manganese(II) phenylphosphonate monohydrate | 45986-31-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: manganese(II) phenylphosphonate monohydrate
• 英文别名: manganese phenylphosphonate monohydrate；Dioxido-oxo-phenyl-lambda5-phosphane;manganese(2+);hydrate；dioxido-oxo-phenyl-λ5-phosphane;manganese(2+);hydrate
• CAS: 45986-31-0
• 化学式: C₆H₅O₃P*H₂O*Mn
• 分子量: 229.031
• InChiKey: HQKQKBXFBTVEBN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.6
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  64.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  manganese phenylphosphonate 在 H₂O 作用下， 以 neat (no solvent) 为溶剂， 生成 manganese(II) phenylphosphonate monohydrate
  参考文献：
  名称：

  Divalent metal phenylphosphonates and phenylarsonates

  摘要：

  DOI：

  10.1016/s0020-1693(00)95524-5

文献信息

• Layered Mixed-Metal Phenylphosphonates, MnxCo1−x(O3PC6H5)·H2O: Structure and Magnetic Properties
  作者：Jeffrey T. Culp、Gail E. Fanucci、Brian C. Watson、A. Nicole Morgan、Rénal Backov、Hitoshi Ohnuki、Mark W. Meisel、Daniel R. Talham

  DOI：10.1006/jssc.2001.9166

  日期：2001.7

  of the magnetic data for the pure Mn2+ (x=1) and pure Co2+ (x=0) samples was fitted by standard 2D Heisenberg and 2D Ising models, respectively, yielding nearest-neighbor exchange interaction energies of J=−2.27±0.02 K for Mn(O3PC6H5)·H2O and J=−2.43±0.05 K for Co(O3PC6H5)·H2O. The magnetic phase diagram, down to 2 K, was constructed over the entire composition range. Both dc and ac magnetic susceptibilities

  组合物的Mn混合金属phenylphosphonates X钴1- X（O 3 PC 6 ħ 5）·H 2用0≤制备ö X ≤1。原子吸收，X射线粉末衍射和电子顺磁共振测量表明，混合金属固体溶液是均匀的并且同构，在整个浓度范围内的单金属母体化合物，与所述的一个小的，系统进化一个和ç面内的晶胞参数。磁数据的对于纯的Mn的温度依赖性2+（X = 1）和纯钴2+（X = 0）的样本进行拟合通过标准的2D海森堡和2D伊辛模型，分别得到的最近邻居交换相互作用能量Ĵ = -2.27±0.02 K中的Mn（O 3 PC 6 ħ 5）·H 2 O和Ĵ = -2.43±0.05 K中钴（O 3 PC 6 ħ 5）·H 2 O的磁性相图，下降到2 K，构建在整个组合物范围内。直流和交流磁化率均用于识别向低温，长距离有序反铁磁态的跃迁。在锰2+ -和Co 2+富集的地区，有序化温度，Ť Ñ，如预期的磁离子杂质掺
• Tailoring the photoluminescence properties of transition metal phosphonates
  作者：Richard Singleton、James Bye、James Dyson、Gary Baker、Robert M. Ranson、Gary B. Hix

  DOI：10.1039/c000531b

  日期：——

  A series of phenylphosphonates, Zn1−xMnx(O3PC6H5)·H2O, where x = 0, 0.005, 0.25, 0.5, 0.75 and 1.0, has been prepared and their photoluminescence responses studied. The presence of Mn in the sample results in a red emission, whilst when x = 0 the emission is green. Levels of Mn <1 mol% result in an orange emission. Ag6(m-O3PC6H4CO2)2 has been prepared by hydrothermal reaction of Ag(NO3) and m-phosphonobenzoic acid. The material has a 1D channel structure in which the channels are lined with the phenyl groups. Ag6(m-O3PC6H4CO2)2 shows a green luminescence response to laser excitation, whilst the related Zn material, Zn3(m-O3PC6H4CO2)2, shows an unusual yellow emission.

  制备了一系列苯基膦酸酯 Zn1−xMnx(O3PC6H5)·H2O，其中 x = 0、0.005、0.25、0.5、0.75 和 1.0，并研究了它们的光致发光响应。样品中 Mn 的存在导致红色发射，而当 x = 0 时，发射呈绿色。 Mn 含量<1 mol% 会导致橙色发射。 Ag6(m-O3PC6H4CO2)2 通过 Ag(NO3) 和间膦酰基苯甲酸的水热反应制备。该材料具有一维通道结构，其中通道排列有苯基。 Ag6(m-O3PC6H4CO2)2 对激光激发显示出绿色发光响应，而相关的 Zn 材料 Zn3(m-O3PC6H4CO2)2 显示出不寻常的黄色发射。
• Selected-Control Synthesis of Metal Phosphonate Nanoparticles and Nanorods
  作者：Shu-Yan Song、Jian-Fang Ma、Jin Yang、Min-Hua Cao、Ke-Chun Li

  DOI：10.1021/ic048436t

  日期：2005.4.1

  By surfactant-assisted methods, nanoscale Co(O3PC6H5)center dot H2O species of different morphologies, namely, nanoparticles and nanorods, have been successfully synthesized and characterized. Upon removal of the organic part of the compound, peculiar Co2P2O7 porous nanorods formed.
• Cao, Guang; Lee, Haiwon; Lynch, Vincent M., Inorganic Chemistry, 1988, vol. 27, # 16, p. 2781 - 2785
  作者：Cao, Guang、Lee, Haiwon、Lynch, Vincent M.、Mallouk, Thomas E.

  DOI：——

  日期：——