2,3-diphenyl-valeronitrile | 40232-60-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 2,3-diphenyl-valeronitrile
• 英文别名: 2,3-Diphenyl-valeronitril；α.β-Diphenyl-valeronitril；2,3-Diphenylpentanenitrile
• CAS: 40232-60-8
• 化学式: C₁₇H₁₇N
• 分子量: 235.329
• InChiKey: KOAYHNNDGAXATM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,3-diphenyl-valeronitrile 在 盐酸 作用下， 生成 2,3-diphenyl-valeric acid
  参考文献：
  名称：

  Kohler, American Chemical Journal, 1906, vol. 35, p. 403

  摘要：

  DOI：
• 作为产物：
  描述：

  苯丙酮 在 甲醇 、 sodium methylate 作用下， 生成 2,3-diphenyl-valeronitrile
  参考文献：
  名称：

  The Preparation of Some 2,3-Diaryl-2-pentenenitriles by the Knoevenagel Condensation

  摘要：

  DOI：

  10.1021/ja01147a124

文献信息

• 2,3-DIPHENYL-VALERONITRILE DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND USE THEREOF AS HERBICIDES AND PLANT GROWTH REGULATORS
  申请人：Mosrin Marc

  公开号：US20140235446A1

  公开（公告）日：2014-08-21

  The compounds of the formula (I) in which L represents a radical of the formula and A 1 , B 1 and A 2 and B 2 are as defined in Claim 1, are suitable as herbicides for the control of harmful plants or as plant growth regulators. The compounds can be prepared by the process of Claim 12.

  式(I)中L代表式的基团，A1、B1、A2和B2如权利要求1所定义，适用于作为除草剂用于控制有害植物或作为植物生长调节剂。这些化合物可以通过权利要求12所述的方法制备。
• Highly Efficient Synthesis of Stereodefined Multisubstituted 1,4-Dicyano- and 1-Cyano-1,3-butadienes and Their Reactions with Organolithium Reagents
  作者：Congyang Wang、Chao Wang、Qifeng Wang、Zhihui Wang、Hui Sun、Xiangyu Guo、Zhenfeng Xi

  DOI：10.1002/chem.200700028

  日期：2007.7.27

  1-cyano-4-halo-1,3-butadienes and organolithium reagents. When 1,4-dicyano-1,3-butadienes were treated with organolithium reagents followed by trapping with electrophiles, a tandem process took place to afford 2H-pyrrolyl nitriles in excellent yields. Reduction of 1,4-dicyano-1,3-butadiene derivatives with LiAlH4 showed novel reaction patterns relative to normal nitriles.

  立体定义的多取代的1-氰基和1,4-二氰基-1,3-丁二烯衍生物从相应的单卤代和二卤代丁二烯和CuCN中以优异的产率获得了分离的产物。该反应以高的立体选择性进行并且保留了起始卤代丁二烯的立体化学。通过它们与有机锂试剂的反应证明了对如此获得的1-氰基和1，4-二氰基-1，3-丁二烯衍生物的效用的研究。由1-氰基-4-卤代-1,3-丁二烯和有机锂试剂以高收率形成2H-吡咯或亚氨基环戊二烯衍生物。当用有机锂试剂处理1,4-二氰基-1,3-丁二烯，然后用亲电试剂捕集时，进行了串联反应，从而以优异的收率得到了2H-吡咯基腈。减少1,4-dicyano-1，
• SUBSTITUTED 5-HYDROXY-2-PHENYL-3-HETEROARYL PENTANENITRILE DERIVATES, METHOD FOR THE PRODUCTION THEREOF AND USE THEREOF AS HERBICIDES AND/OR PLANT GROWH REGULATORS
  申请人：Bayer CropScience Aktiengesellschaft

  公开号：US20170290330A1

  公开（公告）日：2017-10-12

  Primarily, the present invention relates to compounds of the formula (I) defined below and to their use as herbicides, in particular for controlling broad-leaved weeds and/or weed grasses in crops of useful plants and/or as plant growth regulators for influencing the growth of crops of useful plants. The present invention also relates to herbicidal or plant growth-regulating compositions comprising one or more compounds of the formula (I). Moreover, the present invention relates to processes for preparing the compounds of the formula (I).

  主要地，本发明涉及以下定义的式(I)化合物以及它们作为除草剂的用途，特别是用于控制有用植物作物中的阔叶杂草和/或杂草，或作为植物生长调节剂以影响有用植物作物的生长。本发明还涉及包含一个或多个式(I)化合物的除草剂或植物生长调节剂组合物。此外，本发明涉及制备式(I)化合物的方法。
• Substituted 5-hydroxy-2-heteroaryl-3-phenylpentanonitrile derivatives, processes for their preparation and their use as herbicides and/or plant growth regulators
  申请人：BAYER CROPSCIENCE AKTIENGESELLSCHAFT

  公开号：US20170166549A1

  公开（公告）日：2017-06-15

  Primarily, the present invention relates to compounds of the formula (I) defined below and to their use as herbicides, in particular for controlling broad-leaved weeds and/or weed grasses in crops of useful plants and/or as plant growth regulators for influencing the growth of crops of useful plants. The present invention also relates to herbicidal or plant growth-regulating compositions comprising one or more compounds of the formula (I). Moreover, the present invention relates to processes for preparing the compounds of the formula (I).

  主要，本发明涉及下面定义的式（I）的化合物及其作为除草剂的用途，特别是用于控制作物中的阔叶杂草和/或杂草，以及作为影响作物生长的植物生长调节剂。本发明还涉及包含一个或多个式（I）化合物的除草剂或植物生长调节剂组合物。此外，本发明涉及制备式（I）化合物的方法。
• CHEMICAL MECHANICAL POLISHING AND WAFER CLEANING COMPOSITION COMPRISING AMIDOXIME COMPOUNDS AND ASSOCIATED METHOD FOR USE
  申请人：Lee Wai Mun

  公开号：US20090130849A1

  公开（公告）日：2009-05-21

  A composition and associated method for chemical mechanical planarization (or other polishing) is described. The composition contains an amidoxime compound and water. The composition may also contain an abrasive and a compound with oxidation and reduction potential. The composition is useful for attaining improved removal rates for metal, including copper, barrier material, and dielectric layer materials in metal CMP. The composition is particularly useful in conjunction with the associated method for metal CMP applications.

  本文描述了一种化学机械平整化（或其他抛光）的组合物及其相关方法。该组合物含有一种酰胺肟化合物和水。该组合物还可以含有磨料和具有氧化还原潜力的化合物。该组合物可用于在金属CMP中获得改进的金属去除速率，包括铜、屏障材料和金属CMP中的介电层材料。该组合物在金属CMP应用的相关方法中特别有用。