2,7-bis(2-methyl-4-nitrophenylbenzo[3,8]phenanthroline)-1,3,6,8(2H,7H)-tetrone | 936372-34-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,7-bis(2-methyl-4-nitrophenylbenzo[3,8]phenanthroline)-1,3,6,8(2H,7H)-tetrone
• 英文别名: 6,13-Bis(2-methyl-4-nitrophenyl)-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone
• CAS: 936372-34-8
• 化学式: C₂₈H₁₆N₄O₈
• 分子量: 536.457
• InChiKey: HBKKOHKOGMHGTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  40
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  166
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1,4,5,8-萘四甲酸酐 、 4-硝基-2-甲苯胺 以 甲苯 为溶剂， 反应 3.0h， 生成 2,7-bis(2-methyl-4-nitrophenylbenzo[3,8]phenanthroline)-1,3,6,8(2H,7H)-tetrone
  参考文献：
  名称：

  WO2008/73613

  摘要：

  公开号：

文献信息

• MATERIALS AND METHODS FOR CO-CRYSTAL CONTROLLED SOLID-STATE SYNTHESIS OF IMIDES AND IMINES
  申请人：Zaworotko Michael J.

  公开号：US20080146772A1

  公开（公告）日：2008-06-19

  The subject invention pertains to methods for solid-state synthesis of imides and imines using co-crystals. The co-crystal formers utilized are substrates of condensation reactions and co-crystals can be obtained in high yield via methods such as slurrying, solvent evaporation, solvent crystallization, treatment with supercritical fluid(s), melting plus crystallization, slurry conversion, grinding of solids, blending of powders, heating of solids, solvent-drop grinding, or grinding plus melting.
• [EN] MATERIALS AND METHODS FOR CO-CRYSTAL CONTROLLED SOLID-STATE SYNTHESIS OF IMIDES AND IMINES<br/>[FR] MATERIAUX ET PROCEDES DE SYNTHESE EN PHASE SOLIDE D'IMIDES ET D'IMINES REGULEE PAR CO-CRISTAUX
  申请人：UNIV SOUTH FLORIDA

  公开号：WO2008073613A2

  公开（公告）日：2008-06-19

  [EN] The subject invention pertains to methods for solid-state synthesis of imides and imines using co-crystals. The co-crystal formers utilized are substrates of condensation reactions and co-crystals can be obtained in high yield via methods such as slurrying, solvent evaporation, solvent crystallization, treatment with supercritical fluid(s), melting plus crystallization, slurry conversion, grinding of solids, blending of powders, heating of solids, solvent-drop grinding, or grinding plus melting.
  [FR] L'invention concerne des procédés de synthèse en phase solide d'imides et d'imines au moyen de co-cristaux. Les formeurs de co-cristaux utilisés sont des substrats de réactions de condensation et les co-cristaux peuvent être obtenus à haut rendement par la mise en uvre de procédés tels que la mise en suspension, l'évaporation de solvant, la cristallisation de solvant, le traitement par fluide(s) supercritique(s), la fusion plus cristallisation, la conversion de suspension épaisse, le broyage de matières solides, le mélange de poudres, le chauffage de matières solides, le broyage par gouttes de solvant ou le broyage plus fusion.