2,3-二氢-5,6-二苯基-1,4-氧硫杂环己二烯 | 58041-19-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 中文名称: 2,3-二氢-5,6-二苯基-1,4-氧硫杂环己二烯
• 英文名称: 5,6-diphenyl-2,3-dihydro-1,4-oxathiin
• 英文别名: 2,3-diphenyl-5,6-dihydro-1,4-oxatiin；5,6-Diphenyl-2,3-dihydro-[1,4]oxathiin；2,3-dihydro-5,6-diphenyl-1,4-oxathiin；2,3-Diphenyl-1,4-oxathien；5,6-diphenyl-2,3-dihydro-1,4-oxathiine
• CAS: 58041-19-3
• 化学式: C₁₆H₁₄OS
• 分子量: 254.353
• InChiKey: GZVBPNSXCWYLJU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.125
• 拓扑面积：
  34.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• WGK Germany：
  2

SDS

1.1 产品标识符
: 2,3-Dihydro-5,6-diphenyl-1,4-oxathiin
化学品俗名或商品名
1.2 鉴别的其他方法
无数据资料
1.3 有关的确定了的物质或混合物的用途和建议不适合的用途
仅供科研用途，不作为药物、家庭备用药或其它用途。

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模块 2. 危险性概述
2.1 GHS分类
急性毒性, 经口 (类别5)
2.2 GHS 标记要素，包括预防性的陈述
危害类型象形图 无
信号词 警告
危险申明
H303 吞咽可能有害。
警告申明
措施
P312 如感觉不适，呼救解毒中心或医生。
2.3 其它危害物 - 无

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模块 3. 成分/组成信息
3.1 物 质
: C16H14OS
分子式
: 254.35 g/mol
分子量
成分 浓度
2,3-Dihydro-5,6-diphenyl-1,4-oxathiin
-
化学文摘编号(CAS No.) 58041-19-3

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模块 4. 急救措施
4.1 必要的急救措施描述
一般的建议
请教医生。 出示此安全技术说明书给到现场的医生看。
如果吸入
如果吸入,请将患者移到新鲜空气处。 如果停止了呼吸,给于人工呼吸。 请教医生。
在皮肤接触的情况下
用肥皂和大量的水冲洗。 请教医生。
在眼睛接触的情况下
用水冲洗眼睛作为预防措施。
如果误服
切勿给失去知觉者从嘴里喂食任何东西。 用水漱口。 请教医生。
4.2 最重要的症状和影响，急性的和滞后的
据我们所知，此化学，物理和毒性性质尚未经完整的研究。
4.3 及时的医疗处理和所需的特殊处理的说明和指示
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模块 5. 消防措施
5.1 灭火介质
灭火方法及灭火剂
用水雾,耐醇泡沫,干粉或二氧化碳灭火。
5.2 源于此物质或混合物的特别的危害
碳氧化物, 硫氧化物
5.3 救火人员的预防
如必要的话,戴自给式呼吸器去救火。
5.4 进一步的信息
无数据资料

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模块 6. 泄露应急处理
6.1 人员的预防,防护设备和紧急处理程序
使用个人防护设备。 防止粉尘的生成。 防止吸入蒸汽、气雾或气体。 避免吸入粉尘。
6.2 环境预防措施
不要让产物进入下水道。
6.3 抑制和清除溢出物的方法和材料
收集、处理泄漏物，不要产生灰尘。 扫掉和铲掉。 存放在合适的封闭的处理容器内。
6.4 参考其他部分
丢弃处理请参阅第13节。

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模块 7. 操作处置与储存
7.1 安全操作的注意事项
防止粉尘和气溶胶生成。
在有粉尘生成的地方,提供合适的排风设备。一般性的防火保护措施。
7.2 安全储存的条件,包括任何不兼容性
贮存在阴凉处。 容器保持紧闭，储存在干燥通风处。
建议的贮存温度： 2 - 8 °C
7.3 特定用途
无数据资料

