N-N-butyl-4-di(2-pyridylmethyl)amino-1,8-naphthalimide | 1292289-00-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: N-N-butyl-4-di(2-pyridylmethyl)amino-1,8-naphthalimide
• 英文别名: MSIND；6-[Bis(pyridin-2-ylmethyl)amino]-2-butylbenzo[de]isoquinoline-1,3-dione；6-[bis(pyridin-2-ylmethyl)amino]-2-butylbenzo[de]isoquinoline-1,3-dione
• CAS: 1292289-00-9
• 化学式: C₂₈H₂₆N₄O₂
• 分子量: 450.54
• InChiKey: OELVNCGNOHAWQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  34
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  66.4
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N-N-butyl-4-di(2-pyridylmethyl)amino-1,8-naphthalimide 、 copper dichloride 以 乙醇 、 二氯甲烷 为溶剂， 生成 Cl₂Cu(N-n-butyl-4-di(2-pyridylmethyl)amino-1,8-naphthalimide)
  参考文献：
  名称：

  A colorimetric probe for copper(II) ion based on 4-amino-1,8-naphthalimide

  摘要：

  A novel fluorescent probe with naphthalimide as fluorophore and di(2-picolyl) amino unit as receptor for Cu(II) was designed and synthesized. In water/acetonitrile solution, the presence of Cu2+ ions induced significant blue shift on the maximum absorption band as well as complete fluorescence quenching due to the formation of a 1: 1 metal-ligand complex. It exhibited high selectivity toward Cu(II) and no interference from other metal ions was observed. The structure of the complex was characterized by single crystal X-ray diffraction experiments. The results of this research demonstrate successfully that excellent sensing properties can be achieved by a small organic compound with very simple structure. This is also the first single crystal structure which reveals directly the coordination pattern of fluorescent probe bearing di-2-picoly-amine unit with Cu(II). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.07.039
• 作为产物：
  描述：

  4-溴-1,8-萘二甲酸酐 以 乙醇 、 甲乙醚 为溶剂， 反应 72.0h， 生成 N-N-butyl-4-di(2-pyridylmethyl)amino-1,8-naphthalimide
  参考文献：
  名称：

  A pellet-type optical nanomaterial of silica-based naphthalimide–DPA–Cu(ii) complexes: recyclable fluorescence detection of pyrophosphate

  摘要：

  研究了一种由介孔二氧化硅固定萘二甲酰亚胺铜（II）络合物（MSINDâCu）制备而成的颗粒型纳米材料，它是一种用于检测 PPi 的选择性荧光化学传感器，具有 "offâonâ "荧光变化大、检测限低、响应时间短、pH 值检测范围宽等特点。

  DOI：

  10.1039/c1cc00021g

文献信息

• A colorimetric probe for copper(II) ion based on 4-amino-1,8-naphthalimide
  作者：Haixia Wang、Lin Yang、Wenbo Zhang、Yu Zhou、Bing Zhao、Xiyou Li

  DOI：10.1016/j.ica.2011.07.039

  日期：2012.2

  A novel fluorescent probe with naphthalimide as fluorophore and di(2-picolyl) amino unit as receptor for Cu(II) was designed and synthesized. In water/acetonitrile solution, the presence of Cu2+ ions induced significant blue shift on the maximum absorption band as well as complete fluorescence quenching due to the formation of a 1: 1 metal-ligand complex. It exhibited high selectivity toward Cu(II) and no interference from other metal ions was observed. The structure of the complex was characterized by single crystal X-ray diffraction experiments. The results of this research demonstrate successfully that excellent sensing properties can be achieved by a small organic compound with very simple structure. This is also the first single crystal structure which reveals directly the coordination pattern of fluorescent probe bearing di-2-picoly-amine unit with Cu(II). (C) 2011 Elsevier B.V. All rights reserved.
• A pellet-type optical nanomaterial of silica-based naphthalimide–DPA–Cu(ii) complexes: recyclable fluorescence detection of pyrophosphate
  作者：Jun Feng Zhang、Minsung Park、Wen Xiu Ren、Youngmee Kim、Sung Jin Kim、Jong Hwa Jung、Jong Seung Kim

  DOI：10.1039/c1cc00021g

  日期：——

  A pellet-type nanomaterial prepared from a mesoporous silica-immobilized naphthalimide–DPA–Cu(II) complex (MSIND–Cu) is investigated as a selective fluorescent chemosensor for PPi detection with a large “off–on” fluorescence change, low detection limit, short response time and a broad pH test range.

  研究了一种由介孔二氧化硅固定萘二甲酰亚胺铜（II）络合物（MSINDâCu）制备而成的颗粒型纳米材料，它是一种用于检测 PPi 的选择性荧光化学传感器，具有 "offâonâ "荧光变化大、检测限低、响应时间短、pH 值检测范围宽等特点。