1-(diphenylphosphinoethyl)-2-diphenylphosphine sulphide | 141422-94-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(diphenylphosphinoethyl)-2-diphenylphosphine sulphide
• 英文别名: 1,2-bis(diphenylphosphino)ethane monosulfide；1,2-bis(diphenylphosphano)ethane sulfide；Ph2P(CH2)2P(S)Ph2；dppeS；Phosphine sulfide, [2-(diphenylphosphino)ethyl]diphenyl-；2-diphenylphosphanylethyl-diphenyl-sulfanylidene-λ5-phosphane
• CAS: 141422-94-8
• 化学式: C₂₆H₂₄P₂S
• 分子量: 430.49
• InChiKey: QNEDBSJABDCVPE-UHFFFAOYSA-N

物化性质

• 沸点：
  558.7±52.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  29
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  32.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(diphenylphosphinoethyl)-2-diphenylphosphine sulphide 以 氯仿 、 乙腈 为溶剂， 生成 palladium bis([2-(diphenylphosphino)ethyl]diphenylphosphine sulfide-S,P')dinitrate tetrahydrate
  参考文献：
  名称：

  P,S-Ligands. Complexes ofP,P,P′,P′-tetraphenylethylenediphosphine monosulfide with PdCl2

  摘要：

  1 : 1 and 1 : 2 complexes of Ph2P(CH2)(2)P(S)Ph-2 with PdCl2 were synthesized. Their structures were established by P-31 NMR and IR spectroscopy and X-ray diffraction analysis. In the crystals, the 1 : 1 complex has a chelate structure. In CH2Cl2, this complex partially dissociates at the Pd ... S=P bond. According to the X-ray diffraction data, only the P-III atoms in the 1 : 2 complex are coordinated. The reaction of the I : 2 complex with AgNO3 afforded the cationic chelate complex [Pd(Ph2P(CH2)(2)P(S)Ph-2)(2)](2+) 2NO(3)(-).

  DOI：

  10.1007/bf02494907
• 作为产物：
  描述：

  1,2-双(二苯基膦)乙烷 在 sulfur 作用下， 生成 1-(diphenylphosphinoethyl)-2-diphenylphosphine sulphide
  参考文献：
  名称：

  Lobana, T. S.; Sharma, P. K., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1988, vol. 27, # 8, p. 732 - 733

  摘要：

  DOI：

文献信息

• Regioselectivity and memory effects in palladium catalyzed allylic alkylations with bidentate P^PS donor ligands
  作者：Suzanna C. Milheiro、J.W. Faller

  DOI：10.1016/j.jorganchem.2010.10.022

  日期：2011.2

  bidentate bisphosphine monosulfide ligands, were found to catalyze allylic alkylation reactions with high branched:linear selectivity with some ligands. Some of these catalysts also display a regiochemical memory effect, in which the hemilability and rigidity of the P^PS ligands affect the reaction rate and the degree to which a memory effect is observed.

  一系列配合物，[将Pd（η 3 -C 3 H ^ 5）（P ^ P小号）] [的SbF 6 ]，其中P ^ P小号是二齿膦配位体一硫化物，发现催化具有高支化烯丙基烷基化反应：有一些配体的线性选择性。这些催化剂也显示区域化学记忆效应，其中，所述的hemilability和刚性P ^ P小号配体影响反应速率和被观察到的记忆效应的程度。
• Synthesis and Carbonylation of Platinum( <scp>II</scp> ) Organometallic Complexes with Bis(phosphanyl) Monosulfides − Crystal Structures of [κ ^<i>2</i> <i>P</i> , <i>S</i> ‐{Ph ₂ CH ₂ P(S)Ph ₂ }Pt(CH ₃ )(Cl)] and [κ <i>P</i> ,μ‐κ <i>S</i> ‐{Ph ₂ CH ₂ CH ₂ P(S)Ph ₂ }Pt‐(CH ₃ )] ₂ [BF ₄ ] ₂
  作者：Piero Mastrorilli、Cosimo F. Nobile、Gian P. Suranna、Francesco P. Fanizzi、Giuseppe Ciccarella、Ulli Englert、Qi Li