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模块 8. 接触控制/个体防护
8.1 控制参数
最高容许浓度
没有已知的国家规定的暴露极限。
8.2 暴露控制
适当的技术控制
根据工业卫生和安全使用规则来操作。 休息以前和工作结束时洗手。
人身保护设备
眼/面保护
请使用经官方标准如NIOSH (美国) 或 EN 166(欧盟) 检测与批准的设备防护眼部。
皮肤保护
戴手套取 手套在使用前必须受检查。
请使用合适的方法脱除手套(不要接触手套外部表面),避免任何皮肤部位接触此产品.
使用后请将被污染过的手套根据相关法律法规和有效的实验室规章程序谨慎处理. 请清洗并吹干双手
所选择的保护手套必须符合EU的89/686/EEC规定和从它衍生出来的EN 376标准。
身体保护
根据危险物质的类型，浓度和量，以及特定的工作场所来选择人体保护措施。,
防护设备的类型必须根据特定工作场所中的危险物的浓度和含量来选择。
呼吸系统防护
不需要保护呼吸。如需防护粉尘损害，请使用N95型（US）或P1型（EN 143)防尘面具。
呼吸器使用经过测试并通过政府标准如NIOSH（US）或CEN（EU）的呼吸器和零件。

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模块 9. 理化特性
9.1 基本的理化特性的信息
a) 外观与性状
形状: 固体
b) 气味
无数据资料
c) 气味临界值
无数据资料
d) pH值
无数据资料
e) 熔点/凝固点
无数据资料
f) 起始沸点和沸程
无数据资料
g) 闪点
无数据资料
h) 蒸发速率
无数据资料
i) 可燃性(固体,气体)
无数据资料
j) 高的/低的燃烧性或爆炸性限度 无数据资料
k) 蒸气压
无数据资料
l) 相对蒸气密度
无数据资料
m) 相对密度
无数据资料
n) 水溶性
无数据资料
o) 辛醇/水分配系数的对数值
无数据资料
p) 自燃温度
无数据资料
q) 分解温度
无数据资料
r) 粘度
无数据资料

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模块 10. 稳定性和反应活性
10.1 反应性
无数据资料
10.2 化学稳定性
无数据资料
10.3 危险反应的可能性
无数据资料
10.4 避免接触的条件
无数据资料
10.5 不兼容的材料
无数据资料
10.6 危险的分解产物
其它分解产物 - 无数据资料

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模块 11. 毒理学资料
11.1 毒理学影响的信息
急性毒性
半致死剂量(LD50) 经口 - 大鼠 - 3,000 mg/kg
皮肤腐蚀/刺激
无数据资料
严重眼损伤 / 眼刺激
无数据资料
呼吸道或皮肤过敏
无数据资料
生殖细胞诱变
无数据资料
致癌性
IARC:
此产品中没有大于或等于 0。1%含量的组分被 IARC鉴别为可能的或肯定的人类致癌物。
生殖毒性
无数据资料
特异性靶器官系统毒性（一次接触）
无数据资料
特异性靶器官系统毒性（反复接触）
无数据资料
吸入危险
无数据资料
潜在的健康影响
吸入 吸入可能有害。 可能引起呼吸道刺激。
摄入 如服入是有害的。
皮肤 如果通过皮肤吸收可能是有害的。 可能引起皮肤刺激。
眼睛 可能引起眼睛刺激。
接触后的征兆和症状
据我们所知，此化学，物理和毒性性质尚未经完整的研究。
附加说明
化学物质毒性作用登记: RP5320000

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模块 12. 生态学资料
12.1 毒性
无数据资料
12.2 持久存留性和降解性
无数据资料
12.3 生物积累的潜在可能性
无数据资料
12.4 土壤中的迁移
无数据资料
12.5 PBT 和 vPvB的结果评价
无数据资料
12.6 其它不利的影响
无数据资料

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模块 13. 废弃处置
13.1 废物处理方法
产品
将剩余的和未回收的溶液交给处理公司。 联系专业的拥有废弃物处理执照的机构来处理此物质。
与易燃溶剂相溶或者相混合，在备有燃烧后处理和洗刷作用的化学焚化炉中燃烧
污染了的包装物
作为未用过的产品弃置。

