4,4'-Diaminodiphenylhexafluoropropane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-Diaminodiphenylhexafluoropropane
• 英文别名: 4-[1-(4-Aminophenyl)-1,2,2,3,3,3-hexafluoropropyl]aniline
• 化学式: C₁₅H₁₂F₆N₂
• 分子量: 334.264
• InChiKey: NMMYPVBFDRCTEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  4,4'-Diaminodiphenylhexafluoropropane 、 苯甲酰基异硫氰酸酯 以 乙酸乙酯 为溶剂， 以97.3%的产率得到4,4'-di(benzoylthiocarbamoylamino)diphenylhexafluoropropane
  参考文献：
  名称：

  Dimerized thiourea derivatives near-infared absorbents comprising the

  摘要：

  通过加热式1或式2的二聚硫脲衍生物和铜化合物，获得近红外吸收剂：##STR1## 该近红外吸收剂用于制备在近红外区域具有广泛吸收的近红外吸收树脂材料，且该吸收剂在树脂的成型温度下基本不分解。二聚硫脲衍生物的典型例子包括4,4'-二(苄基硫代氨基甲酰基)氨基二苯甲烷、4,4'-二(苄基硫代氨基甲酰基)氨基二苯基六氟丙烷和1,4'-二(二苯甲酰基硫代氨基甲酰基氨基)-2,5-二甲基苯，铜化合物的典型例子包括硬脂酸铜和β-丙烯酰氧基丙基氢邻苯二甲酸铜。

  公开号：

  US05723075A1

文献信息

• Compound having silsesquioxane skeleton and its polymer
  申请人：Inagaki Jyun-ichi

  公开号：US20050009982A1

  公开（公告）日：2005-01-13

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, and Q 2 is a group represented by Formula (2) wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, —CH═CR—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in Claim 1.

  本发明涉及一种由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是苯基，可能具有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己基、环己烯基或苯基，其中可选的氢原子可被卤素或具有1至5个碳原子的烷基取代；Q2是由式（2）表示的基团，其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己亚基、1,4-环己烯亚基、具有6至10个碳原子的缩合环基团，为二价基团，或1,4-苯亚基，Z0至Z3独立地为单键、—CH═CR—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。式（1）中的Y1是权利要求1中定义的基团。
• Verification of translation
  申请人：Inagaki Jyun-ichi

  公开号：US20070190344A1

  公开（公告）日：2007-08-16

  A compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q 2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, and A 1 to A 4 , Z 0 to Z 4 and Y 1 are defined in the specification.

  公式（1）所表示的化合物和使用该化合物制得的聚合物：其中R1是苯基，可以有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己烯基或苯基，其中可选氢原子可以被卤素或具有1至5个碳原子的烷基所取代；Q2是由公式（2）表示的基团：其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4、Z0至Z4和Y1在规范中有定义。
• COMPOUND HAVING SILSESQUIOXANE SKELETON AND ITS POLYMER
  申请人：INAGAKI Jyun-ichi

  公开号：US20120178894A1

  公开（公告）日：2012-07-12

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, <—Z 0 A 1 -Z 1  l A 2 -Z 2  m A 3 -Z 3  n A 4  p -Z 4 —  (2) and Q 2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in claim 1.

  本发明涉及一种由公式（1）表示的化合物以及使用该化合物获得的聚合物：其中R1是苯基，可以具有取代基，Q1是氢、卤素、1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己烯基或苯基，其中可选的氢原子可以被卤素或1至5个碳原子的烷基所取代，<—Z0A1-Z1lA2-Z2mA3-Z3nA4p-Z4—（2）和Q2是由公式（2）表示的基团：其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己基、1,4-环己烯基、具有6至10个碳原子的紧凑环基团，或1,4-苯基，Z0至Z3独立地为单键、CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。公式（1）中的Y1是权利要求1中定义的基团。
• A process for bis (4-aminophenyl) hexafluoropropane
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0311028A2

  公开（公告）日：1989-04-12

  This invention is an improved process for preparing 2,2-bis(4-aminophenyl)hexafluoropropane which comprises subjecting 2,2-bis(4-aminocarbonylphenyl)hexafluoropropane to the Hofmann reaction and then treating that reaction product under reducing conditions to produce the desired amine in high yield.

  本发明是一种制备 2,2-双（4-氨基苯基）六氟丙烷的改进工艺，包括将 2,2-双（4-氨基羰基苯基）六氟丙烷进行霍夫曼反应，然后在还原条件下处理该反应产物，以高产率生产所需的胺。
• Copolyimides derived from 2,2-bis (amino phenyl) hexafluoropropane
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0354360A1

  公开（公告）日：1990-02-14

  Polyimides derived from the reaction product of 3,3′-6­F diamine or 4,4′-6 F diamine and pyromellitic dianhydride (PMDA) can be rendered solvent soluble while at the same time exhibiting an improvement in both mechanical and electrical properties by the inclusion of at least one other dianhydride having a diaryl nucleus in the reaction media. Suitable such dianhydrides include bis (3,4 dicarboxy phenyl) ether dianhydride (ODPA), 3,3′4,4′ benzophenone tetracarboxylic dianhydride (BTDA), 3,3′,4,4′ diphenyl tetracarboxylic acid dianhydride (BPDA) and 2,2 bis(3,4 dicarboxyphenyl) hexafluoropropane dianhydride (6F-DA). Such polyimides are soluble in common organic solvents such as methyl ethyl ketone or N methyl pyrrolidone, and exhibit excellent film forming properties with improved mechanical and electrical properties as compared to the corresponding homopolyimides. They possess excellent heat stability (Tg's in excess of about 350oC) and have superior electrical properties, for example, dielectric constant of less than about 2.5 at 10 megahertz.

  由 3，3′-6F 二胺或 4，4′-6F 二胺和偏苯二酸酐（PMDA）的反应产物制得的聚酰亚胺，通过在反应介质中加入至少一种具有二芳基核的二酸酐，可在改善机械和电气性能的同时，使其具有溶剂可溶性。合适的此类二酸酐包括双（3,4-二羧基苯基）醚二酸酐（ODPA）、3,3′4,4′二苯甲酮四羧酸二酸酐（BTDA）、3,3′,4,4′二苯基四羧酸二酐（BPDA）和 2,2-双（3,4-二羧基苯基）六氟丙烷二酐（6F-DA）。这些聚酰亚胺可溶于甲乙酮或 N 甲基吡咯烷酮等常见有机溶剂，与相应的均聚酰亚胺相比，它们具有优异的成膜性能，机械和电气性能也有所改善。它们具有出色的热稳定性（Tg 超过约 350 摄氏度）和卓越的电气性能，例如在 10 兆赫兹时介电常数小于约 2.5。