  DOI：10.1002/ejic.200300428

  日期：2004.3

  The neutral complexes of formula [κ2P,S-(dppmS)Pt(CH3)(Cl)] (1) and [κ2P,S-(dppeS)Pt(CH3)(Cl)] (2) [dppmS = Ph2PCH2P(S)Ph2, dppeS = Ph2P(CH2)2P(S)Ph2] have been synthesised and characterised. Reaction of 1 and 2 with AgBF4 carried out in CH3CN or CH3CN/CH2Cl2 affords the corresponding monomeric cationic complexes [κ2P,S-(dppmS)Pt(CH3CN)(CH3)][BF4] (3) and [κ2P,S-(dppeS)Pt(CH3CN)(CH3)][BF4] (4). Complexes

  式 [κ2P,S-(dppmS)Pt(CH3)(Cl)] (1) 和 [κ2P,S-(dppeS)Pt( )(Cl)] (2) [dppmS = Ph2PCH2P(S) 的中性配合物)Ph2, dppeS = Ph2P(CH2)2P(S)Ph2] 已被合成和表征。在 CN 或 CN/ Cl2 中进行 1 和 2 与 AgBF4 的反应得到相应的单体阳离子配合物 [κ2P,S-(dppmS)Pt( CN)( )][BF4] (3) 和 [κ2P,S-( dppeS)Pt( CN)( )][BF4] (4)。配合物 3 和 4 在 CD2Cl2 中部分解离，在 3 的情况下，产生不对称二聚体 [κ2P,S-(dppmS)]( )PtκP,μ-κS-(dppmS)}Pt( )( CN)][BF4]2 (5)，以及在 4 的情况下，对称的硫桥二聚体
• O'Mahoney, Caroline A.; Parkin, Ivan P.; Williams, David J., Journal of the Chemical Society, Dalton Transactions, 1989, p. 1179 - 1186
  作者：O'Mahoney, Caroline A.、Parkin, Ivan P.、Williams, David J.、Woollins, J. Derek

  DOI：——

  日期：——
• Carbonyl complexes of ruthenium(II) with unsymmetrical phosphine–phosphinesulfide ligands of the type Ph2P(CH2)nP(S)Ph2, n=1–4
  作者：Pratap Chutia、Manab Sharma、Pankaj Das、Nandini Kumari、John Derek Woollins、Alexandra M.Z Slawin、Dipak Kumar Dutta

  DOI：10.1016/s0277-5387(03)00371-1

  日期：2003.8

  Reaction of [Ru(CO)(2)Cl-2](n) with ligands Ph2P(CH2)(n) P(S)Ph-2 (n = 1(a), 2(b), 3(c), 4(d)) in 1:1 molar ratio produces complex cis-[Ru(CO)(2)Cl-2(P boolean AND S)](1a) (P boolean AND S = eta(2)-(P, S) Coordinated) and cis -[Ru(CO)(2)Cl-2(P-S)](1b-d) (P-S = eta(1)-(P) coordinated), while 1:2 molar ratio yields complex of the type cis -[Ru(CO)(2)Cl-2(P-S)(2)](2a-d). The complex 2a undergoes partial decarbonylation reaction in CH2Cl2-hexane solution to give a new chelated complex [Ru(CO)Cl(P boolean AND S)(2)]Cl(2a'). Abstraction of halide with AglO(4) from the non-chelated complexes 1b-d and 2a-d afford corresponding chelated complexes [Ru(CO)(2)Cl(P boolean AND S)](ClO4)(3b-d) and [Ru(CO)(2)(P boolean AND S)(2)](ClO4)(2)(4a-d). The molecular structure of the complex 2a' has been determined by single crystal X-ray diffraction. The ruthenium atom is at the Centre of slightly distorted octahedral structure having the two phosphorus atoms of the two chelated P, S coordinated ligands at trans to each other, one CO group and Cl atom completing the coordination sphere. Other complexes have been characterized by elemental analysis, IR, 1H and 31p JHJ NMR spectroscopy. (C) 2003 Elsevier Ltd. All rights reserved.
• Lobana, Tarlok S.; Verma, Renu, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2003, vol. 42, # 3, p. 534 - 536
  作者：Lobana, Tarlok S.、Verma, Renu

  DOI：——

  日期：——