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模块 14. 运输信息
14.1 UN编号
欧洲陆运危规: - 国际海运危规: - 国际空运危规: -
14.2 联合国（UN）规定的名称
欧洲陆运危规: 无危险货物
国际海运危规: 无危险货物
国际空运危规: 无危险货物
14.3 运输危险类别
欧洲陆运危规: - 国际海运危规: - 国际空运危规: -
14.4 包裹组
欧洲陆运危规: - 国际海运危规: - 国际空运危规: -
14.5 环境危险
欧洲陆运危规: 否 国际海运危规 海运污染物: 否 国际空运危规: 否
14.6 对使用者的特别预防
无数据资料

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模块 16. 其他信息
进一步的信息
版权所有：2011 公司。许可无限制纸张拷贝，仅限于内部使用。
上述信息视为正确，但不包含所有的信息，仅作为指引使用。本文件中的信息是基于我们目前所知，就正
确的安全提示来说适用于本品。该信息不代表保证此产品的性质。
公司对任何操作或者接触上述产品而引起的损害不负有任何责任，。更多使用条款，参见发票或包
装条的反面。

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模块 15 - 法规信息
N/A

反应信息

• 作为反应物：
  描述：

  2,3-二氢-5,6-二苯基-1,4-氧硫杂环己二烯 在 5-(4'-hydroxyphenyl)-10,15,20-triphenylporphyrin 作用下， 反应 1.0h， 以99%的产率得到
  参考文献：
  名称：

  Low energy light-triggered oxidative cleavage of olefins

  摘要：

  A series of substituted olefins were tested for their reactivity with singlet oxygen as a singlet oxygen-mediated cleavable linker. Low intensity light of 200 mW/cm(2) was irradiated to the solution of an olefin and 5,10,15-triphenyl-20-(4-hydroxyphenyl)-21H,23H-porphyrin under atmospheric condition, Among the tested olefins, 1,2-cis-diphenoxyethylene reacted fast with singlet oxygen, >80% within 15 min yielding a stoichiometric conversion to aldehyde product without ally side reactions. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.12.069
• 作为产物：
  描述：

  2-(Bromo-phenyl-methyl)-2-phenyl-[1,3]oxathiolane 在 potassium tert-butylate 作用下， 以 二甲基亚砜 为溶剂， 反应 0.5h， 以85%的产率得到2,3-二氢-5,6-二苯基-1,4-氧硫杂环己二烯
  参考文献：
  名称：

  Synthesis of 1,4-oxathiins and 5,6-dihydro-1,4-oxathiins

  摘要：

  DOI：

  10.1021/jo00360a045

文献信息

• Effects of heteroatom substituents on the properties of 1,2-dioxetanes
  作者：Richard S. Handley、Alan J. Stern、A.Paul Schaap

  DOI：10.1016/s0040-4039(00)98147-4

  日期：1985.1

  Nitrogen and sulfur-substituted dioxetanes exhibit dramatically lower activation energies for decomposition compared to the corresponding oxygen-bearing dioxetane. A mechanism involving intramolecular electron-transfer processes is proposed for the cleavage of these unstable dioxetanes.

  与相应的含氧二氧杂环丁烷相比，氮和硫取代的二氧杂环丁烷显示出极低的分解活化能。提出了一种涉及分子内电子转移过程的机制，用于裂解这些不稳定的二氧杂环丁烷。
• Ring Expansion Reaction of 1,3-Dithiolanes and 1,3-Oxathiolanes Using Tellurium Tetrachloride
  作者：Hiroyuki Tani、Tokuo Inamasu、Rui Tamura、Hitomi Suzuki

  DOI：10.1246/cl.1990.1323

  日期：1990.8

  On treatment with tellurium tetrachloride in dichloromethane at room temperature, 1,3-dithiolanes and 1,3-oxathiolanes undergo smooth ring expansion to give dihydro-1,4-dithiin and dihydro-1,4-oxathiin derivatives respectively in good to moderate yields.

