Bisamine | 147637-37-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bisamine
• 英文别名: [[[diphenyl(trimethylsilylimino)-λ5-phosphanyl]amino]-phenyl-trimethylsilylimino-λ5-phosphanyl]benzene
• CAS: 147637-37-4
• 化学式: C₃₀H₃₉N₃P₂Si₂
• 分子量: 559.778
• InChiKey: ADDHYOBARNUJCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.78
• 重原子数：
  37.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  36.75
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  Bisamine 在 正丁基锂 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 3.0h， 以58%的产率得到lithium-bis<(N-trimethylsilyl)imino-(P-diphenyl)phoshoranyl>amide
  参考文献：
  名称：

  Hasselbring, Reinhard; Roesky, Herbert W.; Rietzel, Mathias, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 72, # 1.4, p. 209 - 216

  摘要：

  DOI：
• 作为产物：
  描述：

  N,N-二甲基三甲基硅胺 、 1-Amino-3-imino-1,1,3,3-tetraphenyl-3lambda~5~-diphosphazan-1-ium chloride 在 三乙胺 作用下， 以 甲苯 为溶剂， 反应 4.0h， 生成 Bisamine
  参考文献：
  名称：

  Hasselbring, Reinhard; Roesky, Herbert W.; Rietzel, Mathias, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 72, # 1.4, p. 209 - 216

  摘要：

  DOI：

文献信息

• Hasselbring, Reinhard; Roesky, Herbert W.; Heine, Andreas, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1994, vol. 49, # 1, p. 43 - 49
  作者：Hasselbring, Reinhard、Roesky, Herbert W.、Heine, Andreas、Stalke, Dietmar、Sheldrick, George M.

  DOI：——

  日期：——
• Oxovanadium‐Phosphazene Complexes: Synthesis and Characterization
  作者：Yash Paul、Sushil K. Pandey

  DOI：10.1081/sim-120025437

  日期：2003.1.11

  Cyclic vanadium-phosphazene complexes in 5- and 6-coordination have been synthesized by the reaction of bis(acetylacetonato)oxovanadium(IV), [VO(acac)(2)], or trichlorooxovanadium(V), [VOCl3], with acyclic phosphazene ligands, [HN(PPh2NR)(2)], (where R = Ph or SiMe3) in 1:1 and 1:2 molar ratio. These green colored complexes correspond to the general formulae [VO(acac)L], [VOCl2L] and [VOClL2] (where L = [HN(PPh2NR)(2)]. They are fairly soluble in most organic solvents and sensitive to moisture. These complexes are characterized by various physico-chemical technique. viz elemental analyses (C, H, N, V and Cl), molecular weight determinations and spectral Studies including IR and NMR (H-1, C-13 and P-31), which indicated the monomeric nature of the complexes having a bidentate mode of bonding with the phosphazene ligand endowing a square-pyramidal or octahedral geometry around the vanadium atom, respectively.
• Cyclometallaphosphazene Complexes of Titanium(IV)
  作者：Yash Paul、Suresh Magotra、Sushil K. Pandey

  DOI：10.1080/15533170701674868

  日期：2007.11.1

  Cyclometallacyclophosphazene complexes of titanium(IV) corresponding to [N(PPh2NR)(2)}(n)TiCl4-n], [N(PPh2NR)(2)}(n)TiCl2-n] (OPri)(2)], [N(PPh2NR)(2)}(n)[GRAPHICS](OPri)(2-n)](R = Ph or SiMe3, G = CH2CH2, n = 1 or 2) have been synthesized under anhydrous and inert conditions by the reaction of acyclic bis-silylated phosphazene ligand (A), [HN(PPh2NSiMe3)(2)] with TiCl4, TiCl2(OPri)(2) or[GRAPHICS](OPri)(2) in 1:1 and 2:1 molar ratios. These titanatriazadiphosphorines were characterized by elemental analyses (C, H, N, Cl and Ti), molecular weight determination, and spectral studies including IR and NMR (H-1, C-13, and P-31), which have indicated monomeric nature of the complexes and bidentate mode of bonding by phosphazene moiety leading to a trigonal bipyramidal and octahedral geometries around the titanium atom in 5 and 6 coordination numbers.
• Roesky, Herbert W.; Olms, Petra; Hasselbring, Reinhard, Phosphorus, Sulfur and Silicon and the Related Elements, 1993, vol. 76, # 1-4, p. 255 - 260
  作者：Roesky, Herbert W.、Olms, Petra、Hasselbring, Reinhard、Winkhofer, Norbert、Liu, Feng Quan、Noltemeyer, Mathias

  DOI：——

  日期：——