4-(4-(dimethylamino)styryl)-1-((diphenylcarbamoyl)oxy)pyridin-1-ium tetraphenylborate | 705971-91-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(4-(dimethylamino)styryl)-1-((diphenylcarbamoyl)oxy)pyridin-1-ium tetraphenylborate
• CAS: 705971-91-1
• 化学式: C₂₄H₂₀B*C₂₈H₂₆N₃O₂
• 分子量: 755.767
• InChiKey: FTMDCFUVKSBRPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.66
• 重原子数：
  58.0
• 可旋转键数：
  10.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  36.66
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  4-甲基吡啶氧化物 、 4-(4-(dimethylamino)styryl)-1-((diphenylcarbamoyl)oxy)pyridin-1-ium tetraphenylborate 以 乙腈 为溶剂， 生成 、 4-(4'-N,N-dimethylaminostyryl)pyridine N-oxide
  参考文献：
  名称：

  Equilibrium of acyl transfer between pyridine N-oxides and their acylonium salts

  摘要：

  TransFer of' acyl groups from N-acyloxypyridinium salts to pyridine N-oxides in acetonitrile was studied. The equilibrium constants of' acyl exchange were determined. These quantities vary in the range coverino ei,,ht orders of magnituJe, depending on the structure of the reavents. and are independent of' the z' c C C structure ol'the acyl group.

  DOI：

  10.1134/s1070363208060248
• 作为产物：
  描述：

  、 4-(4'-N,N-dimethylaminostyryl)pyridine N-oxide 以 乙腈 为溶剂， 生成 4-甲基吡啶氧化物 、 4-(4-(dimethylamino)styryl)-1-((diphenylcarbamoyl)oxy)pyridin-1-ium tetraphenylborate
  参考文献：
  名称：

  Equilibrium of acyl transfer between pyridine N-oxides and their acylonium salts

  摘要：

  TransFer of' acyl groups from N-acyloxypyridinium salts to pyridine N-oxides in acetonitrile was studied. The equilibrium constants of' acyl exchange were determined. These quantities vary in the range coverino ei,,ht orders of magnituJe, depending on the structure of the reavents. and are independent of' the z' c C C structure ol'the acyl group.

  DOI：

  10.1134/s1070363208060248