  在室温下使用氯化四碲 treatment，1,3-二噻环烷和1,3-氧噻环烷在二氯甲烷中平滑地环扩展，分别得到二氢-1,4-二噻并和二氢-1,4-氧噻并，产率从良好到适中。
• MULTICOMPARTMENT GRANULATE FORMULATIONS FOR ACTIVE SUBSTANCES
  申请人：Letmathe Claudia

  公开号：US20090317468A1

  公开（公告）日：2009-12-24

  The invention relates to molded article that contains active substances and comprises at least two compartments that have a different material composition. Each compartment is independently provided with at least one active substance that is contained in a matrix. Each matrix encompasses at least one filler at a concentration of ≧20 percent by weight to ≦100 percent by weight relative to the total weight of the respective matrix. The invention further relates to a method for producing such molded articles as well as the use thereof.

  该发明涉及一种含有活性物质的成型制品，包括至少两个具有不同材料组成的隔间。每个隔间都独立地装有至少一种活性物质，该活性物质含在一个基质中。每个基质包含至少一种填料，其浓度相对于各自基质的总重量为≧20%至≦100%。该发明还涉及一种生产这种成型制品的方法以及其用途。
• Substituted 2,3-dihydro-,4-oxathiin plant growth stunting agents
  申请人：Uniroyal, Inc.

