甲醇 为溶剂， 以84%的产率得到Cu2(C10H12O4)(2,2'-dipyridylamine)(CF3COO)2
  参考文献：
  名称：

  Polynuclear Co(II) and Cu(II) complexes of tetraacetylethane: Cu^II₂(dpa)₂(tae)(O₂CCF₃)₂, {[Cu^II₂(dpa)₂(tae)(4,4<i>'</i>-bipy)](O₂CCF₃)₂}<I>_n</I>, and [Co^II₂(dpa)₄(tae)](O₂CCH₃)₂(H₂O)₂, dpa = 2,2<i>'</i>-dipyridylamine, tae = tetraacetylethane dianion

  摘要：

  The syntheses and structures of copper(II) and cobalt(II) complexes employing tetraacetylethane as the bridging ligand have been investigated. The reaction of Cu(O2CCF3)(2) with tetraacetylethane (tae) and 2,2'-dipyridylamine (dpa) yielded a dinuclear complex Cu-2(II)(dpa)(2)(tae)(O2CCF3)(2) (1), which has an extended hydrogen-bonded chain structure in the solid state. The reaction of 4,4'-dipyridyl (4,4'-bipy) with compound 1 resulted in the formation of a polymeric compound {[Cu-2(II)(dpa)(2)(tae)(4,4'-bipy)](O2CCF3)(2)}(n) (2), where the dinuclear unit is crosslinked by the 4,4'-dipyridyl ligand. The reaction of Co(O2CCH3)(2) with tetraacetylethane and 2,2'-dipyridylamine yielded a helical dinuclear complex [Co-2(II)(dpa)(4)(tae)](O2CCH3)(2)(H2O)(2) (3), which forms a hydrogen-bonded band architecture in the solid state. The three-dimensional structure of 3 has molecular sieve-like channels that host methanol molecules reversibly. While only either negligible or weak magnetic exchanges appear to be present in compounds 1 and 2, there appears to be a significant ferromagnetic exchange in 3, which is likely caused by orbital orthogonality of the Co(IT) ions, as supported by the crystal structure and EHMO calculations.

  DOI：

  10.1139/cjc-77-8-1424