  公开号：US03947264A1

  公开（公告）日：1976-03-30

  Substituted 2,3-dihydro-1,4-oxathiins of the formula ##SPC1## Display useful plant growth regulant effects including herbicidal effects. Examples are 2,3-dihydro-5,6-diphenyl-1,4-oxathiin, and 2,3-dihydro-5-(4-methyl-phenyl)-6-phenyl-1,4-oxathiin 4-oxide. The compounds are useful for the selective control of grasses and as dwarfing agents, as well as for inhibition of vegetative and reproductive axillary growth, and for increasing the sugar content of sugar producing species. A number of these are new compounds. This invention relates to a method of regulating the growth of plants and to plant growth regulant compositions useful in such method, as well as to chemical compounds useful in such compositions. Regulation of the growth of plants is frequently desirable for a number of reasons. For example, the control of weeds is of great economic importance. Weed competition inhibits the production of foliage, fruit or seed of agricultural crops. The presence of weeds may also reduce the quality of the harvested crop and reduce harvesting efficiency. Weed control is essential for maximum production of many agronomic and horticultural crops, including corn (Zea mays L.), rice (Oryza sativa L.) and soybeans (Glycine max (L.) Merr.). Weeds on non-cropped areas may cause a fire hazard, undesirable drifting of sand or snow, impaired beauty of the landscape and irritation to persons with allergies. The invention, in one aspect, is based on the discovery that certain substituted 2,3-dihydro-1,4-oxathiins are remarkably effective preemergence herbicides, especially for the selective control of grasses. Another form of regulation of plant growth that is of great economic importance involves non-herbicidal growth regulant effects. These include, by way of nonlimiting example, such effects as dwarfing, antitranspiration, inhibition of vegetative and reproductive axillary growth and increasing the sugar content of sugar producing species. In one important aspect the invention provides a highly effective method for producing such effects, employing certain substituted 2,3-dihydro-1,4-oxathiins. The substituted 2,3-dihydro-1,4-oxathiins employed to produce herbicidal and other plant growth regulating effects in accordance with the invention are those of the formula ##SPC2## Wherein the R's are the same or different and are selected from the group consisting of hydrogen, lower alkyl (especially methyl and ethyl), halogen (e.g., chlorine, bromine, fluorine), lower alkoxy (e.g., methoxy), amino, lower alkylthio (e.g., methylthio), and lower acyloxy (e.g., acetyloxy), and n is zero, 1 or 2. The compound wherein all of the R's are hydrogen, and n is zero, namely, 2,3-dihydro-5,6-diphenyl-1,4-oxathiin, is known [Marshall and Stevenson, J. Chem. Soc. 2360 (1959)]; the other compounds are believed to be new. In a preferred class of compounds useful in the invention the R's have the following values: R.sub.1 = H R.sub.2 = H, CH.sub.3, C.sub.2 H.sub.5 R.sub.3 = H, Cl, CH.sub.3 R.sub.4 = H, Cl, CH.sub.3 ##EQU1## R.sub.6 = H, Cl, CH.sub.3 R.sub.7 = H, Cl, CH.sub.3, OCH.sub.3 R.sub.8 = H, Cl, Br, F, CH.sub.3, C.sub.2 H.sub.5, OCH.sub.3, NH.sub.2 R.sub.9 = H, CH.sub.3 R.sub.10 = H. Again, the members of this preferred class of compounds are new, except where all of the R's are hydrogen and n is zero (i.e., except for 2,3-dihydro-5,6-diphenyl-1,4-oxathiin). Of special interest are the compounds of the class described having substituents on one or both phenyls, or a substitutent on the dihydro portion of the 1,4-oxathiin ring, or a combination of both. Also of special note are such compounds with a para substituent on the 5-phenyl group. In one respect, the invention is concerned with chemicals of the kind described wherein n is 1 or 2, and use thereof in plant growth regulation. In another respect the invention is directed to chemicals of the above-stated formula in which at least one of the R's is other than hydrogen or lower alkyl, as well as plant growth regulant uses of such chemicals. The substituted 2,3-dihydro-1,4-oxathiins employed in the invention may be prepared by reacting a 2-mercaptoalkanol with an appropriately substituted 2-halo-2-phenylacetophenone in the presence of a base and cyclizing the resulting intermediate with water removal in the presence of p-toluenesulfonic acid as a catalyst. The preparation of the 2-halo-2-phenylacetophenones may be achieved using one of the following general procedures: a. Reaction of a substituted benzoin with thionyl chloride. b. Reaction of a substituted 2-phenylacetophenone with sulfuryl chloride. c. Reaction of a substituted 2-phenylacetophenone with bromine. The 2-phenylacetophenones may be prepared by the standard methods known in the literature, such as Friedel-Crafts acylation or Grignard condensation with the appropriate chemicals. The 2,3-dihydro-1,4-oxathiin in which n is zero may be oxidized to the corresponding 4-oxide or 4,4-dioxide (n = 1 or 2) by controlled addition of one or two equivalants respectively of a 30% hydrogen peroxide solution to one equivalent of the oxathiin in glacial acetic acid. In one aspect, the invention contemplates application of any of the substituted 2,3-dihydro-1,4-oxathiin compounds described, in amount effective to regulate growth, to a locus at which such growth regulant effects as preemergence herbicidal effects, dwarfing, fruiting body inhibition, increasing sugar content, etc., are desired. In another aspect, the invention is directed to a plant growth regulant composition comprising a chemical compound as described herein, in amount effective to regulate the growth of plants, in admixture with a carrier therefor. It will be understood that the term plants as used herein includes plant parts such as foliage, roots, flowers and seeds. The amount of substituted 1,4-oxathiin employed follows conventional practice for herbicidal use or other plant growth regulant uses and the chemical is suitably applied as a formulation in accordance with conventional agricultural chemical practice. Thus, the chemical may be impregnated on finely-divided or granular inorganic or organic carriers such as attapulgite clay, sand, vermiculite, corn cobs, activated carbon or other granular carriers known to the art. The impregnated granules may then be spread on the soil. Furthermore, the chemical may be formulated, for example, as a wettable powder by grinding it into a fine powder and mixing it with an inactive powdered carrier to which a surface active dispersing agent has been added. Typical powdered solid carriers are the various mineral silicates, e.g., mica, talc, pyrophyllite, and clays. The wettable powder may then be dispersed in water and sprayed on the soil surface, or on crop plants. Similarly, an emulsifiable concentrate may be prepared by dissolving the chemical in a solvent such as benzene, toluene, or other aliphatic or aromatic hydrocarbon to which a surface active dispersing agent has been added. The emulsifiable concentrate may then be dispersed in water and applied by spraying. Suitable surface active agents are well known to those skilled in the art, and reference may be had to McCutcheon's Detergents and Emulsifiers, 1970, Allured Publishing Corp., Ridgewood, N.J., or Hoffman et al. U.S. Pat. Nos. 2,614,916, cols. 2 to 4 and 2,547,724, cols. 3 and 4, for examples of appropriate surface active agents. The concentration of active chemical in the formulation may vary widely, e.g., from 1 to 95%. The concentration of active chemical in dispersions applied to the soil or foliage is almost invariably from 0.002% to 75%. The chemical is frequently applied at rates of 0.10 to 25 pounds per acre. For use as a preemergence herbicide, the chemical is applied to soil which contains weed and crop seed (either to the surface of the soil or incorporated into the upper one to three inches of soil). The chemicals may be employed individually, or as a mixture of two or more chemicals. The most suitable rate of application in any given case will depend on such factors as the particular response desired, soil type, soil pH, soil organic matter content, wind velocity, the quantity and intensity of rainfall before and after treatment, the air and soil temperature, light intensity and light duration per day. All of these factors can have an influence on the efficacy of the chemicals for a given plant growth control use. The herbicidal use may include selective weed control in crops such as soybeans, sugar beets, etc. Depending on crop, variety, dosage, time of application and certain cultural practices, growth regulating effects which are obtained include the following: a. dwarfing b. cessation of terminal growth c. inhibition of axillary and intercalary growth d. flowering inhibition e. fruiting body inhibition f. twisting and epinastic responses g. modification of root growth h. increasing sugar in sugar producing species i. antitranspiration to control water loss. The foregoing responses are general plant responses any one of which could contribute directly to yield increases. For example, a spray application may be made to tobacco after the flowers are removed to obtain excellent axillary growth control. It may be applied to cotton to facilitate a cut off spray or it may be applied on cotton early to retard the development of rank cotton. Chemicals described herein also may be used on ornamental plants. For example, a spray application may be made to chrysanthemums to obtain disbudding which, if done by hand, is very costly. It has been shown to increase the percent sugar in sugarcane. It can be postulated from the results on sugarcane that the chemicals may be preventing breakdown of sugars. The chemicals have also shown remarkable properties in inhibiting flower bud development on peaches. This is useful for preventing frost damage in marginal growth areas where late frosts are inevitable. Flower thinning may be accomplished also. Another plant growth regulant effect that the chemicals of the invention exhibit is that of antitranspiration. The chemicals control stomatal opening and hence prevent excessive water loss. Due to this response greater yields can be obtained with plants growing under stress. The following examples, in which all quantities are expressed by weight unless otherwise indicated, will serve to illustrate the practice of the invention in more detail. Examples 1-51 involve preparation of typical plant growth regulant chemicals of the invention, employing four different methods of preparation, identified by the letters A to D in TABLE I, as follows: A. Halogenation of the appropriate 2-phenylacetophenone followed by reaction with a 2-mercaptoalkanol and cyclization. B. Reaction of a purified 2-halo-2-phenylacetophenone with a 2-mercaptoalkanol followed by cyclization. C. Oxidation of the appropriate 1,4-oxathiin with one equivalent of oxidizing agent. D. Oxidation of the appropriate 1,4-oxathiin with two equivalents of oxidizing agent. The identity of each of the compounds in the working examples was established partly by nuclear magnetic resonance spectrum and partly by analytical data. The n.m.r. spectra of the compounds revealed the characteristic couplings due to the protons of the dihydro portion of the dihydro-1,4-oxathiin ring, thereby confirming the structure. In Examples 52-60 and TABLES II-IX the various substituted 1,4-oxathiins are identified by the Example numbers given in TABLE I. Preferred new chemicals of the invention are those selected from the group consisting of the chemicals of Examples 3, 4, 2, 20, 21, 22, 9, 10, 6, 12 and 16; especially preferred are the chemicals of Examples 3, 20 and 21. Plant growth regulant compositions of particular interest containing the present chemicals are those based on chemicals selected from the group consisting of 1, 3, 9, 12, 20, 21, 16, 17, 18, 29, 30 and 38, more preferably those based on chemicals 1, 3, 20, 21 and 12. For use in preemergence control of weeds the preferred chemicals are those of Examples 3, 20, 21, 30, 38, 10, 16, 18, 13, 24 and 43, more especially the chemicals of Examples 3, 21, 18, 10 and 13. Preferred plant growth retardant chemicals are those of Examples 1, 20, 29, 30, 38 and 9, more preferably Examples 1 and 20. For inhibition of axillary vegetative and reproductive growth, preferred chemicals are those of Examples 1, 3, 9, 12, 20, 21, 16, 17 and 18, more preferably 1, 3, 20, 21 and 12.

  2,3-二氢-1,4-噁硫烯（oxathiins）的替代物具有有用的植物生长调节效果，包括除草效果。例如，2,3-二氢-5,6-二苯基-1,4-噁硫烯和2,3-二氢-5-(4-甲基苯基)-6-苯基-1,4-噁硫烯-4-氧化物。这些化合物可用于选择性控制草本植物，作为矮化剂，抑制营养和生殖腋芽生长，以及增加生产糖类物种的糖含量。其中许多是新化合物。本发明涉及一种调节植物生长的方法，以及在该方法中有用的植物生长调节组合物，以及在这些组合物中有用的化合物。调节植物生长通常是出于多种原因而有必要的。例如，控制杂草对经济至关重要。杂草竞争会抑制农作物的叶片、果实或种子的产量。杂草的存在也可能降低收获作物的质量和收获效率。对于许多农艺和园艺作物，包括玉米（Zea mays L.）、水稻（Oryza sativa L.）和大豆（Glycine max (L.) Merr.）等，杂草控制对于最大产量是必不可少的。非耕地上的杂草可能导致火灾危险、沙土或积雪漂移不受欢迎、景观美观受损以及引起过敏者的刺激。本发明的某一方面基于发现，某些替代的2,3-二氢-1,4-噁硫烯是非常有效的前出苗除草剂，特别是对草本植物的选择性控制。另一种对植物生长的调节方式具有极大的经济重要性，涉及非除草剂生长调节效果。这些效果包括但不限于矮化、抗蒸发、抑制营养和生殖腋芽生长以及增加生产糖类物种的糖含量。在一个重要方面，本发明提供了一种高效的方法来产生这些效果，利用特定的替代的2,3-二氢-1,4-噁硫烯。在本发明中用于产生除草和其他植物生长调节效果的替代的2,3-二氢-1,4-噁硫烯是具有以下结构的：（详细结构见原文）。这些化合物可通过将2-巯基醇与适当取代的2-卤代-2-苯基乙酮在碱的存在下反应，并在对甲苯磺酸存在下去水环化所制备。2-苯基乙酮的制备可通过文献中已知的标准方法，如弗里德尔-克拉夫斯（Friedel-Crafts）酰化或格氏试剂与适当化学品的缩合反应等方法实现。在本发明中使用的2,3-二氢-1,4-噁硫烯可通过将2,3-二氢-1,4-噁硫烯氧化为相应的4-氧化物或4,4-二氧化物（n = 1或2）来制备。这些化合物可用于调节植物生长，具有前出苗除草效果、矮化、果实体抑制、增加糖含量等效果。
• [EN] ACTIVE COMPOUND COMBINATIONS COMPRISING CARBOXAMIDE DERIVATIVES<br/>[FR] COMBINAISONS DE COMPOSÉS ACTIFS COMPRENANT DES DÉRIVÉS CARBOXAMIDE
  申请人：BAYER CROPSCIENCE AG

  公开号：WO2014060502A1

  公开（公告）日：2014-04-24

  The present invention relates to active compound combinations, in particular within a composition, which comprises (A) ) a N-cyclopropyl-N-[substituted-benzyl]-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide or thiocarboxamide derivative and (B) a further herbicidally active compound or (C) a plant growth regulator and/or (D) a safener for reducing phytotoxic actions of agrochemicals. Moreover, the invention relates to a method for curatively or preventively controlling the phytopathogenic fungi of plants or crops, to the use of a combination according to the invention for the treatment of seed, to a method for protecting a seed and not at least to the treated seed.

  本发明涉及活性化合物组合物，特别是在组合物中包含(A) N-环丙基-N-[取代苄基]-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-羧酰胺或硫代羧酰胺衍生物和(B)另一种除草剂活性化合物或(C)植物生长调节剂和/或(D)用于减少农药植物毒性作用的安全剂。此外，本发明还涉及一种治疗或预防植物或作物的植物病原真菌的方法，使用本发明中的组合物来处理种子的用途，一种保护种子的方法，最后是经过处理的种子。